一锅法制备磁性双污泥生物炭及其对水中盐酸环丙沙星的吸附去除[1]
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1.华北水利水电大学环境与市政工程学院;2.河南环境与水利职业技术学院环境工程系;3.华北水利水电大学乌拉尔学院

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河南省科技攻关(242102231015,242102320135)。


One-Pot Synthesis of magnetic dual sludge biochar and its application of ciprofloxacin hydrochloride adsorption in aqueous solution
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1.School of Environmental and Municipal Engineering, North China University of Water Resources and Electric Power;2.Department of Environment engineering, Henan Vocational College of Water Conservancy and Environment;3.School of Ural, North China University of Water Resources and Electric Power

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    摘要:

    以造纸污泥(PMS)和自来水厂铁盐污泥(IBWS)为原料,采用一锅法制备磁性双污泥生物炭(MDSBC)。在采用SEM、N2吸附-解吸、XRD、FTIR、XPS和振动样品磁强计对材料进行表征的基础上,开展了MDSBC对水中盐酸环丙沙星(CIP)的静态吸附研究。结果表明,质量比IBWS:PMS=1:2.5时,500℃缺氧热解制备的MDSBC同时具备理想的CIP吸附容量和良好的磁分离性能。在初始pH3-9的范围内,受静电斥力的影响,pH=3的吸附容量最低,为28.13mg/g;pH=5的吸附容量最高,为33.65mg/g。MDSBC对CIP的吸附过程符合伪二级动力学模型。吸附等温线模型符合Langmuir热力学模型,吸附过程是自发的放热过程。溶液中Cl-和SO42-对CIP吸附的影响不大,而PO43-能够明显抑制MDSBC对CIP的吸附,且抑制程度随PO43-浓度增加而增大。MDSBC在循环使用5次后,吸附容量下降了12.5%。机理分析结果表明,物理吸附、化学吸附、氢键和π-π键作用参与了MDSBC对CIP的吸附。MDSBC是一种良好的CIP吸附材料。

    Abstract:

    Papermaking sludge (PMS) and iron-based waterworks sludge (IBWS) was used as raw materials to prepare magnetic dual sludge biochar (MDSBC) using the one pot method. After being characterized by SEM, N2 adsorption-desorption, XRD, FTIR, XPS, and vibrating sample magnetometer, the static adsorption of ciprofloxacin hydrochloride (CIP) in water by MDSBC was studied. The results showed that when the mass ratio of IBWS: PMS was 1:2.5, MDSBC prepared by pyrolysis at 500 ℃ in N2 atmosphere had desirable CIP adsorption capacity and good magnetic separation performance. Within the initial pH range of 3-9, the adsorption capacity at pH 3 was the lowest due to electrostatic repulsion, which is 28.13 mg/g; The adsorption capacity was highest at pH 5, which was 33.65 mg/g. The adsorption process of CIP by MDSBC fitted the pseudo-first-order kinetic model. The adsorption isotherm model conformed to Langmuir model, and the adsorption process was spontaneous and exothermic. Aqueous Cl- and SO42- prompted CIP adsorption slightly, while PO43- could significantly inhibit the CIP adsorption with the rising PO43- concentration. After 5 cycles of reuse, the adsorption capacity of MDSBC decreased by 12.5%. The mechanism analysis indicated that electrostatic adsorption, chemical adsorption, hydrogen bonding, and π-π interaction were involved in the adsorption of CIP by MDSBC.

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帖靖玺,闫梦佳,段晓涵,马佳颖,吴继胜,宋妍霏,陈都,刘玉浩.一锅法制备磁性双污泥生物炭及其对水中盐酸环丙沙星的吸附去除[1][J].精细化工,2025,42(5):

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  • 收稿日期:2024-08-11
  • 最后修改日期:2024-10-24
  • 录用日期:2024-09-09
  • 在线发布日期: 2025-04-27
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