锂硫电池用凝胶电解质的制备及性能
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沈阳化工大学 材料科学与工程学院

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TM912.9

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国家自然科学基金(青年科学基金项目)


Preparation and performance study of gel electrolyte for lithium-sulfur batteries
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School of Materials Science and Engineering,Shenyang University of Chemical Technology,Shenyang

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The National Natural Science Foundation of China (Young Scientist Fund Program)

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    摘要:

    锂硫电池作为一种前景广阔的二次电池系统因其具有极高的能量密度而受到广泛关注。然而,可溶性多硫化锂(LiPs)在传统液态电解质中的穿梭效应严重阻碍了锂硫电池的发展。本工作利用紫外光引发聚合快速便捷的特点,采用在锂负极进行半原位聚合的方法制备了一种由聚乙二醇双甲基丙烯酸酯(PEGDMA)聚合物交联网络和PP隔膜复合而成的应用于锂硫电池的的凝胶聚合物电解质,在保持较高离子传导率的同时能够有效抑制多硫化锂的穿梭。相较于聚合物凝胶电解质的一般制备方法,采用贴锂负极半原位法组装的电池在对锂负极稳定性及电池容量保持率方面均有较大的提升。进一步研究了单体浓度对凝胶聚合物电解质及锂硫电池性能的影响。电池在0.2 C倍率下充放电150次后其放电比容量仍然保持735.1mAh/g,容量保持率可达到80.8%。

    Abstract:

    Lithium-sulfur batteries, as a promising secondary battery system, have garnered extensive attention due to their exceptionally high energy density. However, the shuttle effect of soluble lithium polysulfides (LiPS) in traditional liquid electrolytes significantly impedes the development of lithium-sulfur batteries. In this work, a gel polymer electrolyte for lithium-sulphur batteries was prepared by using semi-in-situ polymerisation at lithium cathode with the advantage of the rapid and convenient characteristics of UV photoinitiated polymerization. This electrolyte is composed of a poly(ethylene glycol) dimethacrylate (PEGDMA) polymer crosslinked network combined with a PP separator, which can effectively suppress the shuttling of LiPS while maintaining a high ionic conductivity. Compared to the general preparation method of polymer gel electrolytes, batteries assembled using the semi-in-situ method at the lithium anode show significant improvements in the stability of the lithium anode and the retention of battery capacity. Further, the effect of monomer concentration on the performance of gel polymer electrolytes and lithium-sulfur batteries was investigated. The battery maintains a discharge specific capacity of 735.1mAh/g after 150 cycles at a 0.2 C rate, with a capacity retention rate reaching 80.8%.

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蔡逸飞,齐舵,王天宇,张一博.锂硫电池用凝胶电解质的制备及性能[J].精细化工,2025,42(5):

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  • 收稿日期:2024-03-11
  • 最后修改日期:2024-05-13
  • 录用日期:2024-04-08
  • 在线发布日期: 2025-04-27
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