海水基速溶耐温聚合物的制备与性能
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1.陕西科技大学 化学与化工学院 轻化工助剂化学与技术教育部重点实验室;2.长庆油田分公司油气工艺研究院

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陕西省外国专家服务计划(2023WGZJ-ZD-03);陕西省重点研发计划项目(2023-YBGY-307,2024GX-YBXM-393);陕西省教育厅产业化项目(23JC008);西安市科技计划项目(22GXFW0014)


Preparation and properties of seawater based instant and temperature resistant polymers
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1.Key Laboratory of Chemical Additives for China National Light Industry, Shaanxi University of Science&Technology, Xi''an;2.Key Laboratory of Chemical Additives for China National Light Industry,Shaanxi University of Science&Technology,Xi''an;3.Research Institute of Petroleum Technology,Changqing Oilfield Company,Xi''an;4.Key Laboratory of Chemical Additives for China National Light Industry,Shaanxi University of Science Technology,Xi''an

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    摘要:

    为提高压裂液聚合物在海水中的耐温耐盐性能,以丙烯酰胺(AM)、2-丙烯酰胺基-2-甲基丙磺酸(AMPS)、4-丙烯酰吗啉(ACMO)和非离子疏水单体十八烷基聚氧乙烯醚甲基丙烯酸酯(OEMA)为单体,通过水溶液聚合法制备了海水基速溶耐温聚合物(PAOAA)。采用FTIR、1HNMR和SEM对其结构和形貌进行表征;通过增稠能力和流变性能实验对PAOAA作为压裂液进行性能测试。结果表明,PAOAA可在海水中2.0 min内溶解,质量分数0.8%的PAOAA溶液表观黏度为108 mPa·s,并表现出良好的耐温耐剪切性能,在100、170 s-1剪切速率下的终点黏度差别不大,不同温度下的终点黏度均>50 mPa·s。单体AMPS中含有的磺酸基团屏蔽海水中的盐离子,提高了PAOAA的水溶性;杂环ACMO提高了PAOAA分子链的刚性;非离子疏水单体OEMA使PAOAA表现出缔合微区,提高了PAOAA的耐温性能,在三者的协同作用下,PAOAA表现出速溶耐温性能。

    Abstract:

    To enhance the temperature and salt resistance of fracturing fluid polymers in seawater, acrylamide (AM), 2-acrylamido-2-methylpropanesulfonic acid (AMPS), 4-acryloylmorpholine (ACMO), and the nonionic hydrophobic monomer octadecyl polyoxyethylene ether methacrylate (OEMA) were used as monomers to prepare seawater-based instant temperature-resistant polymers (PAOAA) via aqueous solution polymerization. The structure and morphology were characterized using FTIR, 1H NMR, and SEM; PAOAA"s performance as a fracturing fluid was tested through thickening and rheological experiments. The results indicate that PAOAA can be dissolved in seawater within 2.0 minutes. The apparent viscosity of a 0.8% PAOAA solution is 108 mPa·s, demonstrating strong temperature and shear resistance. There is little difference in the endpoint viscosity at 100 and 170 s-1 shear rates, with values consistently over 50 mPa·s at different temperatures. The sulfonic acid groups in monomer AMPS shield salt ions in seawater, enhancing the water solubility of PAOAA; Heterocyclic ACMO enhances the rigidity of PAOAA molecular chains; The nonionic hydrophobic monomer OEMA allows PAOAA to form associative microdomains, improving its temperature resistance. The combined effects of these monomers result in the instantaneous and temperature-resistant properties of PAOAA.

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蔺旭杰,王磊,李小玲,赖小娟,党志强,李朋.海水基速溶耐温聚合物的制备与性能[J].精细化工,2025,42(3):

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  • 收稿日期:2024-01-26
  • 最后修改日期:2024-05-11
  • 录用日期:2024-04-19
  • 在线发布日期: 2025-03-14
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