Page 82 - 《精细化工》2022年第7期

·1368· 精细化工 FINE CHEMICALS 第 39 卷

PAM 水凝胶的平衡溶胀比达到 512.0，具有超吸水 [15] SHAO Y, YANG S G, ZHANG W B. Macromolecular isomerism in
giant molecules[J]. Chemistry-A European Journal, 2020, 26(14):
性。Janus 型 POSS 的引入显著提高了水凝胶的韧性、
2985-2992.
抗压缩性能和动态力学性能，1% AS-POSS/PAA/ [16] SHAO Y, YIN H, WANG X M, et al. Mixed[2 : 6] hetero-arm star
PAM 水凝胶的断裂伸长率达到 1074%，随着 AS- polymers based on Janus POSS with precisely defined arm
distribution[J]. Polymer Chemistry, 2016, 7(13): 2381-2388.
POSS 用量的增加，水凝胶的屈服应变由 330%逐渐 [17] ZHANG W B, YU X F, WANG C L, et al. Molecular nanoparticles
减小到 57%。AS-POSS/PAA/PAM 水凝胶具有良好 are unique elements for macromolecular science: From "nanoatoms"
to giant molecules[J]. Macromolecules, 2014, 47(4): 1221-1239.
的离子导电性能，在柔性传感器、凝胶电解质和生
[18] YU X F, LI Y W, DONG X H, et al. Giant surfactants based on
物电极等领域具有较大应用潜力。 molecular nanoparticles: Precise synthesis and solution self-
assembly[J]. Journal of Polymer Science Part B-Polymer Physics,
参考文献： 2014, 52(20): 1309-1325.
[19] ZHANG W B, CHENG S Z D. Toward rational and modular
[1] PATRYCJA Ż, PIETRASZUK C. Application of olefin metathesis in molecular design in soft matter engineering[J]. Chinese Journal of
the synthesis of functionalized polyhedral oligomeric silsesquioxanes Polymer Science, 2015, 33(6): 797-814.
(POSS) and POSS-containing polymeric materials[J]. Beilstein Journal
[20] ZHANG W A, MULLER A H E. Architecture, self-assembly and
of Organic Chemistry, 2019, 15: 310-332. properties of well-defined hybrid polymers based on polyhedral
[2] DU Y J, LIU H Z. Cage-like silsesquioxanes-based hybrid oligomeric silsequioxane (POSS)[J]. Progress in Polymer Science,
materials[J]. Dalton Transactions, 2020, 49(17): 5396-5405. 2013, 38(8): 1121-1162.
[3] XUE L, LI L G, FENG S Y, et al. A facile route to multifunctional [21] TANAKA K, CHUJO Y. Advanced functional materials based on
cage silsesquioxanes via the photochemical thiol-ene reaction[J]. polyhedral oligomeric silsesquioxane (POSS)[J]. Journal of Materials
Journal of Organometallic Chemistry, 2015, 783: 49-54. Chemistry, 2012, 22(5): 1733-1746.
[4] LI Y W, DONG X H, ZOU Y, et al. Polyhedral oligomeric [22] WANG F K, LU X H, HE C B. Some recent developments of
silsesquioxane meets “click” chemistry: Rational design and facile polyhedral oligomeric silsesquioxane (POSS)-based polymeric
preparation of functional hybrid materials[J]. Polymer, 2017, 125: materials[J]. Journal of Materials Chemistry, 2011, 21(9): 2775-2782.
303-329. [23] ZHANG Y S, KHADEMHOSSEINI A. Advances in engineering
[5] GAO S X, XU K, GUI X F, et al. Synthesis of soluble hydrogels[J]. Science, 2017, 356(6337): eaaf3627.
silsesquioxane-polythiophene hybrid copolymers with a controlled [24] MIN J H, PATEL M, KOH W G. Incorporation of conductive
morphology[J]. ACS Applied Polymer Materials, 2019, 1(3): materials into hydrogels for tissue engineering applications[J].
437-451. Polymers, 2018, 10(10): 1078.
[6] XIA Y, DING S, LIU Y J, et al. Facile synthesis and self-assembly of [25] MAHINROOSTA M, FARSANGI Z J, ALLAHVERDI A, et al.
amphiphilic polyether-octafunctionalized polyhedral oligomeric Hydrogels as intelligent materials: A brief review of synthesis,
silsesquioxane via thiol-ene click reaction[J]. Polymers, 2017, 9(7): 251. properties and applications[J]. Materials Today Chemistry, 2018, 8:
[7] LICKISS P, RATABOUL F. ChemInform abstract: Fully condensed 42-55.
polyhedral oligosilsesquioxanes (POSS): From synthesis to [26] GYLES D A, CASTRO L D, CARRERA S J O, et al. A review of the
application[J]. Advances in Organometallic Chemistry, 2008, 57(21): designs and prominent biomedical advances of natural and synthetic
1-116. hydrogel formulations[J]. European Polymer Journal, 2017, 88:
[8] DE GENNES P G. Soft matter[J]. Science, 1992, 256(5056): 495- 373-392.
497. [27] ZHANG Q, LIU L B, PAN C G, et al. Review of recent achievements
[9] SUN D Y (孙大吟), YE Y L (叶一兰), LIANG F X (梁福鑫), et al. in self-healing conductive materials and their applications[J]. Journal
Some recent advances in Janus particulate emulsifiers[J]. CIESC of Materials Science, 2018, 53(1): 27-46.
Journal (化工学报), 2021, 72(12): 6203-6215. [28] WANG S H (王思恒), YANG X X (杨欣欣), HUANG X J (黄旭娟),
[10] SU Z B, ZHANG R M, YAN X Y, et al. The role of architectural et al. Preparation of anti-freezing hydrogels and its application in
engineering in macromolecular self-assemblies via non-covalent flexible electronics[J]. Fine Chemicals(精细化工), 2021, 38(6):
interactions: A molecular LEGO approach[J]. Progress in Polymer 1081-1091.
Science, 2020, 103: 101230. [29] CORDES D B, LICKISS P D, RATABOUL F. Recent developments
[11] ASUNCION M Z, RONCHI M, ABU-SEIR H, et al. Synthesis, in the chemistry of cubic polyhedral oligosilsesquioxanes[J].
functionalization and properties of incompletely condensed “half Chemical Reviews, 2010, 110(4): 2081-2173.
cube” silsesquioxanes as a potential route to nanoscale Janus [30] SHENG H (盛卉), XUE B (薛斌), QIN M (秦猛), et al. Preparation
particles[J]. Comptes Rendus Chimie, 2010, 13(1): 270-281. and applications of stretchable and tough hydrogels[J]. Chemical
[12] OGURI N, EGAWA Y, TAKEDA N, et al. Janus cube Journal of Chinese Universities (高等学校化学学报), 2020, 41(6):
octasilsesquioxane: Facile synthesis and structure elucidation[J]. 1194-1207.
Angewandte Chemie International Edition, 2016, 55(32): 9336-9339. [31] WANG S H (王思恒), YANG X X (杨欣欣), LIU H (刘鹤), et al.
[13] WANG X M, GUO Q Y, HAN S Y, et al. Stochastic/controlled Research progress in preparation and application of conductive
symmetry breaking of the T-8-POSS cages toward multifunctional hydrogels[J]. Chemical Industry and Engineering Progress (化工进
regioisomeric nanobuilding blocks[J]. Chemistry-A European 展), 2021, 40(5): 2646-2664.
Journal, 2015, 21(43): 15246-15255. [32] WANG P G, PEI D F, WANG Z B, et al. Biocompatible and
[14] HAN S Y, WANG X M, SHAO Y, et al. Janus POSS based on mixed self-healing ionic gel skin as shape-adaptable and skin-adhering
[2 : 6] octakis-adduct regioisomers[J]. Chemistry-A European sensor of human motions[J]. Chemical Engineering Journal, 2020,
Journal, 2016, 22(18): 6397-6403. 398: 125540.