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第 35 卷第 9 期 精 细 化 工 Vol.35, No.9
201 8 年 9 月 FINE CHEMICALS Sept. 2018

功能材料
聚醚硅氧烷/聚半硅氧烷双重改性

蓖麻油基水性聚氨酯

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葛硕硕 ，张萍波 ，蒋平平 ，唐敏艳 ，俞晓琴 ，包燕敏 ，高学文
〔1. 江南大学 化学与材料工程学院，江苏 无锡 214122；2. 昆山嘉利普制版胶粘剂油墨有限公司，江
苏 昆山 215300；3. 嘉合实业（苏州）有限公司，江苏 苏州 215021〕
摘要：以蓖麻油与端羟基聚醚改性聚二甲氧基硅氧烷（PEPSO）互混作为多元醇原料，制备出植物油基水性聚
氨酯，将不同用量的四羟基八苯基双层笼型倍半硅氧烷（DDSQ-4OH）引入到其中，制备出系列 PEPSO/
DDSQ-4OH 复合改性聚氨酯纳米复合材料（WPU-15、WPU-15-2、WPU-15-4、WPU-15-6、WPU-15-8）。利用
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FTIR、 HNMR、TGA、SEM、TEM 和粒径分析仪对 DDSQ-4OH 及 PEPSO/DDSQ-4OH 进行了结构表征与性能
测试，并探讨了 DDSQ-4OH 对聚氨酯材料热稳定性、表面疏水性及力学性能的影响。TGA 结果表明，与不含
DDSQ-4OH 的聚氨酯材料相比，当 DDSQ-4OH6 用量为 8%（以扩链剂乙二胺物质的量为基准，下同）时，复
合材料的初始降解温度（T 5% ）提高了 22.5 ℃；静态接触角、扫描电镜测试结果表明，随 DDSQ-4OH 用量的增
加，粒子间出现团聚现象，但仍能均匀分散于水性聚氨酯基体中，材料表面的疏水性增大，样品 WPU-15-6 的
静态接触角达到 90.4；拉伸测试结果表明，DDSQ-4OH 的引入能在一定程度上提高材料的拉伸强度，由 WPU-15
的 9.7 MPa 增至 WPU-15-6 的 16.0 MPa。
关键词：聚醚硅氧烷二元醇；四羟基八苯基双层笼型倍半硅氧烷；植物油基水性聚氨酯；复合材料；功能材料
中图分类号：TQ323.8 文献标识码：A 文章编号：1003-5214 (2018) 09-1504-08

Castor Oil Based Waterborne Polyurethane Doubly Modified
Polyether Modified by Polysiloxane and Double-decker

Octaphenylsilsesquioxanetetraol

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GE Shuo-shuo , ZHANG Ping-bo , JIANG Ping-ping , TANG Min-yan ,
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YU Xiao-qin , BAO Yan-min , GAO Xue-wen
（1. School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, Jiangsu, China; 2. Kunshan Jialipu
Making-plate Adhesive Ink Co., Ltd., Kunshan 215300, Jiangsu, China; 3. Jiahe Industrial (Suzhou) Co., Ltd., Suzhou 215021,
Jiangsu, China）
Abstract: Plant oil-based waterborne polyurethanes were synthesized from castor oil and hydroxyl-
terminated polyether modified polysiloxane (PEPSO). During the synthesis of prepolymer, different amount
of double-decker octaphenylsilsesquioxanetetraol (DDSQ-4OH) was introduced into the waterborne
polyurethane main chains, which led to a series of PEPSO/DDSQ-4OH modified waterborne polyurethane
nanocomposites with different amount of DDSQ-4OH (WPU-15, WPU-15-2, WPU-15-4, WPU-15-6 and
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WPU-15-8). FTIR, HNMR, TGA, SEM, TEM and particle size analyzer were used to characterize these
materials. The influence of nano-particle DDSQ-4OH on the thermal stability, hydrophobicity and
mechanical properties of polyurethane materials was discussed. TGA results showed that the initial
decomposition temperature (T 5%) of the composite containing 8% (based on mole of the chain extender
ethylenediamine, as the below) DDSQ-4OH increased by 22.5 ℃ compared with WPU which didn't
contain DDSQ-4OH. Static contact angle test and SEM results revealed that when the DDSQ-4OH amount
increased, the hydrophobicity of the obtained polyurethanes was improved, and the static contact angle of

收稿日期：2017-08-05; 定用日期：2018-05-29; DOI: 10.13550/j.jxhg.20170635
基金项目：江苏省产学研联合创新资金项目（BY2014023-08）
作者简介：葛硕硕（1993—），男，硕士生。联系人：张萍波（1981—），副教授，硕士生导师，E-mail：pingbozhang@126.com。