生物基化学品合成聚酰胺弹性体的研究进展
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作者单位:

1.四川大学 轻工科学与工程学院;2.四川页岩气勘探开发有限责任公司;3.四川汇利集团

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TS15

基金项目:

国家自然科学基金(21876119)


Research progress in synthesis of polyamide elastomer from biobased platform chemicals
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Affiliation:

1.College of Biomass Science and Engineering,Sichuan University;2.Sichuan Shale Gas Exploration and Development Co,Ltd,Chengdu;3.Sichuan Huili Industry Co,Ltd,Chengdu

Fund Project:

National Natural Science Foundation of China (21876119)

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    摘要:

    聚酰胺热塑性弹性体(TPAEs)具有优异的力学性能、熵弹性和可加工性,已成为一种重要的弹性体材料。但传统的TPAEs原料主要来自于石化资源,造成了高能耗和环境污染等问题。因此,生物基TPAEs符合现代绿色环保、“双碳”目标的发展诉求,利用生物基平台化学品制备弹性体具有实际应用价值和现实意义。本文系统概括了制备TPAEs的生物质平台化学品原料,包括生物基的二胺、二羧酸、氨基酸和内酰胺等。详细介绍各类生物基化学品的来源、合成路线以及相应的生物基TPAEs的性能,对生物基化学品的国内发展现状和未来方向进行了展望;总结了合成生物基TPAEs软段化合物的种类、制备机理和性能差异,并简要展望了生物基TPAEs的功能特性与应用前景。此外还提出了生物基平台化学品及TPAEs的机遇和挑战,从而推动生物基弹性体材料进一步扩大未来的实际应用。

    Abstract:

    Thermoplastic polyamide elastomers (TPAEs) have emerged as important elastomer materials, because of their outstanding mechanical properties, entropy elasticity and processability. However, the traditional raw precursors of TPAEs are mainly from fossil materials, which causes high energy consumption and environmental pollution. Therefore, bio-based TPAEs are aligned with the development demands of modern green environmental protection and the "double carbon" goal. The utilization of bio-based platform chemicals for the production of elastomers holds practical value and significance. This study provides a comprehensive summary of biomass platform chemical raw materials used in the preparation of TPAEs, including bio-based diamines, bio-based dicarboxylic acids, bio-based amino acids, and bio-based lactams. Detailed information on the sources, preparation methods, and properties of various bio-based chemicals and their corresponding TPAEs is presented, and the domestic development status and future direction of bio-based chemicals are prospected. The types, preparation mechanisms and performance differences of soft segment compounds for synthetic bio-based TPAEs are summarized, along with a brief outlook on the functional properties and potential applications of bio-based TPAEs. Moreover, the paper discusses the opportunities and challenges associated with bio-based platform chemicals and TPAEs, aiming to drive the further advancement of bio-based elastomer materials in practical applications.

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张佳星,李 健,张 辉,王梦月,阎 斌.生物基化学品合成聚酰胺弹性体的研究进展[J].精细化工,2025,42(7):

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  • 收稿日期:2024-05-14
  • 最后修改日期:2024-07-15
  • 录用日期:2024-07-09
  • 在线发布日期: 2025-07-10
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