The preparation of metal organic polymer-based negative materials and its lithium storage properties
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TQ15

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    Abstract:

    In order to find a new type of metal-organic polymer-based anode material with excellent electrochemical performance, a new type of cobalt-based metal-organic polymer (Co-MOP) was synthesized by hydrothermal method with trimellitic acid as the organic ligand and cobalt nitrate hexahydrate. Co-MOP was calcined at 500 ℃, 600 ℃ and 700 ℃ under air atmosphere to obtain the corresponding Co-MOP-500, Co-MOP-600, and Co-MOP-700 derivative materials. Co-MOP derived materials have been studied as anode materials for lithium-ion batteries. The electrochemical test results show that Co-MOP-600 exhibits excellent electrochemical performance. At a current density of 100 mA/g, the first discharge specific capacity of the Co-MOP-600 electrode reaches 1818.5 mAh/g, and the specific capacity can be maintained at 1308.5 mAh/g after 100 cycles.

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History
  • Received:June 21,2021
  • Revised:August 16,2021
  • Adopted:August 16,2021
  • Online: November 05,2021
  • Published:
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