Page 140 - 《精细化工》2023年第4期

g826g ㇫㏳ࡃጒ FINE CHEMICALS す 40 ࢤ

2.1.4 ᕨႁ䯆⢴ܳᲽ ϻఫ 5 ज㻮喑PEG/GO/TiO 2 ㏠ㆠฺवᱽ᫆⮱⌨
ఫ 4 ͧ PVDF 㛉হ PEG/GO/TiO 2 /PVDF ⮱ᕨႁ ߍᬻ᭫᣽倅γ PEG/GO/TiO 2 /PVDF ⮱ HA ᝗⪆⢴喑
䯆⢴ȡ ᒀ PEG/GO/TiO 2 ㏠ㆠฺवᱽ᫆䉕䛼ܳ᪝ͧ 0.60%

ᬣ喑0.60% PEG/GO/TiO 2 /PVDF ڤᰶᰭҠ⮱ HA ᝗⪆
⢴喑ͧ 96.8%喑℁ PVDF 㛉෋ߍ 7.7%ȡ
ఫ6ͧPVDF㛉হPEG/GO/TiO 2/PVDF⮱㛉䕇䛼ȡ

ఫ 4 PVDF 㛉হ PEG/GO/TiO 2 /PVDF ⮱ᕨႁ䯆⢴
Fig. 4 Total porosity of PVDF membrane and PEG/GO/
TiO 2 /PVDF

ϻఫ 4 ज㻮喑ᒀ PEG/GO/TiO 2 ㏠ㆠฺवᱽ᫆䉕
䛼ܳ᪝ϻ 0 ෋㜠 0.60%ᬣ喑ฺव䊲␑㛉⮱ᕨႁ䯆⢴౴ ఫ 6 PVDF 㛉হ PEG/GO/TiO 2 /PVDF ⮱㛉䕇䛼
Fig. 6 Membrane flux of PVDF membrane and PEG/GO/
෋๔ȡᄳڤᰶϟⅡᕔ⮱ PEG/GO/TiO 2 ㏠ㆠฺवᱽ᫆ᣧ TiO 2 /PVDF
ڒ PVDF 䨥㛉⋟͚ज᭫㦄ߍᔘ䲋⏣ݯহ⏣ݯᱽ᫆͸
䬡⮱э䉕䕌⢴喍Ⅱᰡᔘౝព᪐ݝ⋟ᔮ㖇व➖㛉͚喎喑 ϻఫ 6 ज㻮喑̻ PVDF 㛉Ⱕ℁喑PEG/GO/TiO 2 /
हᬣ෋ᑧ Į Ⱕ⮱ᒏ᜽হ PVDF ⮱ᬍჇᒏᕔ䉕喑PVDF PVDF ⮱ J w ȠJ p হ J r ̻ᕨႁ䯆⢴হ HA ᝗⪆⢴౴ॵ
⩞λᬍ∂ۼ䒨⮱Ꮑ߈হᒏ᜽⮱᫚㷯◦㔹ϔ⩌ᑞ◦喑 ٵ෋ߍऻ䭺ѻ⮱䊸߬ȡᒀ PEG/GO/TiO 2 ㏠ㆠฺवᱽ
ᰭ㏵ᒏ᜽ႁ䯆喑఍ₑӰ䔈γ㛉ႁ⮱ᒏ᜽হ᣽倅γ㛉⮱ ᫆䉕䛼ܳ᪝ͧ 0.60%ᬣ喑0.60% PEG/GO/TiO 2 /PVDF
2
ᕨႁ䯆⢴ [43] ȡᒀ PEG/GO/TiO 2 ㏠ㆠฺवᱽ᫆䉕䛼ܳ᪝ 㛉䕇䛼䓫ݝᰭ๔喑ڣ͚ J w ͧ 282.44 L/(m ·h)ȠJ p ͧ
2
2
ͧ 0.60%ᬣ喑0.60% PEG/GO/TiO 2/PVDF 䓫ݝᰭ๔⮱ 131.96 L/(m ·h)ȠJ r ͧ 194.98 L/(m ·h)喑ܳݘͧ PVDF
2
2
2
ᕨႁ䯆⢴喑ͧ 85.57%喑℁ PVDF 㛉෋ߍ 13.40%ȡ♣ 㛉Ȳ133.80 L/(m ·h)Ƞ90.50 L/(m ·h)Ƞ109.57 L/(m ·h)ȳ
㔹喑PEG/GO/TiO 2 䉕䛼ܳ᪝䒰ᄾᬣᄦ㛉⮱ᩦᕔ᩵᳉Ꭳ ⮱ 2.1 ԺȠ1.5 Ժহ 1.8 Ժȡ̻ᑍᔄьぶ [29] 䕇䓴ⱌ⾧䓴
̺᭫㦄喑㔹ᒀ䉕䛼ܳ᪝>0.60%ᬣ喑ᄳ䭺ѻฺव䊲␑㛉 ␑∂ݣิ⮱ GT ฺ व㛉Ⱕ℁喑᱙ጒ㞧ݣิ⮱
2
⮱ᕨႁ䯆⢴ȡ䔆⻺⣝䆎ᑿ఍λⰥ䒙ࡃ䓴⼸͚ PEG/GO/TiO 2/PVDF ⮱ J w ෋ߍ 217.14 L/(m ·h)喑J r ෋
2
PEG/GO/TiO 2 ㏠ㆠฺवᱽ᫆⮱㖇䯳෋ߍγ䨥㛉⋟⮱叼 ߍ 136.40 L/(m ·h)ȡ఍ₑ喑PEG/GO/TiO 2 ㏠ㆠฺव
ᏓᎣ䭺ѻγฺव䊲␑㛉⮱ᕨႁ䯆⢴ȡ఍ₑ喑ᄦ PVDF ᱽ᫆䉕䛼ܳ᪝ͧ 0.60%ᬣ㘪᭫㦄喍P<0.05喎ᩦ઱
㛉䔈㵹ᩦᕔᬣ喑ᄨⅯᰭҠ⮱ PEG/GO/TiO 2 ㏠ㆠฺवᱽ PVDF 㛉⮱㛉䕇䛼ȡ᪝ᢛ㶕ᬻ喑ᒀ PEG/GO/TiO 2 ㏠
᫆䉕䛼ܳ᪝᭜᣽倅 PEG/GO/TiO 2/PVDF ᕔ㘪⮱ڠ䩛ȡ ㆠฺवᱽ᫆䉕䛼ܳ᪝ͧ 0.60%ᬣ喑ᬍ䃧᭜㛉⮱᝗⪆
2.2 ฺव䊲␑㛉⮱㛉䕇䛼ࣷ᝗⪆ᕔ㘪ܳᲽ ᕔ㘪䔅᭜㛉⮱⍄䔼ᕔ㘪౴㶕⣝ᰭҠȡ䔆᭜఍ͧ喑̭
ఫ 5 ͧ PVDF 㛉হ PEG/GO/TiO 2 /PVDF ⮱ HA ᫦䲏喑㛉ϟⅡᕔ⮱෋ᑧजВ॥ᑂ㛉ധ䉕ڲ⮱Ⅱܳၽ喑
᝗⪆⢴ȡ 䔈㔹Ӱ䔈Ⅱܳၽ⍄䔼䓴㛉喠ओ̭᫦䲏喑PEG/GO/TiO 2
㏠ㆠฺवᱽ᫆⮱ϟⅡᕔजВ෋ᑧⰥ䒙ࡃ䓴⼸͚⮱⏣
ݯহ䲋⏣ݯϑᢏ喑ᎣҬ㛉ڤᰶᰡ็⮱็ႁ㶕䲏ȡ
PEG/GO/TiO 2 䉕䛼ܳ᪝䓴็ᝃ䓴ᄾ౴ᄦ㛉ϔ⩌
̺ݖᒞ৺ȡҸຯ喟ᒀ PEG/GO/TiO 2 ㏠ㆠฺवᱽ᫆䉕
䛼ܳ᪝>0.60%ᬣ喑ᄦ HA ᝗⪆⢴হ㛉䕇䛼౴⪒ᰶ̸
䭺喑䔆ज㘪̻㏠ㆠㆿၽ⮱ఏ㖇হϔ⩌๔Ⱑᒱ⮱ႁᰶ
ڠȡₑใ喑䮼Ɑ PEG/GO/TiO 2 ㏠ㆠฺवᱽ᫆䉕䛼ܳ
᪝⮱෋ߍ喑䨥㛉⋟⮱叼Ꮣ෋ߍ喑倅⊀Ꮣቹڒ㏠ㆠᲬ
⮱ႁ䭨උ喑ϻ㔹䭺ѻγ᪡Ҁႁ䯆Ꮣ喑ᄩ㜡㛉⮱⍄䔼

⢴䭺ѻ喑㛉䕇䛼̸䭺ȡᅪノౕ჋侹͚ࣾ⣝ϟⅡᕔധ
ఫ 5 PVDF 㛉হ PEG/GO/TiO 2 /PVDF ⮱ HA ᝗⪆⢴
Fig. 5 HA rejection rate of PVDF membrane and PEG/GO/ ఏ⮱➦ᒮም䔼䓴⢴Ƞᣒ㼓㻿Ƞᕨႁ䯆⢴Ƞ᝗⪆⢴Ƞ
TiO 2 /PVDF 㛉䕇䛼䬡ज㘪ႅౕₐⰥڠڠ㈨喑ѳ̻ PEG/GO/TiO 2