Nine novel compounds 1,1，-bis[(2-benzoylhydrazinyl)carbonyl]-ferrocene 3 were obtained from chlorocarbonyl ferrocene and aromatic formyl hydrazine by using microwave method. The structures of the title compounds have been determinded by IR, 1H NMR and ESI/MS techniques. The studies on the UV-Vis absorption spectroscopies show that the anion receptor 3f have selective recognition for F-, CH3COO-, and 3h, 3i for F-, CH3COO-, H2PO4-. Preliminary biological activity test show that ortho-substituted compounds 3a, 3b and 3c have bacteriostatic action to staphylococcus aureus, escherichia coli.