聚丙烯酸酯-纳米TiO2/聚碳酸酯薄膜的制备及性能
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1. 海南大学 海南省精细化工工程技术研究中心;2.海南省华盛新材料科技有限公司

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海南省重大科技计划项目(ZDKJ2021043);海南省研究生创新科研课题(Qhys2021-136)


Preparation, UV resistance and abrasion resistance of PA-nano TiO2/PC film with high light transmittance
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1. Hainan Provincial Fine Chemical Engineering Research Center,Hainan University;2.Hainan Huasheng New Material Technology Co., Ltd

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    摘要:

    在维持聚碳酸酯(PC)薄膜卓越的透明性前提下,对其进行抗紫外及耐磨性提升能够极大拓展其应用范围。本文通过旋涂工艺,将聚丙烯酸酯/纳米TiO2共混乳液(PA-纳米TiO2)与PC薄膜复合,制备PA-纳米TiO2/PC复合薄膜,扫描电子显微镜和紫外测试结果表明 PA-纳米TiO2/PC复合薄膜中纳米颗粒分布均匀,膜层表面均匀致密,对紫外吸收增强的同时能保证复合薄膜透光率仍与高透光PC薄膜相同,最高透过率高达90%,保持卓越的透明性。通过摩擦磨损测试结果可知,复合薄膜摩擦系数减小,表面硬度从改性前的B提升至2H,呈现更好的耐磨性。紫外老化试验结果表明,相同时间下PA-纳米TiO2/PC复合薄膜的老化程度更低,变色程度更低,抗紫外老化性能更好。

    Abstract:

    On the premise of ensuring the excellent transparency of polycarbonate (PC) film, the improvement of UV resistance and abrasion resistance can greatly expand its application range. In this paper, a PA-nano TiO2/PC composite film was prepared by coating the PC film with polyacrylate/nano TiO2 blended emulsion (PA-nano TiO2) through spin coating process. The results of scanning electron microscopy and ultraviolet test showed that the nanoparticles in the PA-nano TiO2/PC composite film distributed uniformly, the surface of the film was uniform and dense, and the ultraviolet absorption was enhanced. The transmittance of the composite film was still the same as that of the high-transmittance PC film, with the highest light transmittance of 90%, maintaining excellent transparency. From the friction and wear test results, it could be seen that the friction coefficient of the composite film decreased, and the surface hardness increased from B to 2H after modification, showing better wear resistance ability. The results of ultraviolet aging test showed that the PA-nano TiO2/PC composite film had a lower aging degree, a lower degree of discoloration, and better anti-ultraviolet aging performance at the same aging time.

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杨旭冰,张晋,刘威,秦梓瑜,刘钟馨,嵇向阳,王敦,尹学琼.聚丙烯酸酯-纳米TiO2/聚碳酸酯薄膜的制备及性能[J].精细化工,2025,42(2):

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  • 收稿日期:2024-03-15
  • 最后修改日期:2024-04-01
  • 录用日期:2024-03-27
  • 在线发布日期: 2025-01-23
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