Tin antimony oxide-graphene oxide (ATO/GO) sheet hybrids are fabricated using GO as a precursor, then anchoring ATO on GO sheets with the help of 3-aminopropyltriethoxysilane. Scanning transmission electron microscope (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) are performed on the resultant composites. By using ATO/GO as fillers, the effect of ATO/GO content on the anticorrosion and antistatic properties of waterborne epoxy coatings (AE) are researched. The results show that the surface resistance of composite coating increase as ATO/GO content is increasing. When m (ATO/GO) =3wt%, water vapor transmittance of coating decrease to 62.13g/(m2?h) , and has lowest corrosion current density (Icorr=3.73E-9 A/cm2) and Maximum corrosion voltage (Ecorr=-0.19926v), anticorrosive efficiency increased by99.95% compared with blank sample.