Aniline/silicone-acrylate(Ani/SiAc) copolymer emulsion was prepared by emulsifier-free emulsion polymerization through grafting aniline(Ani) on vinyltrimethylsilane(VTMS) modified acrylate latex particles. The emulsion was characterization by FTIR and TEM, the anticorrosive property of its latex film was studied by polarization curves and electrochemical impedance spectra (EIS). The effect of temperature and the molar ratio of H2O2 and Ani to the anticorrosive property were discussed. The results showed that the electrochemical impedance value of Ani/SiAc copolymer latex film was 9.03×107 Ω•cm2 and the corrosion current density was merely 5.04×10-8 A/cm2 when the react temperature was 20°C for 6 h firstly, then 80°C for 2 h, and n(H2O2): n(Ani) was 2.5:1.