2-EEMPA为主体的双溶剂吸收剂用于CO2捕集
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河北工业大学 能源与环境工程学院

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X701; TQ016

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Dual-solvent absorbents based on 2-EEMPA for CO2 capture
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School of Energy and Environmental Engineering,Hebei University of Technology

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    摘要:

    为开发具备高循环负载和低再生能耗的CO2吸收剂。采用N-(2-乙氧基乙基)-3-吗啉丙-1-胺(2-EEMPA)、2-氨基-2-甲基-1-丙醇(AMP)和哌嗪(PZ)作为活性组分,同时以N, N-二甲基甲酰胺(DMF)和水(H2O)为溶剂,构建了三种体系:2-EEMPA/DMF/H2O、2-EEMPA/AMP/DMF/H2O和2-EEMPA/PZ/DMF/H2O。研究了三个体系在不同配比下的CO2吸收和解吸性能,并与30% MEA溶液进行了比较。结果表明,30E20D50H、20E10A40D30H和20E10P40D30H分别为各自体系最佳的配比组成。其中20E10P40D30H吸收剂表现最为优异,首次循环负载达到了0.573 mol/mol,是30% MEA溶液的2.09倍;在80℃下,解吸率为82.7%,较30% MEA溶液提升了28.1个百分点,且解吸能耗仅为30% MEA溶液的34.6%;经过五次循环吸收解吸后,CO2吸收负载仍保持在0.609 mol/mol,较30% MEA溶液提升了65.0%。

    Abstract:

    In order to develop CO2 absorbents with higher cyclic loading and lower regeneration energy consumption. Three systems were constructed: 2-EEMPA/DMF/H2O, 2-EEMP/AMP/DMF/H2O and 2-EEMPA/PZ/DMF/H2O, using N-(2-ethoxyethyl)-3-morpholinopropan-1-amine (2-EEMPA), 2-amino-2-methyl-1-propanol (AMP) and piperazine (PZ) as active components and N, N-dimethylformamide (DMF) and water (H2O) as solvents. The CO2 absorption and desorption performance of the three systems at different ratios were studied and compared with the 30% MEA solution. The results showed that 30E20D50H, 20E10A40D30H and 20E10P40D30H were the best ratios for their respective systems. Among them, 20E10P40D30H absorbent performed the best, the first cycle loading reached 0.573 mol/mol, which was 2.09 times that of 30% MEA solution, and the desorption rate was 82.7% at 80°C, which was 28.1 percentage points higher than that of 30% MEA solution, and the desorption energy consumption was only 34.6% of 30% MEA solution. After five cycles of absorption and desorption, the CO2 absorption loading remained at 0.609 mol/mol, which was 65.0% higher than that of 30% MEA solution.

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刘岳能,吴亚杰,曹蒙欢,单楠烁,苟湘.2-EEMPA为主体的双溶剂吸收剂用于CO2捕集[J].精细化工,2025,42(3):

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  • 收稿日期:2024-03-02
  • 最后修改日期:2024-05-26
  • 录用日期:2024-04-07
  • 在线发布日期: 2025-03-14
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