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·1044· 精细化工 FINE CHEMICALS 第 38 卷

MS-NZVI/SP，催化水中 EBT 的类芬顿降解。红外 141809.
光谱测试出现的 O—H，C==C 和 C—O—C 的吸收 [10] HE X F (何新凤). Study on the degradation of methyl orange dye
wastewater by heterogeneous Fenton method[D]. Xi'an: Shaanxi
峰说明绿色合成的方法会在材料表面覆盖一层多酚 Normal University (陕西师范大学), 2011.
0
有机层，减缓 Fe 的氧化，使其具有稳定性。SP 的 [11] XUE C, PENG Y M, CHEN A W, et al. Drastically inhibited
NZVI-Fenton oxidation of organic pollutants by cysteine: Multiple
主要成分为方解石型 CaCO 3 ，NZVI 呈球状，均匀
roles in the NZVI/O 2/hv system[J]. Journal of Colloid and Interface
负载在 SP 上，有效解决了团聚问题，材料具有重复 Science, 2021, 582(15): 22-29.
使用性。MS-NZVI/SP 催化降解 50 mg/L EBT 的优 [12] GOPAL G, SANKAR H, NATARAJAN C K, et al. Tetracycline
removal using green synthesized bimetallic NZVI-Cu and bentonite
化条件为：NZVI 与 SP 负载质量比 1∶1，温度 35 ℃， supported green NZVI-Cu nanocomposite: A comparative study[J].
溶液 pH 为 3，投加 4 mL H 2 O 2 （质量分数 5%），100 mg Journal of Environmental Management, 2020, 254(15): 109812.
MS-NZVI/SP，在此条件下，反应 120 min 后降解率 [13] ZHOU L L, LI R R, ZHANG G L, et al. Zero-valent iron
nanoparticles supported by functionalized waste rock wool for
可达 93.01%。动力学结果说明，MS-NZVI/SP 类芬 efficient removal of hexavalent chromium[J]. Chemical Engineering
顿降解 EBT 的反应可用准二级反应过程描述。 Journal, 2018, 339(1): 85-96.
[14] ZHANG D J, LI Y, SUN A W, et al. Enhanced nitrobenzene
未来的研究可进一步探索对海南特色资源的利
reduction by modified biochar supported sulfidated nano zerovalent
用，比如用不同的水果皮制备生物炭，作为载体负 iron: Comparison of surface modification methods[J]. Science of The
载 NZVI，并探究其对不同有机污染物的类芬顿降解 Total Environment, 2019, 694(1): 133701.
[15] WANG T, LIN J J, CHEN Z L, et al. Green synthesized iron
效果，以达到废弃资源更高效的利用。
nanoparticles by green tea and eucalyptus leaves extracts used for
removal of nitrate in aqueous solution[J]. Journal of Cleaner
参考文献： Production, 2014, 83(15): 413-419.
[1] VAHID J B, RAZIEH S F. Preparation and performance of [16] HUANG W Y (黄文烨). Extraction and characterization of pectin
alginate/basil seed mucilage biocomposite for removal of Eriochrome and phenolics from mangos teen rind[D]. Guangzhou: Jinan
Black T dye from aqueous solution[J]. International Journal of University (暨南大学), 2016.
Biological Macromolecules, 2020, 152(1): 990-1001. [17] WANG Z (王征), TONG Z (仝壮), WANG Y S (王燕诗), et al. The
2+
[2] GANESAN S, UTHAPPA U T, RICHELLE M R, et al. Ceria adsorption of Pb on water by four shell powders[J]. Journal of
decorated porous diatom-xerogel as an effective adsorbent for the Jiangxi Normal University (江西师范大学学报), 2019, 43(1): 84-89.
efficient removal of Eriochrome Black T[J]. Chemosphere, 2020, [18] ZHU F, MA S Y, LIU T, et al. Green synthesis of nano zero-valent
238(1): 124692. iron/Cu by green tea to remove hexavalent chromium from
[3] SUN J H, SHI S H, LEE Y F, et al. Fenton oxidative decolorization groundwater[J]. Journal of Cleaner Production, 2018, 174(10):
of the azo dye Direct Blue 15 in aqueous solution[J]. Chemical 184-190.
Engineering Journal, 2009, 115(3): 680-683. [19] FAZLZADEH M, RAHMANI K, ZAREI A, et al. A novel green
[4] JONG H P, JIM J W, NEGAR T, et al. Removal of Eriochrome Black synthesis of zero valent iron nanoparticles (NZVI) using three plant
T by sulfate radical generated from Fe-impregnated biochar/ extracts and their efficient application for removal of Cr(Ⅵ) from
persulfate in Fenton-like reaction[J]. Journal of Industrial and aqueous solutions[J]. Advanced Powder Technology, 2017, 28(1):
Engineering Chemistry, 2019, 71(25): 201-209. 122-130.
[5] ZHANG Y J (张饮江), XIANG Y Q (相元泉), LU X (鲁仙). [20] XIAO C Y, LI H Y, Z Y, et al. Green synthesis of iron nanoparticle by
Characteristics on the Eriochrome Black T (EBT) degradation in tea extract (polyphenols) and its selective removal of cationic dyes[J].
aquatics by Fe/persulfate system[J]. China Environmental Science Journal of Environmental Management, 2020, 275(1): 111262.
(中国环境科学), 2020, 40(2): 635-660. [21] HUANG C (黄超), YU B (余兵), LI R C (李任超), et al.
[6] SOBHAN M D, SAHAR Z A, MASOUD S N. Facile hydrothermal Combination of reduction and heterogeneous Fenton oxidation for
and novel preparation of nanostructured Ho 2O 3 for photodegradation removal of 2, 4-DCP from aqueous solution using organobentonite-
of Eriochrome Black T dye as water pollutant[J]. Advanced Powder nanoscale zerovalent iron[J]. Chinese Journal of Environmental
Technology, 2017, 28(3): 747-754. Engineering (环境工程学报), 2015, 9(8): 3643-3649.
[7] HAO L P, GAO W Y, YAN S, et al. Functionalized diatomite/oyster [22] WANG J Y (王嘉瑜), PU S Y (蒲生彦), HOU G Q (侯国庆). Green
shell powder doped electrospun polyacrylonitrile submicron fiber as synthesis of NZVI using plant extracts for treatment of hexavalent
a high-efficiency adsorbent for removing methylene blue from chromium in groundwater[J]. Chinese Journal of Environmental
aqueous solution: Thermodynamics, kinetics and isotherms[J]. Engineering (环境工程学报), 2020, 14(9): 2537-2547.
Journal of Molecular Liquids, 2020, 298(15): 112022. [23] ZHU Y C (朱永昌), LI J F (李剑锋), LIU Y J (刘妍君), et al.
[8] DONADELLI J A, CARAM B, KALABOKA M, et al. Mechanisms Fenton-like oxidation of phenol in water by green synthetic iron
of 4-phenylazophenol elimination in micro- and nano-ZVI assisted- nanoparticles[J]. Technology of Water Treatment (水处理技术),
Fenton systems[J]. Journal of Environmental Chemical Engineering, 2019, 45(5): 63-67.
2020, 8(1): 103624. [24] BAO Y X (暴雅娴), HUA Z Z (华兆哲), LI X F (李秀芬), et al.
[9] LIANG D H, LI N, AN J K, et al. Fenton-based technologies as Kinetic study on the degradation of methyl orange by Fenton
efficient advanced oxidation processes for microcystin-LR oxidation[J]. Water Resources Protection (水资源保护), 2007, 95(2):
degradation[J]. Science of The Total Environment, 2021, 753(20): 84-87.