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第 36 卷第 6 期 精 细 化 工 Vol.36, No.6
201 9 年 6 月 FINE CHEMICALS June 2019

功能材料
梳状改性苯乙烯-马来酸酐共聚物制备与性能

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钱 涛 1,2 ，钟 毅 1,2* ，毛志平 1,2 ，徐 红 ，
张琳萍 1,2 ，隋晓锋 1,2 ，王碧佳 1,2
（1. 东华大学 生态纺织教育部重点实验室，上海 201620；2. 东华大学 纺织科技创新中心，上海
201620；3. 鲁泰纺织股份有限公司，山东 淄博 255000）

摘要：以靛红酸酐（IA）与聚乙二醇单甲醚 550（MPEG550）合成带有伯氨基的活性支链（IP550），并对苯乙
烯-马来酸酐共聚物（SMA）进行酰胺化改性，制备出梳状改性 SMA（SMA-IP550）。考察了产物的合成条件，
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并采用 FTIR 和 HNMR 对 SMA-IP550 的结构进行表征。结果表明：催化剂（4-二甲氨基吡啶）用量为反应物
总质量的 0.9%，MPEG550 和 IA 的物质的量比为 1∶1，反应温度 120 ℃，反应时间 30 min，活性支链 IP550 产
率达 79.3%；SMA 改性温度为 140 ℃，IP550 与 SMA 中马来酸酐（MA）的物质的量比为 0.5∶1，反应体系的固含
量 30%，反应时间 2 h，得到接枝率为 42.5%的改性苯乙烯-马来酸酐共聚物（SMA-IP550）。通过对比不同长度
活性支链改性 SMA 的分散、降黏、乳化和润湿性能，结果表明该类助剂结构可调，其分散作用以及乳化作用与
结构紧密相关。
关键词：SMA；改性；支链；性能
中图分类号：TS190.2 文献标识码：A 文章编号：1003-5214 (2019) 06-1021-07

Preparation and Properties of Comb-like Modified
Styrene-Maleic Anhydride Copolymers

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1,2
QIAN Tao , ZHONG Yi 1,2* , MAO Zhi-ping , XU Hong , ZHANG Lin-ping ,
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SUI Xiao-feng , WANG Bi-jia
（1. Key Laboratory of Ecological Textile, Donghua University, Shanghai 201620, China; 2. Innovation Center for Textile
Science and Technology, Donghua University, Shanghai 201620, China; 3. Luthai Textile Co., Ltd, Zibo 255000, Shandong, China）
Abstract: An active branched chain (IP550) with a primary amino group was synthesized by isatoic
anhydride (IA) and methoxypolyethylene glycols 550 (MPEG550). An amidation reaction between
styrene-maleic anhydride copolymer (SMA) and IP550 led to comb-like modified polymer surfactant
(SMA-IP550). The synthesis conditions of IP550 and SMA-IP550 were investigated. The chemical
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structure of SMA-IP550 was characterized by FTIR and HNMR. The results showed that when dosage of
catalyst (4-dimethylaminopyridine) was 0.9% of the total mass of reactants, molar ratio of MPEG550 to IA
was 1∶1, reaction temperature was 120 ℃, and reaction time was 30 min, the yield of IP550 reached
79.3%. Modified SMA(SMA-IP550) with 42.5% grafting yield was obtained under the conditions of
temperature 140 ℃, molar ratio of IP550 to MA 0.5∶1, solid content 30%, and reaction time 2 h. By
comparing the dispersion, viscosity reduction, emulsification and wettability of modified SMA with
different branched-chain lengths, it was found that the structure of comb-like modified styrene-maleic
anhydride copolymer could be adjusted, and their dispersion and emulsification were closely related to their
structure.
Key words: SMA; modification; branched chain; properties
Foundation items: National Key R&D Program of China (2017YFB0309700); Taishan Industry Leading
Talent Project

收稿日期：2018-09-03; 定用日期：2018-12-25; DOI: 10.13550/j.jxhg.20180649
基金项目：国家重点研发计划资助（2017YFB0309700）；泰山产业领军人才工程专项经费资助
作者简介：钱 涛（1993—），男，硕士生。联系人：钟 毅（1974—），女，讲师，E-mail：zhongyi@dhu.edu.cn。