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第 36 卷第 5 期 精 细 化 工 Vol.36, No.5
201 9 年 5 月 FINE CHEMICALS May 2019

水处理技术与环境保护
NaClO-PMS 及 NaClO-O 协同活化降解印染废水
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张斌阳 ，李东亚 1,2* ，徐海明 ，孙 磊 1,3 ，夏东升
（1. 武汉纺织大学 环境工程学院，湖北 武汉 430200；2. 纺织印染清洁生产教育部工程研究中心，湖
北武汉 430200；3. 石狮市展耀纺织科技有限公司，福建 石狮 362712）

摘要：将次氯酸钠（NaClO）分别与过硫酸氢钾（KHSO 5 , 简称 PMS）和臭氧（O 3 ）协同活化，用于处理模拟
印染废水，以罗丹明 B（Rhodamine B, RhB）、活性艳蓝（Reactive Brilliant Blue, Knr）、活性艳红（Reactive Red,
X-3B）、甲基橙（Methyl Orange, MO）染料的降解率为指标，采用紫外-可见吸收光谱分析测试法，探讨其物质
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的量比、pH 及废水中 Cl 、NO 3 、SO 4 、HCO 3 等因素的影响。结果表明：NaClO-PMS 及 NaClO-O 3 体系最佳物
质的量比分别为 n(NaClO) : n(PMS)=1 : 1，n(NaClO) : n(O 3 )=2 : 3，分别在 pH 为 3~11、3~9 时对模拟印染废水具
有较好的降解效果，NaClO-PMS 体系在酸性条件下降解 RhB 效果较好，pH=3 时降解率可达到 96.18%；NaClO-O 3
体系在中性条件下对 RhB 的降解效果较好，pH=7 时降解率为 97.91%；阴离子对 NaClO-PMS 及 NaClO-O 3 体系
处理印染废水的影响均较小。
关键词：高级氧化；臭氧；次氯酸钠；过硫酸氢盐；印染废水；水处理技术
中图分类号：X703.1 文献标识码：A 文章编号：1003-5214 (2019) 05-0979-05

Degradation of Printing and Dyeing Wastewater by Synergistic
Activated NaClO-PMS or NaClO-O 3

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ZHANG Bin-yang , LI Dong-ya 1,2* , XU Hai-ming , SUN Lei , XIA Dong-sheng
（1. School of Environmental Engineering, Wuhan Textile University, Wuhan 430200, Hubei, China; 2. Engineering
Research Center of Textile Printing and Dyeing Production, Ministry of Education, Wuhan 430200, Hubei, China; 3.
ShishiZhanyao Textile Technology Co., Ltd., Shishi 362712,Fujian,China）
Abstract: Sodium hypochlorite (NaClO) was synergistically activated with peroxymonosulfate (PMS) and
ozone (O 3) to treat simulated printing and dyeing wastewater. The indicators are the degradation rates of
dyes such as Rhodamine B (RhB), Reactive Brilliant Blue (Knr), Reactive Red (X-3B), and Methyl Orange
(MO). UV-visible absorption spectroscopy analysis method is used to explore the influence of factors such
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as the ratio of material mass, pH, Cl , NO 3 , SO 4 , and HCO 3 in wastewater. The results show that the ratio
of the optimum mass of NaClO-PMS and NaClO-O 3 systems are n(NaClO) : n(PMS)=1 : 1 and
n(NaClO) : n(O 3)=2 : 3, which have good degradation of RhB at the pH of 3~11 and 3~9, respectively. The
NaClO-PMS system has better degradation of RhB under acidic conditions, the degradation rate reaches
96.18% at pH=3. The NaClO-O 3 system has a good degradation effect on RhB under the neutral pH
condition, and the degradation rate reaches 97.91% at pH=7. The concentration of anions have a little
influence on the treatment effect of printing and dyeing wastewater by NaClO-PMS or NaClO-O 3 system.
Key words: advanced oxidation; ozone; sodium hypochlorite; persulfate; printing and dyeing wastewater;
water treatment
Foundation items: The Creative Research Groups Program of the Natural Science Foundation of Hubei
Province (2018CFB682, 2017CFA026); Science and Technology Plan Key Project of Shishi City
(SS[2016]0137)

收稿日期：2018-04-15; 定用日期：2019-01-16; DOI: 10.13550/j.jxhg.20180267
基金项目：湖北省自然科学基金项目（2018CFB682,2017CFA026）；石狮市科技计划重点项目（SS[2016]0137）
作者简介：张斌阳（1995—），女，硕士生。联系人：李东亚(1982—)，男，博士，E-mail：dyli@wtu.edu.cn；夏东升(1971—)，男，
教授，E-mail：dongsheng_xia@wtu.edu.cn。