Page 21 - 201906
P. 21
第 6 期 钱 涛,等: 梳状改性苯乙烯-马来酸酐共聚物制备与性能 ·1027·
之,润湿性能下降。因此,润湿性大小为 SMA- 科学: 化学), 2016, 46(11): 1242-1248.
IP750>SMA-IP550>SMA-IP400>SMA-IP200。 [4] Zhu Junfeng (朱军峰), Wang Pei (王佩), Zhang Guanghua (张光华),
et al. Preparation and properties of comb-like polycarboxylate
AMPS/MAA/MAAMPEG[J]. Journal of Functional Materials(功能
材料), 2017, 48(5): 5205-5210.
[5] Liu Tingguo (刘廷国), Liu Tianbao (刘天宝), Wang Xin (汪新), et
al. Synthesis of low molecular weight styrene-maleic anhydride
alternating copolymers [J]. Journal of Molecular Science (分子科学
学报), 2017, 33(2): 138-145.
[6] Fu S H, Zhang L P, Tian A L, et al. Preparation of a novel colorant
with branched poly(styrene-alt-maleic anhydride) for textile
printing[J]. Industrial & Engineering Chemistry Research, 2014,
53(24): 10007-10014.
[7] Lindhoud S, Carvalho V, Pronk J, et al. SMA-SH: Modified styrene-
maleic acid copolymer for functionalization of lipid nanodiscs[J].
Biomacromolecules, 2016, 17(4): 1516-1522.
图 10 SMA-IP 在玻璃/空气/水界面的动态接触角随时间 [8] Chen Baofan (陈宝璠). Preparation and properties of polycarboxylate
变化趋势 dispersant of linear ma-aa-mas for ceramics[J]. Bulletin of the
Fig. 10 Dynamic contact angle among glass/air/water of Chinese Ceramic Society (硅酸盐通报), 2014, 33(9): 2223-2229.
SMA-IP samples with time [9] Xu Yan (徐妍), Ma Chao (马超), Feng Jianguo (冯建国), et al.
Adsorption behavior of comb-like polycarboxylic copolymer
hyperdispersants on the surface offlumorph particles[J]. Journal of
3 结论 China Agrochemicals (中国农药), 2017, 13(11): 59-62.
[10] Ran Q P, Qiao M, Liu J P, et al. SMA-g-MPEG comb-like polymer
(1)利用靛红酸酐与聚乙二醇单甲醚 550 反 as a dispersant for Al 2O 3 suspensions[J]. Applied Surface Science,
2012, 258(7): 2447-2453.
应,优化工艺后,在 120 ℃下反应 30 min,得到产
[11] Ran Q P, Liu J P, Miao C W. Impact of molecular size of
率 79.3%的活性支链 IP550,然后使其与 SMA 反应, SMA-g-MPEG comb-like polymer on the dispersion of CaCO 3
在 140 ℃下反应 2 h,得到接枝率 42.5%的梳状改性 suspensions[J]. Colloid & Polymer Science, 2012, 290(5): 435-443.
[12] Xu Cuiling (许翠玲), Fu Shaohai (付少海), Zhang Liping (张丽平),
苯乙烯-马来酸酐共聚物。
et al. Preparation and application of esters of hyperbranched
(2)改性 SMA 的侧链长与其分散、降黏、乳 styrene-maleic anhydride copolymer[J]. Journal of Fine Chemicals
化、润湿性能具有紧密的联系。实验结果表明,带 (精细化工), 2015, 32(3): 321-329.
[13] Lin Shengsen (林圣森), Du Zhiping (杜志平), Wang Wanxu (王万
有适中侧链长的 SMA-IP550 的应用领域更为广泛。
绪), et al. Preparation and properties of comb-like amphiphilic
尤其是在对分散染料的应用方面,质量分数仅为染 polymers[J]. Journal of Fine Chemicals (精细化工), 2011, 28(3):
料的 10%,可将染料粒径分散到 356.1 nm,在染料 232-236.
[14] Li Mei (李梅), Tong Chunhui (仝春晖). Microwave assisted
分散与喷墨印花中应用前景广阔,将在后续的工作
synthesis of N-oxazoline phenyl maleimide[J]. Coal and Chemical
中继续研究。 Industry (煤炭与化工), 2008, 31(6): 50-52.
[15] Zhang G H, Zhu N, Li Y B, et al. Influence of side-chain structure of
参考文献: polycarboxylate dispersant on the performance of coal water
slurry[J]. Fuel Processing Technology, 2017, 161: 1-7.
[1] Yan Xinyan (闫鑫焱), Rao Xiaoping (饶小平), Song Zhanqian (宋湛
[16] Wang G Y, Bai Y Y, Ma X Y, et al. Effects of the PEG length of
谦), et al. Preparation and properties of polyterpene maleic anhydride
polycarboxylate-based terpolymers on their dispersion properties[J].
polyethylene glycol ester polymer surfactant[J]. Chemistry and
Industry of Forest Products (林产化学与工业), 2017, 37(2): 129-134. Journal of Molecular Liquids, 2016, 225: 333-338.
[2] Lu Xianbo (卢先博), Luo Xiang (雒香), Wang Xuechuan (王学川), [17] Gong Hesheng (龚荷生). Determination of amine value of polyamide
et al. Advances in polymer surfactants[J]. China Surfactant Soap and resin by perchloric acid nonaqueous titration[J]. Chemical World (化
Detergent Industries (中国洗涤用品工业), 2016, (8): 87-91. 学世界), 1985, (5): 16-18.
[3] Gui Qifeng (桂奇峰), Zhang Bo (张博), Zhang Shupeng (张树鹏), et [18] Cao K, Wei X X, Li B J, et al. Study of the influence of imidization
al. Application and mechanism analysis of polycarboxylate degree of poly(styrene-co-octadecyl maleimide) as waxy crude oil
dispersant in pesticide suspensions[J]. Scientia Sinica Chimica (中国 flow improvers[J]. Energy & Fuels, 2013, 27(2): 640-645.