Page 90 - 《精细化工》2022年第11期
P. 90

·2240·                            精细化工   FINE CHEMICALS                                 第 39 卷

            低于其他的硒化钴系列,与 NiCoSe 4 相近。因而,                           Edition, 2016, 128(23): 6814-6819.
                                                               [7]   ROY A, JADHAV H S, THOTAT G M, et al. Electrochemical growth
            本研究制备的 CoSe 2 @NF 催化剂具有突出的全解水                          of Co(OH) 2 nanoflakes on Ni foam for methanol electro-oxidation[J].
            性能。这归因于 CoSe 2 @NF 表面粗糙的串珠状纳米                          New Journal of Chemistry, 2017, 41: 9546-9553.
                                                               [8]   DOU S, LI X Y, LI T, et al. Cobalt nanoparticle-embedded carbon
            线结构增加了有效活性位点的数量,在 OER 和 HER                            nanotube/porous carbon hybrid derived from MOF-encapsulated
            反应过程中提高了其反应效率。                                         Co 3O 4 for oxygen electrocatalysis[J]. Chemical  Communications,
                                                                   2016, 52(62): 9727-9730.

                                                               [9]   LIU H T, GUAN J Y, YANG S X, et al. Metal-organic framework-
                                                                   derived Co 2P nanoparticle/multi-doped porous carbon as a trifunctional
                                                                   electrocatalyst[J].  Advanced Materials, 2020, 32(36): 2003649-
                                                                   2003656.
                                                               [10]  GUO Y Y, YUAN P F, ZHANG J N, et al. Co 2P-CoN double active
                                                                   centers confined in N-doped carbon nanotube: Heterostructural
                                                                   engineering for trifunctional catalysis toward HER, ORR, OER, and
                                                                   Zn-air batteries driven water splitting[J]. Advanced Functional
                                                                   Materials, 2018, 28(51): 1805641-1805648.
                                                               [11]  CHAJRABARTTY S, KARMAKAR S,  RAJ  C  R. An electro-
                                                                   catalytically active nanoflake-like Co 9S 8-CoSe 2 heterostructure  for
                                                                   overall water splitting[J]. ACS Applied Nano Materials, 2020, 3(11):
                                                                   11326-11334.
                                                               [12]  LI Y G, FU X, ZHU W X, et al. Self-ZIF template-directed synthesis
                                                                   of a CoS nanoflake array as a Janus electrocatalyst for overall water
                     图 10   钴基硒化物全解水性能比较
                                                                   splitting[J]. Inorganic Chemistry Frontiers, 2019, 6: 2090-2095.
            Fig. 10    Comparison of overall water splitting performance   [13]  ZHOU Y, XIAO H Q, ZHANG S, et al. Interlayer expanded lamellar
                    of cobalt-based selenides                      CoSe 2 on carbon paper as highly efficient and stable overall water
                                                                   splitting electrodes[J]. Electrochimica Acta, 2017, 141: 106-115.
                                                               [14]  KONG D S, WANG H T, LU Z Y, et al. CoSe 2 nanoparticles grown
            3   结论                                                 on carbon fiber paper: An efficient and stable electrocatalyst for
                                                                   hydrogen evolution reaction[J]. American  Chemical Society, 2014,
                 利用水热法制备出 Co(OH)F@NF 后,对其在                         136: 4897-4900.
                                                               [15]  WAN S, JIN W Y, GUO X L, et al. Self-templating construction of
            400  ℃硒化 2 h 得到表面粗糙的串珠状纳米线                             porous CoSe 2 nanosheet arrays as efficient  bifunctional electro-
            CoSe 2 @NF,较大的长径比可增大催化剂与电解液                            catalysts for overall water splitting[J]. ACS Sustainable Chemistry &
                                                                   Engineering, 2018, 6(11): 15374-15382.
            的接触面积。对其进行同一碱性电解液的双功能催                             [16]  WEI X L (卫学玲), BAO W W (包维维), JIANG P (蒋鹏) , et al.
            化性能测试,其 OER 性能优于涂覆的 IrO 2 @NF;其                        One-step hydrothermal synthesis of 3D flower-like Co 9S 8/MoS 2
                                                                   @TM as efficient oxygen evolution electrode[J]. Fine Chemicals (精
            HER 性能 与涂覆的 Pt/C@NF 相当。装 配有                            细化工) , 2022, 39(1): 164-170.
                                                     2
            CoSe 2 @NF 电极的碱性全解水槽在 20 mA/cm 电流                  [17]  TANG C, CHENG N Y, PU Z H, et al. NiSe nanowire film supported
                                                                   on nickel foam: An efficient and stable 3D bifunctional electrode for
            密度运行 100 h 后,电流密度仅下降了 11%。本工                           full water splitting[J].  Angewandte Chemie International Edition,
                                                                   2015, 127(32): 9483-9487.
            作为设计和合成用于碱性全解水的双功能硒化纳米                             [18]  CHEN  T, LI S Z,  WEN J,  et al. Rational construction of hollow
            催化性剂提供了普适性策略和实验支撑。                                     core-branch CoSe 2  nanoarrays for high-performance  asymmetric
                                                                   supercapacitor and efficient oxygen evolution [J]. Small, 2018, 14(5):
            参考文献:                                                  1700979-1700986.
                                                               [19]  CHEN B W (陈保卫), GAO W J (高文君), DU S M (杜庶铭), et al.
            [1]   JAIN I P, LAL C, JAIN A. Hydrogen storage in Mg: A  most   Synthesis and catalytic performance comparison of rod-shaped
                 promising material[J]. International Journal of Hydrogen Energy,   FeS 2/NiS 2 and FeP/Ni 2P[J]. Fine Chemicals (精细化工), 2020,
                 2010, 35(10): 5133-5144.                          37(12): 2467-2473.
            [2]   BAO W W, XIAO L,  ZHANG J J,  et al. Interface engineering of   [20]  LIU  Y, XU H  X, LIU  H B,  et al.  Active site identification and
                 NiV-LDH@FeOOH heterostructures as high-performance electro-   evaluation criteria of in  situ grown CoTe and NiTe nanoarrays for
                 catalyst for oxygen evolution reaction in alkaline conditions[J].   hydrogen evolution and oxygen evolution  reactions[J]. Small
                 Chemical Communications, 2020, 56(65): 9360-9363.   Methods, 2019, 3(5): 1900113-1900123.
            [3]   MIDILLI A, KUCUK H, TOPAL M E,  et al. A  comprehensive   [21]  LIU T T, LIU Q, ASIRI A M, et al. Amorphous CoSe film behaves as
                 review on hydrogen production from coal gasification: Challenges   an active and stable full water splitting electrocatalyst under strongly
                 and opportunities[J]. International Journal of Hydrogen Energy,   alkaline conditions[J]. Chemical Communications, 2015, 51(93):
                 2021, 46(50): 25385-25412.                        16683-16686.
            [4]   KUMAR G, SHOBANA S, NAGARAJAN D, et al. Biomass based   [22]  GUO Y X, YAO Z Y, SHANG C S, et al. Amorphous Co 2B grown on
                 hydrogen production by dark fermentation-recent trends and   CoSe 2 nanosheets  as a hybrid catalyst for efficient overall water
                 opportunities for greener processes[J]. Current Opinion in   splitting in alkaline medium[J]. ACS Applied Materials & Interfaces
                 Biotechnology, 2018, 50: 136-145.                 A, 2017, 9(45): 39312-39317.
            [5]   ZOU X  Y, WEI X L, BAO W W,  et al. Local electronic structure   [23]  WANG Y, YANG Y T, WANG X,  et al. Electro-synthesized
                 modulation of NiVP@NiFeV-LDH  electrode for high-efficiency   Co(OH) 2@CoSe with Co—OH active site for overall water splitting
                 oxygen evolution  reaction[J]. International Journal of  Hydrogen   electrocatalysis[J]. Nanoscale, 2020, 2: 792-797.
                 Energy, 2021, 46(64): 32385-32393.            [24]  WEI G J, DU K,  ZHAO X  X,  et al. Cable-like carbon  nanotubes
            [6]   ZHANG J, WANG T, POHL D,  et al. Interface engineering  of   decorated  metal-organic framework derived ultrathin CoSe 2/CNTs
                 MoS 2/Ni 3S 2 heterostructures for  highly enhanced electrochemical   nanosheets for electrocatalytic overall water splitting[J]. Chinese
                 overall water splitting activity[J]. Angewandte Chemie International     Chemical Letters, 2020, 31(10): 2641-2644.
   85   86   87   88   89   90   91   92   93   94   95