Page 47 - 201807
P. 47
第 7 期 李玉峰,等: 无皂苯胺/硅丙共聚乳液的制备及其防腐蚀性能 ·1115·
结合接枝在丙烯酸酯聚合物链上,且共聚乳液粒子 [11] Li Yufeng (李玉峰), Tong Liping (童丽萍), Zhu Jingjing (祝晶晶).
呈明显的核壳结构。该共聚乳液可以直接在 Q235 Study on preparation and anticorrosion properties of aniline/siliane-
acrylate copolymer emulsion [J]. New Chemical Materials (化工新
钢表面刷涂成膜。电化学测试结果表明,当共聚温 型材料), 2015, 43(3): 38-40.
度为 20 ℃反应 6 h、80 ℃反应 2 h,n(H 2O 2): n(Ani) = [12] Zhou J H, Chen X, Ma J Z. Synthesis of cationic fluorinated
2.5∶1 时,制得的共聚乳胶涂层对 Q235 钢具有优异 polyacrylate copolymer by RAFT emulsifier-free emulsion
polymerization and its application as waterborne textile finishing
7
2
的防腐蚀性能,电化学阻抗值达到 9.03×10 Ω·cm , agent[J]. Dyes and Pigments, 2017: 139(4): 102-109.
–8
2
腐蚀电流密度仅为 5.04×10 A/cm 。本文研制的共 [13] Varakirkkulchai P, Parakul S K, Prasassarakich P. Polyaniline/
聚乳胶涂层在金属腐蚀防护领域具有良好的应用前 polyacrylate core–shell composites: Preparation, morphology and
anticorrosive properties [J]. Progress in Organic Coatings, 2015, 85:
景。下一步要进一步优化无皂苯胺/硅丙共聚乳液的 84–91.
合成工艺,并深入研究其构效关系,在分子水平上 [14] National technical committee on paints & pigments of
充分发挥 PANI 和硅丙乳液的协同作用,实现对金 standardization administration of China. GB/T 9286-1998 Paints and
varnishes — Cross cut test for films(色漆和清漆漆膜的划格试验)
属更有效的防护。
[S]. Beijing: Standards Press of China, 1998 (in Chinese).
[15] National technical committee on paints & pigments of
参考文献: standardization administration of China. GB/T 6742-2007 Paints and
[1] Spinks G M, Dominis A J, Wallace G G, et al. Electroactive varnishes — Bend test : Cylindrical mandrel(色漆和清漆弯曲试验:
conducting polymers for corrosion control [J]. Journal of Solid State 圆柱轴) [S]. Beijing: Standards Press of China, 2007 (in Chinese).
Electrochemistry, 2002, 6(2): 85-100. [16] National technical committee on paints & pigments of standardization
[2] Ćirić-Marjanović G. Recent advances in polyaniline research: administration of China. GB/T 1732-1993 Paints and varnishes —
Polymerization mechanisms, structural aspects, properties and Determination of impact resistance of film (漆膜耐冲击测定方
applications [J]. Synthetic Metals, 2013, 177: 1-47. 法)[S]. Beijing: Standards Press of China, 1993 (in Chinese).
[3] Ates M. A review on conducting polymer coatings for corrosion [17] Xu X K, Shi Y C, Sun L B. Synthesis and characterization of
protection [J]. Journal of Adhesion Science and Technology, 2016, poly(methylmethacrylate–butyl acrylate–acrylic acid)/polyaniline
30(14): 1510-1536. core–shell nanoparticles in miniemulsion media [J]. Journal of
[4] Tian Z F, Yu H J, Li W, et al. Recent progress in the preparation of Applied Polymer Science, 2012, 123(3): 1401-1406.
polyaniline nanostructures and their applications in anticorrosive [18] Konwer S, Barthakur L J, Dolui S K. Synthesis of graphite
coatings [J]. Royal Society of Chemistry, 2014, 4: 28195-28208. incorporated core–shell composite of styrene-methylacrylate/
[5] Zhong Fachun (钟发春), Sun Yi (孙毅), Xu Tao (徐涛), et al. polyaniline by surfactant free mini-emulsion polymerization and
Preparation and application of polyaniline/polyacrylates composites evaluation of their electrical property[J]. Journal of Materials
[C]. Proceedings of Journal of Functional Materials (功能材料论文 Science. Materials in Electronics, 2012, 23: 837-845.
集), 2010: 299-303. [19] Nan Junyi (南军义), Lin Weiwei (林薇薇), Tian Yonghui (田永辉).
[6] Yang F, Zhu A P. Preparation and characterization of polyaniline-poly Synthesis of polyaniline doped by polymeric acid using core-shell
(styrene- acrylate) composite latexes [J]. Polymer Bulletin, 2015, 72: emulsion polymerization [J]. Journal of Functional Polymers (功能
2503-2518. 高分子学报), 2000, 13(3): 297-300.
[7] Ge Chengyue (戈成岳). Study of composite methods for polyaniline’s [20] Liu Lan (刘兰), Zhong Fachun (钟发春), Wang Xiaochuan (王晓川),
application and its anti-corrosion properties [D]. Beijing: Graduate et al. Synthesis and characterization of PANI/PMMA composites
School of the Chinese Academy of Sciences(中国科学院大学), prepared by in-situ emulsion polymerization [J].Chemical Industry
2011. and Engineering Progess (化工进展), 2008, 27(8): 1230-1233.
[8] Li Yufeng (李玉峰), Wang Di (王迪), Tong Liping (童丽萍), et al. [21] Lin K Y, Hu L W, Chen K L, et al. Characterization of
Preparation of acrylate-aniline copolymerization emulsion and its polyaniline synthesized from chemical oxidative polymerization at
anticorrosion properties [J]. Journal of Functional Polymers (功能高 various polymerization temperatures [J]. European Polymer Journal,
分子学报), 2013, 26(3): 55-60. 2017, 88(7): 311-319.
[9] Yang Fan (杨番), Wang Zhu (王柱), Liu Haifeng (刘海峰), et al. [22] Pan Zhen (潘珍), Qiu Ye (邱野), Meng Yong (孟勇), et al. Study on
Preparation and application of new acrylate latex water repellent green synthesis of polyaniline by ferrous sulfate and hydrogen
modified with organic silicon[J]. Fine Chemicals (精细化工), 2016, peroxide system [J]. Fine Chemical Intermediates (精细化工中间
33(6): 686-692. 体), 2014, 44(6): 67-71.
[10] Zhang Xinya (张心亚), Sun Zhijuan (孙志娟), Huang Hong (黄洪), [23] Li Yufeng (李玉峰), Tong Liping (童丽萍), Zhu Jingjing (祝晶晶).
et al. Sythesis and properties of organosiloxane modified vinyl Study on preparation and anticorrosion properties of aniline/silane-
acetate/acrylate copolymer emulsion[J]. Fine Chemicals (精细化工), acrylate copolymer emulsion [J]. New Chemical Materials (化工新
2005, 22(8): 634-637. 型材料), 2015, 43(3): 38-40.