The carrier Fe-HAP was synthesized by ion exchange method using commercially available low-grade HAP as raw material, and then supported Ni2P/HAP and Ni2P/Fe-HAP catalysts were prepared by impregnation method. The catalyst was characterized by N2 adsorption-desorption, scanning electron microscope (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and thermogravimetry (TG). Doping Fe3+ greatly increases the specific surface area of the carrier, Ni2P dispersed on the surface of Fe-HAP and good thermal stability. The reaction system was prepared by hydrogenation of phenol to cyclohexanone. The catalytic performance of Ni2P/HAP and Ni2P/Fe-HAP catalysts was compared using cyclohexanone prepared from phenol hydrogenation as the reaction system at a reaction temperature of 150 ° C, a pressure of 0.5 MPa, and a time of 3.5 h. It was found that the Ni2P/Fe-HAP catalyst showed good catalytic activity and cyclohexanone selectivity.