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·42· 精细化工 FINE CHEMICALS 第 38 卷
表 5 高温离子聚集阻燃 PET 的改性结果
Table 5 Results of the flame retarding PET prepared by high-temperature ion aggregation
2
2
2
2
单体 添加量/% η/(dL/g) T g/℃ T m/℃ LOI/% UL-94 PHRR/(kW/m ) THR/(MJ/m ) TSR/(m /m ) 熔滴
DHPPO-Na [50] 10 0.63 69 — 31.0±0.5 — 240~276 40~46 392~452 无
DHPPO-K [51] 10 0.57 — — 33 — 203 49 — 无
SHPPP [52] 10 0.519 71.4 226 27 — — — — 改善
2 结论与展望 Journal of Applied Polymer Science, 2019, 136(28): 47758.
[9] FANG Y C, LIU X H, TAO X C. Intumescent flame retardant and
anti-dripping of PET fabrics through layer-by-layer assembly of
PET 共聚阻燃改性方法优点突出,具有很好的 chitosan and ammonium polyphosphate[J]. Progress in Organic
应用前景。虽然磷系共聚阻燃剂具有较好的阻燃性 Coatings, 2019, 134: 162-168.
[10] WANG D Y, WANG Y Z, WANG J S, et al. Thermal oxidative
能以及良好的安全性能,其实验研究和工业化应用
degradation behaviours of flame-retardant copolyesters containing
较为成熟,但是其造成 PET 聚酯抗熔滴性能下降等 phosphorous linked pendent group/montmorillonite nanocomposites[J].
问题。因此,实现 PET 聚酯阻燃抗熔滴成为研究热 Polymer Degradation and Stability, 2005, 87(1): 171-176.
[11] WANG D Y, GE X G, WANG Y Z, et al. A novel phosphorus-
点之一。纳米等抗熔滴改善阻燃剂,虽然一定程度 containing poly(ethylene terephthalate) nanocomposite with both
上改善了 PET 的熔滴性能,但过多种类的添加剂增 flame retardancy and anti-dripping effects[J]. Macromolecular Materials
加了 PET 制备工艺的复杂性以及对 PET 优良性能的 and Engineering, 2006, 291(6): 638-645.
[12] SALMEIA K A, GOONEIE A, SIMONETTI P, et al. Comprehensive
损耗。高温交联、高温重排、高温离子聚集以及高 study on flame retardant polyesters from phosphorus additives[J].
温端基捕获链扩展等方法能有效改善 PET 聚酯的阻 Polymer Degradation and Stability, 2018, 155: 22-34.
[13] VELENCOSO M M, BATTIG A, MARKWART J C, et al. Molecular
燃和抗熔滴性能,为新型环保型阻燃抗熔滴 PET 聚
firefighting how modern phosphorus chemistry can help solve the
酯的制备提供了较好的研究思路。相比而言,高温 challenge of flame retardancy[J]. Angew Chem Int Ed Engl, 2018,
交联和高温端基捕获扩链改性方法可以实现 UL-94 57(33): 10450-10467.
[14] SONG Y H, XUE B X, WANG J, et al. Ammonium polyphosphate
的 V-0 级,显示更好的抗熔滴性能,而高温重排和 wrapped carbon microspheres: A novel flame retardant with smoke
高温离子聚集法尚无法通过 UL-94 的 V-0 级。高温 suppression for poly(ethylene terephthalate)[J]. Journal of Polymer
交联改性 PET 聚酯的共聚阻燃单体添加量较小且综 Research, 2019, 27(1): doi.org/10.1007/s10965-019-1972-5.
[15] XIA J R, SU Y M, LI W M. Post-polymerization functionalization to
合性能更加突出。通过对文献的总结和分析,作者 a novel phosphorus- and nitrogen-containing polyether coating for
认为设计合成阻燃效率高,抗熔滴性能优异的智能 flame retardant treatment of PET fabric[J]. Journal of Applied
Polymer Science, 2019, 136(16): 47299.
交联阻燃抗熔滴单体,降低共聚阻燃单体的生产成 [16] LEWIN M. Unsolved problems and unanswered questions in flame
本是共聚阻燃改性 PET 聚酯的研究和应用的主要发 retardance of polymers[J]. Polymer Degradation and Stability, 2005,
展方向。 88(1): 13-19.
[17] ZHANG J (张杰), QIAO H (乔辉), DING J (丁筠), et al. Research
参考文献: progress of PET flame retardant composites[J]. Engineering Plastics
Application (工程塑料应用), 2017, 45(5): 140-144.
[1] YANG H (杨慧), DING P (丁鹏), SHI L Y (施利毅), et al. Progress [18] ZHAI G X (翟功勋), PAN W N (潘伟楠), ZHOU J L (周家良), et al.
in research of halogen-free flame retardant for PET engineering Research progress of phosphorus-containing binary hybrid synergistic
plastics[J]. Shanghai Plastics (上海塑料), 2008, (1): 1-4. flame retardant modified polyethylene terephthalate (PET)[J]. Chinese
[2] JIANG Z L (江振林). Flame retardant and anti-dropping modification of Polymer Bulletin (高分子通报), 2019, (1): 75-82.
polyester fiber and fabric[D]. Shanghai:Donghua University (东华大 [19] LEVCHIK S V, WEIL E D. Flame retardancy of thermoplastic
学), 2017. polyesters:A review of the recent literature[J]. Polymer International,
[3] XIAO L, SUN D C, NIU T L, et al. Syntheses of two dopo-based 2005, 54(1): 11-35.
reactive additives as flame retardants and co-curing agents for epoxy [20] WENDELS S, CHAVEZ T, BONNET M, et al. Recent developments
resins[J]. Phosphorus, Sulfur, and Silicon and the Related Elements, in organophosphorus flame retardants containing P-C bond and their
2014, 189(10): 1564-1571. applications[J]. Materials, 2017, 10(7): 1-32.
[4] PENG Y, NIU M, QIN R H, et al. Study on flame retardancy and [21] YAO Z Y, LIU X X, QIAN L J, et al. Synthesis and characterization
smoke suppression of PET by the synergy between Fe 2O 3 and new of aluminum 2-carboxyethyl-phenyl-phosphinate and its flame-retardant
phosphorus-containing silicone flame retardant[J]. High Performance application in polyester[J]. Polymers, 2019, 11(12): 11121969.
Polymers, 2020, 32(8):871-882. [22] PHAM C T, NGUYEN B T, PHAN H T Q, et al. Highly efficient fire
[5] YANG Y R, NIU M, DAI J M, et al. Flame-retarded polyethylene retardant behavior, thermal stability, and physicomechanical properties
terephthalate with carbon microspheres/magnesium hydroxide compound of rigid polyurethane foam based on recycled poly(ethylene
flame retardant[J]. Fire and Materials, 2018, 42(7): 794-804. terephthalate)[J]. Journal of Applied Polymer Science, 2020, 137(37):
[6] ADNER D, HELMY M, OTTO T, et al. A macromolecular halogen- doi.org/10.1002/app.49110.
free flame retardant and its effect on the properties of thermoplastic [23] ZHAO H B, WANG Y Z. Design and synthesis of PET-based
polyesters[J]. Fire and Materials, 2019, 43(2): 1-6. copolyesters with flame-retardant and antidripping performance[J].
[7] LIANG Q Q (梁倩倩), LIU M (刘敏), DONG L (董林), et al. Macromol Rapid Commun, 2017, 38(23): 201700451.
Research progress of electrospinning ultrafine phase change fibers [24] ZHANG Q (张强). Synthesis, characterization and flame retardant
[J]. Synthetic Fiber in China (合成纤维), 2019, 48(8): 4-6. mechanism of novel copolyester containing phosphorus linked pendant
[8] CHENG J J, LI S X, ZHANG F, et al. Effects of the recycled groups[D]. Wuhan: Wuhan Textile University (武汉科技学院), 2007.
poly(ethylene terephthalate) fibers on the rigid polyurethane foam[J]. [25] ZHAO H, WANG Y Z, WANG D Y, et al. Kinetics of thermal