Structure design and structure-function relationship of emulsified viscosity reducers with temperature resistant and salt tolerant
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TQ423

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The National Key Technologies R&D Program of China

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    Abstract:

    AFOP-10(anionic-nonionic emulsified viscosity reducer)was synthesized from bisphenol AF(BPAF), p-hydroxybenzenesulfonic acid(PHSA), and polyoxyethylene octyl phenol ether-10(OP-10). The surface properties, the temperature resistance and salt tolerance performance was tested. The structure-function relationship was studied, and the mechanism of the emulsified viscosity reducer was preliminarily explored. The results showed that the HLB of AFOP-10 was 11.37, the turbidity point(Tk) was 75℃, the critical micelle concentration(cmc)was 0.08 g/L, and the surface tension of AFOP-10 was 30.30 mN/m. AFOP-10 showed good surface activity. The thermal degradation temperature of AFOP-10 was 363℃. The maximum salt-tolerant concentration of the emulsified viscosity reducer was 49476 mg/L with the molar ratio of BPAF, PHSA and OP-10 1∶6∶9. In the simulated brine system with salinity of 8246 mg/L, AFOP-10 still had good activity after aged at 300℃ for 24 h. The viscosity reduction rate could reach more than 98.50%. AFOP-10 had good emulsification and viscosity reduction effect on oils in different areas of Bohai Oilfield, and it had good universality.

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History
  • Received:November 04,2019
  • Revised:January 03,2020
  • Adopted:January 07,2020
  • Online: March 23,2020
  • Published:
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