全固态锂空气电池的调控策略
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贵州民族大学 化学工程学院 贵州 贵阳 550025

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国家自然科学基金项目(面上项目,重点项目,重大项目)


Regulation strategy of all-solid lithium air batteries
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College of Chemical Engineering,Guizhou Minzu University,Guizhou Guiyang 550025

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The National Natural Science Foundation of China (General Program, Key Program, Major Research Plan)

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    摘要:

    锂空气电池具有高能量密度和低还原电位,是现代社会需要的一种绿色储能电池,其应用范围广泛。由于传统的有机电解液存在可燃、分解、形成锂枝晶以及形成阻碍O2扩散的钝化层等问题,所以需开发固态电解质来提高锂空气电池的各项性能。该文首先介绍了锂空气电池的构建及工作机制,然后综述了经典全固态锂空气电池(ASSLAB)的调控策略,包括正极调控策略和电解质调控策略,同时对正极/电解质一体化设计策略进行了概述,最后对锂空气电池的固体电解质、界面修饰(即电解质与电极界面阻力的改善)和空气正极设计的优化等发展方向进行了展望。

    Abstract:

    Lithium air batteries have high energy density and low reduction potential. They are a green energy storage battery needed by modern society and have a wide range of applications. Because the traditional organic electrolytic has problems such as combustible, decomposition, the formation of lithium dendrites and the formation of a passivation layer that hinders the diffusion of O2, solid electrolytes need to be developed to improve the performance of lithium air batteries. This article first introduces the construction and working mechanism of lithium air batteries, and then summarizes the regulation strategy of the classic all-solid lithium air battery (ASSLAB), including the positive control strategy and electrolyte control strategy. At the same time, it summarizes the integrated design strategy of positive/electrolyte. Finally, it looks forward to the development direction of solid electrolyte, interface modification (i.e., the improvement of electrolyte and electrode interface resistance) and the optimization of air cathode design of lithium air batteries.

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刁坤兰,杜婧羽,占晓,张道海.全固态锂空气电池的调控策略[J].精细化工,2025,42(2):

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  • 收稿日期:2024-01-28
  • 最后修改日期:2024-04-14
  • 录用日期:2024-03-18
  • 在线发布日期: 2025-01-23
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