宽温域热敏变色可擦笔微胶囊色浆的制备
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天津大学化工学院

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TQ621;TQ622

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国家重点研发计划项目(2022YFB3603101),国家自然科学(22278315)


Preparation of wide temperature range thermochromic color-changing erasable pen microcapsule color paste
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School of Chemical Engineering and Technology,Tianjin University

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    摘要:

    为继续提升国产可擦笔色浆工艺水平,研制了具备大滞后变色能力的宽温域变色色浆。以结晶紫内酯(CVL)为隐色体、双酚AF(BPAF)为显色剂、4-苄氧基苯基乙基癸酸酯(DPE)为固体溶剂,获得最适宜可擦墨水的芯材比为m(CVL): m(BPAF): m(DPE)=1:2:50,芯材的消色温度大于55 ℃且具有良好的变色滞后能力。以脲醛树脂为壁材,通过原位聚合的方式对芯材进行微胶囊化,对微胶囊化过程的乳化剂浓度、乳化搅拌速度、时间进行了重点研究,8%乳化剂浓度时,以10000 rpm的搅拌速度乳化1 h时获得微胶囊粒径分布在500~1300 nm,包覆率为82.4%,色浆消色温度为55~60 ℃、显色温度为-15~-20 ℃。所制得的色浆色彩性质良好,可擦性能符合使用要求。

    Abstract:

    In order to further improve the technological level of domestic erasable pen color paste, a wide temperature range color changing paste with large delay capability was developed. Using crystal violet lactone (CVL) as leucochroma, bisphenol AF(BPAF) as chromogenic agent and 4-benzoxy phenyl ethyl caprate (DPE) as solid solvent, the most suitable core material ratio for erasable inks was m(CVL): m(BPAF): m(DPE)=1:2:50, so that the core material achromatic temperature is greater than 55 ℃ and has a good color-changing lag ability. Using urea-formaldehyde resin as the wall material, the core material was microencapsulated by in-situ polymerization, and the emulsifier concentration, emulsifying stirring speed and time during the microencapsulated process were studied. The microcapsules with particle size ranging from 500 nm to 1300 nm were obtained at 8% emulsifier concentration and a stirring speed of 10,000 rpm for 1 h. The coating rate was 82.4%, the achromatic temperature of the paste was 55~60 ℃, and the color developing temperature was -15~-20 ℃. The color properties of the prepared paste are good, and the erasability meets the requirements of use.

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李彬,蒋博睿,姜爽,张天永.宽温域热敏变色可擦笔微胶囊色浆的制备[J].精细化工,2025,42(2):

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  • 收稿日期:2024-01-26
  • 最后修改日期:2024-04-14
  • 录用日期:2024-03-21
  • 在线发布日期: 2025-01-23
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