2-Bromo-6-fluorobenzyl bromide，2-Bromo-6-fluorophenyl methanol， 2-Bromo-6-fluorobenzoic acid and 2-Bromo-6-fluorobenzaldehyde were prepared from 2-Bromo-6-fluorotoluene by bromination，hydrolysis，oxidation and Sommlet reactions．And the synthesis process had been studied in this paper．The result showed that HBr/H2O2 as brominate agent，the yield of 2-Bromo-6-fluorobenzyl bromide was 90.3%；ethanol as solvent，the yield of 2-Bromo-6-fluorophenyl methanol was 92.8%；In the oxidation reaction，2-Bromo-6-fluorobenz- oic acid gived 58.2% with KMnO4，and under the condition of n(2-Bromo-6-fluoro benzyl bromide):n(Methenamine)=1.0:1.3，the yield of 2-Bromo-6-fluorobenzaldehyde was 79%．All products structures were characterized by nuclear magnetic resonance and infrared．