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·134· 精细化工 FINE CHEMICALS 第 37 卷
吸附逐渐饱和,等温吸附线达到平衡,25 ℃时,饱 度为 40 mg/L、温度 25 ℃、pH7 的条件下反应 2 h,
和吸附量为 19.98 mg/g,很难继续提高。 Mg-GAC 除铜性能最好,最佳吸附量为 11.66 mg/g。
根据 Langmuir 和 Freundlich 模型对图 6 实验数 (2)利用表面积及孔径分析仪、X 射线衍射分
据进行线性拟合,拟合图及参数分别见图 7、表 4。 析仪、扫描电镜对改性活性炭进行了表征,结果表
明,氢氧化镁成功地负载于活性炭上。活性炭表面
的微观特性被改变,作者制备的改性活性炭较原活
性炭比表面积和总孔容积都有所增加。
(3)Langmuir 模型可以较好地描述改性活性炭
对 Cu(Ⅱ)的吸附,说明该吸附为单层吸附。
参考文献:
[1] Ma Zongyun ( 马宗云 ). Heavy metal wastewater treatment
technology and its research progress[J]. Metallurgy and Materials (冶
金与材料), 2018, 38(3): 59-60.
[2] Han Fei (韩非), Zong Yue (宗悦), Di Song (邸松), et al. Study on
adsorption properties of activated boron nitride for copper ions in
water[J]. New Chemical Materials (化工新型材料), 2018, 34(3):
204-213.
[3] Venugopal B, Luckey T P. Toxicology of non-radioactive heavy
metals and their salts[J]. Environmental Quality & Safety Supplement,
1975, 1(6): 4-73, 104-114.
[4] Zhao Wenbo (赵文波). Review on treatment methods of electroplating
wastewater[J]. Industrial Water Treatment (工业水处理), 1987, 7(3):
7-11.
[5] Su Qiaoqiao (苏俏俏), Chen Xiaojun (陈晓军), Zhou Long (周龙).
Preparation of nano-α-Al 2O 3 powder by chemical precipitation method[J].
Chemical Technology and Development (化工技术与开发), 2017,
46(12): 36-40.
[6] Mirbagheri S A, Hosseini S N. Pilot plant investigation on petrochemical
wastewater treatment for the removal of copper and chromium with
a—Langmuir; b—Freundlich the objective of reuse[J]. Desalination, 2005, 171(1): 85-93.
[7] Lei Zhaowu (雷兆武), Sun Ying (孙颖). Application of ion exchange
图 7 Mg-GAC 吸附 Cu(Ⅱ)的 Langmuir 和 Freundlich 等
technology in the treatment of heavy metal wastewater[J].
温线 Environmental Science and Management (环境科学与管理), 2008,
Fig. 7 Langmuir and Freundlich isotherms of Mg-GAC for 33(10): 30-31.
adsorption of Cu(Ⅱ) [8] Lai Fei (赖飞), Liu Tong (刘彤), Zhao Hongjiang (赵洪江), et al.
Research status and development prospect of bio-remediation law of
soil mercury pollution[J]. Guangdong Chemical Industry (广东化
表 4 不同温度下吸附等温方程拟合参数 工), 2014, 41(6): 123-124.
Table 4 Adsorption parameters of adsorption isotherm equations [9] Yang Si′e (杨四娥), Lin Jianqing (林建清). Research progress on
at different temperatures modification technology and application of activated carbon[J].
Anhui Agricultural Sciences (安徽农业科学), 2014, 42(9): 2712-
Langmuir 型等温线 Freundlich 型等温线
温度/℃ 2715.
2
q m/(mg/g) K L R 2 q m/(mg/g) K F R [10] Guo Yaping (郭亚萍). Study on electrolytic adsorption of chloroform
25 22.94 0.1918 0.9927 5.124 0.4128 0.8870 in water by activated carbon[D]. Changchun:Northeast Normal
University (东北师范大学), 2002.
35 26.09 0.2051 0.9966 5.819 0.4300 0.9143 [11] Liang Xia (梁霞), Wang Xuejiang (王学江). Activated carbon
45 28.25 0.2785 0.9899 7.502 0.4027 0.8927 modification method and its application in water treatment[J]. Water
Treatment Technology (水处理技术), 2011, 37(8): 1-6.
由表 4 可见,Langmuir 等温线模型比 Freundlich [12] Attia A A, Rashwan W E, Khedr S A. Capacity of activated carbon in
the removal of acid dyes subsequent to its thermal treatment[J]. Dyes
等温线模型有更好的拟合效果,能更好地描述 Mg- & Pigments, 2006, 69(3): 128-136.
GAC 对 Cu(Ⅱ)的吸附,说明 Cu(Ⅱ)吸附在了改性活 [13] Du Haoming (杜皓明), Ou Zhiyang (欧志阳). Research progress on
the application of green water treatment agent magnesium
性炭的表面,并发生了单层吸附。 hydroxide[J]. Guangdong Chemical Industry (广东化工), 2007,
34(8): 45-47.
3 结论 [14] Li Y, Gao B, Wu T, et al. Hexavalent chromium removal from
aqueous solution by adsorption on aluminum magnesium mixed
hydroxide[J]. Water Research, 2009, 43(12): 3067-3075.
作者综合氢氧化镁和活性炭在水处理方面的优 [15] Gray-Munro J E, Strong M. A study on the interfacial chemistry of
点,采用反应结晶技术制备了复合材料 Mg-GAC, magnesium hydroxide surfaces in aqueous phosphate solutions:
-
2+
influence of Ca , Cl and protein[J]. Journal of Colloid & Interface
减少了能源消耗,制备过程简化。 Science, 2013, 393(393): 421-428.
(1)在 Mg-GAC 投加量为 0.3 g、Cu(Ⅱ)质量浓 (下转第 146 页)