Poly(4-acrylamido-2,2,6,6-tetramethylpiperidine-1-oxy)-graphene oxide (PTAm-GO) composite was prepared by atom transfer radical polymerization method material. The composite material was characterized by infrared, Raman, X-ray diffraction, thermogravimetric, electron paramagnetic resonance and other methods, and the active material was used as a positive electrode to be assembled into a button cell to measure its cyclic voltammogram, electrochemical impedance spectrum and Charge and discharge cycle capacity.The results show that the PTAm-GO electrode can undergo a reversible oxidation-reduction reaction, and has a lower electrochemical impedance than PTAm and a charge-discharge capacity about twice higher. After 300 charge-discharge cycles, the electrode specific capacity remains at 138 mAh/g, the capacity retention rate is 96.5%. This has important reference value for the development of organic batteries, especially for the research of oxynitride radical polymer electrode materials.