Abstract:Fluorinated poly (methyl) acrylate emulsions (FPEs) have received lots of attention for waterborne fluorinated coatings because of their merits of ease of preparation and modification,plus the fact that the resultant coatings have low surface energy, good anti-fouling property, and excellent chemical stability. The chemical composition has remarkable impact on emulsion and coating properties. Herein, the reported types of fluorinated monomers and their synthesis are introduced, the structure-performance relationship of FPEs is discussed, the preparation protocols and the prospect applications of FPEs are reviewed, and the challenges and future development of FPEs are discussed.