微波加热下含铬革屑助废弃竹屑的半液化
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四川大学-自贡2019年校地科技合作专项资金项目(2019CDZG-10)


Chromium-containing leather shavings assisted in the semi-liquefaction of waste bamboo under microwave heating
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ichuan University-Zigong Special Funding Project for School-Local Science and Technology Cooperation in 2019 (2019CDZG-10)

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    摘要:

    以废弃竹屑为原料,在含铬革屑(LS)、盐酸和少量苯酚微波辅助形成的液化助剂作用下,制备了一种半液化竹粉,用于竹木板材的粘合。采用单因素实验,考察液化时间、液化温度、LS用量以及液固比〔m(水): m(竹粉)〕对液化效果的影响。用FTIR、SEM与DSC对比表征分析了竹粉半液化前后差别。在LS添加量为12%(以竹粉质量为基准,下同),液固比为5:1,微波加热温度150 ℃反应15 min的条件下,竹粉的液化率可达60.95%。液化率证明LS对竹粉具有催化液化作用,且制备的液化产品作为粘合剂制备胶合板能满足GB/T 9846—2015《普通胶合板》中II类胶合板指标,为两种废弃物的资源循化利用提供参考。

    Abstract:

    Using waste bamboo as raw materials, a semi-liquefied bamboo powder was prepared for the bonding of bamboo and wood boards under the action of a liquefaction aid formed by chromium-containing leather shavings (LS), hydrochloric acid and a small amount of phenol. Single factor experiment was used to investigate the influence of liquefaction time, liquefaction temperature, the dosage of LS and liquid-solid ratio on the effect of liquefaction. The difference of bamboo powder before and after semi-liquefaction was analyzed by FTIR, SEM and DSC. Under the conditions of 12% LS addition, a liquid-solid ratio of 5:1, and a microwave heating temperature of 150 ℃ for 15 min, the liquefaction rate of bamboo powder can reach 60.95%. The liquefaction rate proves that LS has a catalytic liquefaction effect on bamboo powder, and the prepared liquefied product can be used as a binder to prepare plywood to meet the category II plywood index in GB/T 9846-2015 "Ordinary Plywood". Therefore, it provides reference for the recycling utilization of two kinds of waste resources.is heated to the reaction temperature of 150 ℃ for 15 min. The liquefaction rate of bamboo powder reaches 60.95 %. It is proved that the chromium-containing leather shavings can catalyze the liquefaction of bamboo powders, and the liquefied product can meet the requirements of plywood adhesive, which provides a reference for the recycling utilization of two kinds of waste resources.

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蒲红霞,单志华.微波加热下含铬革屑助废弃竹屑的半液化[J].精细化工,2021,38(6):

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  • 收稿日期:2020-10-28
  • 最后修改日期:2021-01-05
  • 录用日期:2021-01-06
  • 在线发布日期: 2021-04-07
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