Page 97 - 《精细化工》2021年第3期
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第 3 期 朱建新,等: 有机氟接枝改性含硅水性聚氨酯的制备及性能 ·517·
C—C 键的键能,FSWPU 胶膜在受热时,分解所需 2020, 37(9): 1799-1805.
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要的温度较高,因此提高了胶膜的热稳定性。
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表 2 不同 FIPDIT 含量 FSWPU 胶膜热失重数据 of desulfurized gypsum by novel modification of silicone oil paraffin
Table 2 TGA data of the FSWPU films with different contents composite emulsion-based waterproofing agent[J]. Journal of the
of FIPDIT Korean Ceramic Society, 2019, 56(6): 558-565.
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样品 T 10%/℃ T 30%/℃ T 50%/℃
ammonium and polyether groups for silyl-terminated polypropylene
FSWPU-0 279 304 324
oxide waterborne emulsions[J]. Journal of Surfactants and Detergents,
FSWPU-1 290 317 337 2016,19(4): 739-745.
FSWPU-5 302 329 350 [8] HOU P K, LI R, LI H T, et al. The use of hydrophobicity and
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(1)FTIR、 HNMR 分析表明,成功合成了 2019, 494(1): 610-618.
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FIPDIT;胶膜 FTIR 的分析表明,成功制备了 FSWPU
fluorinated non-isocyanate polyurethanes coatings with good hydrophobic
胶膜。 and oleophobic properties[J]. Journal of Coatings Technology and
(2)粒径、耐酸碱性、稳定性测试表明,当 Research, 2019, 16(5): 1233-1241.
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FIPDIT 含量为 5%时,粒径为 168 nm,胶膜的耐酸
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碱性显著提高;当 FIPDIT 含量为 7%时,乳液呈乳 Coatings, 2019, 131(1): 291-300.
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(3)当 FIPDIT 含量为 5%时,吸水率低至 9.7%, Coatings, 2010, 69(1): 63-72.
接触角为 113.5°,拉伸强度为 26.7 MPa,断裂伸长 [15] HSU Y T, WANG W H, HUNG W H. Evaluating the properties of a
coating material with polycaprolactone-degradable fluorinated silicon-
率为 328%,而 T 10% 、T 30% 、T 50% 分别为 302、329、
containing waterborne polyurethane[J]. Sustainability, 2020, 12(9): 1-15.
350 ℃。FSWPU 胶膜的耐水性能、力学性能和热稳 [16] LAHIOUHEL D, AMEDURI B, BOUTEVIN B. A telechelic fluorinated
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