Page 172 - 《精细化工》2023年第4期

g858g ㇫㏳ࡃጒ FINE CHEMICALS す 40 ࢤ

ࡴγڣ⩹䲏㛉⮱ᑧᏓ喑᝭В TAO ⮱Πࡃ㘪߈ᰭᑧ喠 2.3.4 ෋⏣㘪߈
㔹हͧ⻨ၽಸ⮱ TABC Πࡃ㘪߈ࣵ๔λ TAMI喑᭜ 䕇䓴ᐼ喍3喎䃎ツϔ৮෋⏣㘪߈喑჋侹㐀᳉㻮
఍ͧ TABC ⮱㟱ധ㠜⣜➦ᰶ⮱ ʌ-ʌ ҉⩕ [32] ℁ TAMI ఫ 5ȡ⩞ఫ 5 जⴒ喑䲋⻨ၽಸ⮱ TAO ෋⏣㘪߈ͧ
⮱⩟ധᰡ㘪᣽ࡴ⩹䲏㛉⮱ᑧᏓȡ㐀᳉㶕ᬻ喑㮪♣Π 100 mL/mol喑㔹䭠⻨ၽಸ⮱ TABC হ TAMI ⮱෋⏣
⋟Ҁ㈨⮱⩹䲏ᑍ߈̻ڣ☚߈႓⽠ჇᕔₐⰥڠ喑ѳᎣ 㘪߈अ๔喑౴ͧ 125 mL/molȡTABC হ TAMI ⮱෋
̺㘪۠ჇΠࡃ⋟␡⮱⽠Ⴧᕔ喑ᒏ᜽䒰➏ధ⮱⩹䲏㛉喑 ⏣㘪߈䘪๔λ TAO ᰶВ̸࣌఍喟喍1喎गᰶ㶕䲏≨ᕔ
㔹व䔯⮱㶕䲏≨ᕔݯܳၽ㐀Ჱहᵤ᭜ᒞ৺Π⟣⋟⽠ ݯ⮱⊀Ꮣ䊲䓴 CMC ᝺ڤᰶ෋⏣҉⩕ [37] 喑ϻ㶕 1 ज
Ⴧᕔ⮱䛺㺮఍㉍ȡ ⴒ喑TABC হ TAMI ⮱ CMC ࡮ܳᣒ䓾喑ι㔲䘪ᄼλ
TAO喠喍2喎෋⏣㘪߈Όऄ㘣᲌๔ᄼহ⻨ၽധఏ⮱ᒞ
㶕 2 25 Ď̸ TAOȠTABC হ TAMI ⮱㶕䲏≨ᕔ࣯᪝ ৺ [25,38-39] 喑⏣⋟͚喑㶕䲏≨ᕔݯᒏ᜽⮱㘣᲌䊷๔喑
Table 2 Parameters of surface activity of TAO, TABC and
TAMI at 25 Ď ڣڲ⾧䬡Ό䊷๔喑ⰥᏁ⮱෋⏣㘪߈ᅞ䊷ᑧ喑㔹⻨ၽ
ധఏ⩢㢤⮱Ⱕοᢿ᫒҉⩕чព๔ܳၽ͸䬡⮱⾧䬡喑
ᵤ৮ Πࡃ㘪߈/s HLB ⶙Ⅱ͚⮱⽠Ⴧᕔ
ϻ㔹Ҭڣ෋⏣㘪߈෋ᑧ喑TABC ⮱Ҁ⼜๔λ TAO喑
TAO 581.0 10.7 4 ㏔
ᒏ᜽⮱㘣᲌͸䬡⮱⾧䬡Όᰡ๔喑఍㔹ڤᰶᰡ๔⮱෋
TABC 341.7 8.2 5 ㏔
⏣㘪߈喑TAMI ᒏ᜽㘣᲌ऻ喑㘣᲌͸䬡ႅౕ⮱䲆⩢
TAMI 271.0 11.5 5 ㏔
᫒߈ព๔γⰥο͸䬡⮱⾧䬡喑ᰶݖλ᣽倅ڣ෋⏣㘪

2.3.2 HLB ߈喠喍3喎㠜᭜ᄼᲮᕔᰶᱧ➖喑ᒀ㠜䔈ڒ㶕䲏≨ᕔݯ
㶕䲏≨ᕔݯ̷⮱ϟⅡധఏহ⪼Ⅱധఏ͸䬡ᓲ䶨 㘣᲌͚ऻ᣽倅γҀ㈨⮱☚߈႓⽠Ⴧᕔ [40-41] 喑TABC
Ԋᠮ̭ჇᎠ㶎᝺㘪ॵ⣝ܧڣ⠙ᰶ⮱⩹䲏ᕔ㘪喑㔹 ℁ TAO ็γ⪼Ⅱധఏ㟱ധ喑TAMI ℁ TAO ็γ⪼Ⅱ
HLB թजВࣺ᭍䔆⻺Ꭰ㶎⮱⼸Ꮣ [29] ȡᵦᢛᐼ喍1喎 ധఏ⩟ധ喑ϻ㔹ᄩ㜡 TABC হ TAMI ̻㠜ᰡღᭀ㐀
হ喍2喎喑ܳݘ䃎ツᓄݝ TAOȠTABCȠTAMI ⮱ HLB व喑ᒏ᜽⮱Ҁ㈨Όᰡ⽠Ⴧ喑᝭В TABC হ TAMI ⮱
թܳݘ᭜ 10.7Ƞ8.2Ƞ11.5喍㶕 2喎ȡᄦλ TAO হ TAMI喑 ෋⏣㘪߈㺮๔λ TAOȡ
ᵦᢛ㶕䲏≨ᕔݯ HLB թ̻ᕔ䉕⮱ᄦᏁڠ㈨ [17] जⴒ喑
ι㔲ज⩕λ O/W ಸΠࡃݯ喑TABC ⮱ HLB թϸλ
7~9 ͸䬡喑䔯व⩕λ⋓⎬ݯȡ̭㝙ᗲ̸ۢ喑ϟⅡധ
ัλ᱘〜⮱㶕䲏≨ᕔݯ≄ۭ҉⩕ᑧ㔹⋓⎬ᕔጛ喠ϟ
Ⅱധัλ͚䬡݆᭜≄ۭ҉⩕ᑞ㔹⋓⎬ᕔᑧȡTABC
⮱ϟⅡധ͑〜䔋Ɑᑧϟ⇦ധ Į-Ძ⇦☜❴⃢হ㟱ധ❴
⃢喑ᆋλ≄ۭ҉⩕ᑞ㔹⋓⎬ᕔᑧ⮱ᗲۢ喑䔯व⩕λ
⋓⎬ݯ喑ₑ㐀䃧̻ HLB 㐀᳉̭㜡ȡ̶㔲ᄦ℁͸̸喑
TAO হ TAMI ϟⅡᕔສλ TABC喑ࢠ TABC ϟ⇦ᕔ
㺮ສλ TAO হ TAMIȡ䔆᭜఍ͧ TABC ͚⮱㟱ധ᭜
䒰ສ⮱ϟ⇦ധఏ喑ϻ㔹᣽ࡴγڣϟ⇦ᕔȡ
2.3.3 ោ⶙Ⅱ㘪߈
2+
2+
⩞λⅡ͚क़ᰶ⮱ιФ䭠⻨ၽຯ Mg ȠCa ぶч
䭺ѻ㶕䲏≨ᕔݯ⮱ࣨ↎Ƞ⌲∮ぶ᩵⢴ [33-34] ȡᩲ≸䄂
2+
γ㶕䲏≨ᕔݯౕ Ca ⏣⋟͚⮱⽠Ⴧᕔȡ⩞㶕 2 जⴒ喑
TAO ౕ⶙Ⅱ͚⽠Ⴧᕔͧ 4 ㏔喑TABC হ TAMI ͧ 5
㏔喑䄡ᬻϔ৮ڤᰶ㞜ສ⮱ោ⶙Ⅱ㘪߈ȡ̭᫦䲏఍ͧ
2+
TAO ܳၽ̷⮱ O ⮱႑⩢ၽᄦღᭀ̻ Ca ࣾ⩌ᑧ䙺
ఫ 5 ॥ٶᏓ̻㠜क़䛼ڠ㈨喍a喎ࣷ TAOȠTABC হ TAMI
Ѻ҉⩕喑ⰥᏁ⮱㐀व㘪䒰๔喑ϻ㔹ᄩ㜡 TAO ౕ⶙
Ⅱ͚⽠Ⴧᕔ䒰ጛ [35] 喠ओ̭᫦䲏᭜఍ͧ䭠⻨ၽಸ㶕䲏 ⮱෋⏣㘪߈喍b喎
Fig. 5 Relationship between absorbance and benzene
≨ᕔݯ TABC হ TAMI ⏣λⅡऻ喑ܳၽকడчᒏ᜽ content (a) and solubilization capacity (b) of TAO,
2+
⻨ၽᅯ喑䄒⻨ၽᅯ㘪䭺ѻ Ca ̻㶕䲏≨ᕔݯܳၽ⮱ TABC and TAMI

㐀व҉⩕ [36] 喑ϻ㔹Ҭڣౕ⶙Ⅱ⏣⋟͚Ԋᠮ㞜ສ⮱⽠ 2.3.5 ើ㣹ᕔ㘪
Ⴧᕔȡ ើ㣹వ∂जВϻჇᕔ⮱㻿Ꮣ䃱Фᱽ᫆⮱ើ㣹