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第 35 卷第 7 期 精 细 化 工 Vol.35, No.7
201 8 年 7 月 FINE CHEMICALS July 2018

油田化学品与油田添加剂
一种大温差耐温耐盐缓凝剂的合成及性能评价

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张 健 ，彭志刚 ，黄仁果 ，杨朝阳 ，梁壬鑫 ，邹长军
（1. 西南石油大学 化学化工学院，四川 成都 610500；2. 川庆钻探有限责任公司 测井公司，四川 成
都 610051；3. 中国石油天然气股份有限公司 兰州化工研究中心，甘肃 兰州 730060； 4.中海油田服
务股份有限公司油田化学事业部塘沽作业公司，天津 300459）
摘要：以 2-丙烯酰胺基-2-甲基丙磺酸（AMPS）、丙烯酸（AA）、二烯丙基二甲基氯化铵（DMDAAC）为单体，
改性蒙脱土为活性填料合成了一种有机-无机复合型大温差缓凝剂（PMC-180）。利用 FTIR、XRD 和 TG 对产物
进行了结构表征，并对其应用性能进行了评价。结果表明：PMC-180 具有插层剥离复合结构，初始热解温度为
267.27 ℃。含 PMC-180 的水泥浆在 90~180 ℃耐温缓凝性能和抗盐性能良好，初始稠度低于 30 Bc，稠化时间可
调，曲线平稳无“鼓包”等异常现象；含 PMC-180 的 24 h 水泥石低温强度高于 14 MPa，满足长封固段固井要
求。PMC-180 的缓凝机理及大温差适应机理为：PMC-180 通过吸附屏蔽及络合抑制作用延缓 Ca(OH) 2 晶核、晶
体生长；PMC-180 片层间距随温变化及阴阳离子竞争吸附减缓低温过渡吸附，使 PMC-180 具有良好的大温差适
应性。
关键词：长封固段；大温差；耐温耐盐；蒙脱土；缓凝剂；油田化学品
中图分类号：TQ317；TQ172；TE256 文献标识码：A 文章编号：1003-5214 (2018) 07-1240-08

Synthesis and Performance Evaluation of a Temperature Resistance and Salt
Tolerance Retarder for Large Temperature Difference Cementing

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ZHANG Jian , PENG Zhi-gang , HUANG Ren-guo , YANG Zhao-yang ,
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LIANG Ren-xin ,ZOU Chang-jun
（1. College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, Sichuan, China;
2. Logging company,Chuanqing Drilling Engineering Co., Ltd., Chengdu 610500, Sichuan, China; 3. Lanzhou Petrochemical
Research Center, PetroChina Co., Ltd., Lanzhou 730060, Gansu, China; 4. Oilfield Chemicals Division, China Oilfield
Services Ltd., Tianjin 300459, China）
Abstract: A polymer/inorganic composite retarder (PMC-180) was prepared by in-situ intercalated
polymerization method using 2-crylamido-2-methylpropanesulfonic acid (AMPS), acrylic acid (AA) and
diallyl dimethyl ammonium chloride (DMDAAC) as monomers, modified montmorillonite as active
polymerization filler. The as-prepared retarder was characterized by FTIR, XRD and TG. And its application
performance was evaluated. The results showed that PMC-180 had an intercalation and exfoliation
composite structure with an initial pyrolysis temperature of 267.27 ℃. The cement paste containing
PMC-180 exhibited good retarding property, salt tolerance and temperature resistance under 90~180 ℃.
The initial consistency was lower than 30 Bc and the thickening time could be regulated effectively.
Furthermore, the thickening curves of different kinds of cement paste were stable without abnormal
phenomenon such as bulging. The compressive strength of cement stone containing PMC-180 was greater
than 14 MPa at low temperature, which could be applied to long sealing and large temperature range
cementing operation. The retarding mechanism and temperature adaptation mechanism of PMC-180 were
as follows: when PMC-180 was adsorbed on the surface of cement particles, the hydration adsorption and
2+
complexation reaction between PMC-180 and Ca inhibited Ca(OH) 2 crystal nucleus or crystal growth.

收稿日期：2017-06-30; 定用日期：2017-10-12; DOI: 10.13550/j.jxhg.20170527
基金项目：国家“863”计划课题（2012AA091501-003）
作者简介：张 健（1990—），男，博士生。联系人：彭志刚（1976—），博导，教授，E-mail：401817890@qq.com。