Two-dimensional transition metal-carbon/nitride (MXene) is a novel two-dimensional carbonized nanomaterial with unique advantages such as a large lateral ratio, short transport pathways, and many nanochannels. The paper firstly reviews the preparation process of MXene/polyvinylidene fluoride (PVDF) membranes and analyzes the regulatory relationships between the electrical, mechanical, thermal, antibacterial, and chemical stability properties of MXene and PVDF membranes; then reviews the progress of MXene/PVDF composite membranes in separation membranes, high dielectric membranes, electromagnetic shielding membranes, and other applications; finally gives an overview of Finally, the development direction of MXene/PVDF membranes is prospected: in the current research stage, the extraction treatment of PVDF membranes is still an effective way to bring into play the excellent performance of MXene, which is a major research tool; at the same time, further in-depth research on the multifunctionality mechanism of MXene"s directional regulation of PVDF membranes can help better understand the interaction law between MXene and PVDF membranes; in addition, the In addition, application-oriented research should be strengthened to form a better practical application system. This will help to understand better the properties and performance of MXene/PVDF composite membranes and promote the research and practical application of MXene/PVDF composite membranes in various fields.