Page 149 - 精细化工2019年第10期

第 10 期 陈利维，等: 碱溶解玉米淀粉制备高吸水性树脂 ·2115·

脂结构更稳定。 2017, 27(4): 15-18.
[11] Xing Chuanbo (刑传波). The preparation and modification of
AA-based superabsorbent resin[D]. Jinan: Shandong University (山
3 结论 东大学), 2008.
[12] Li Tingxi (李廷希）, Chen Quanliang（陈泉良）, Wei Meng (魏萌),
（1）碱溶解淀粉通过水溶液聚合法以玉米淀粉 et al. Synthesis of starch graft water superabsorbent resin[J].
Chemical Propellants and Polymeric Materials (化学推进剂与高分
为接枝骨架、丙烯酸为接枝单体、MBA 为交联剂， 子材料), 2012, 10(6): 58-74.
在引发剂 APS 的作用下制备出淀粉基高吸水性树 [13] Liu Tingguo (刘廷国), Li Bin (李斌), Zhu Kunkun (朱坤坤), et al.
Preparation and properties of chitin-based superabsorbent polymers
脂，通过 FTIR 分析表明聚丙烯酸分子链成功接枝
under homogeneous conditions[J]. Acta Polymerica Sinica (高分子
到玉米淀粉上。 学报), 2013, (7): 915-921.
[14] Lu Aixia (陆爱霞), Luo Yang (罗杨), Yan Yong (严勇). Preparation
（2）采用单因素实验法探究出制备的优化参数
of superabsorbent based on maize starch by microwave irradiation[J].
为丙烯酸与玉米淀粉质量比为 3∶1、丙烯酸中和度 Food and Machinery (食品与机械), 2010, 26(5): 33-35.
[15] Shu Jing (舒静), Ren Lili (任丽丽), Zhang Tiezhen (张铁珍), et al.
为 50%、APS 用量 0.8%、MBA 用量 1.00%，由此制
Microwave-irradiated preparation of superabsorbent resin by graft
备的 SSPA 1 吸水倍率（464 g/g）和吸盐水（0.1 mol/L copolymerization of starch and acrylic acid[J]. Journal of Microwaves (微
波学报), 2009, 25(5): 92-96.
NaCl）倍率（34 g/g）相比于高温糊化淀粉制备的
[16] Xie Xinling (谢新玲), Zhao Qiuju (赵秋菊), Zhang Youquan (张友
SSAP 有所提高。 全), et al. Preparation and property of mechanical activated starch
（3）通过 XRD、SEM 和接枝率的分析发现， grefted acrylic acid superabsorbent[J]. New Chemical Materials (化
工新型材料), 2015, 43(6): 48-50.
碱溶解能有效破坏淀粉结晶结构，获得更均匀的淀 [17] He Longqiang (贺龙强), Hu Peng (胡鹏), Liu Zhongyang (刘中阳).
粉溶液利于反应充分进行，提高反应效率，故能有 Preparation and characterization of salt–resistance super absorbent
resin by graft copolymerization of starch and acrylic acid series[J].
效提高树脂吸水/盐水倍率。通过对比 SSAP 1 与 New Chemical Materials (化工新型材料), 2015, 43(8): 96-98.
SSAP 的应用性能表明，SSAP 1 的吸水速率更快、重 [18] Fang S X, Wang G J, Li P C, et al. Synthesis of chitosan derivative
graft acrylic acid superabsorbent polymers and its application as
复吸水性能更优。本工艺为淀粉基高吸水性树脂的 water retaining agent[J]. International Journal of Biological
制备提供了新思路，不仅简化了制备过程，降低成 Macromolecules, 2018, 115: 754-761.
[19] Zhang D B. Microwave-irradiated preparation of super absorbent
本，且对高吸水性树脂的可持续发展起一定推动作用。 resin by graft copolymerization of starch and acrylic acid[J].
Advanced Materials Research, 2011, 291/292/293/294: 1335-1338.
参考文献： [20] Wang R J, Yang L W, Zhang H H, et al. Synthesis of super absorbent
resin from starch/bentonite[J]. Advanced Materials Research, 2013,
[1] Qiu Haiyan (邱海燕), Xue Songsong (薛松松), Zhang Hongjie (张 873: 708-712.
洪杰 ), et al. Synthesis and properties of CMC-g-P (AM-co- [21] Liang Xingtang (梁兴唐), Liu Zijie (刘子杰), Deng Qin (邓勤), et
NaAMC14S) superabsorbent resin[J]. Fine Chemicals (精细化工), al. Fast synthesis of starch based composite superabsorbent polymer
2018, 35(9): 1069-1614, 1620.
[2] Choudhary M S. Inverse suspension polymerization of partially by microwave method and its swelling properties[J]. Fine Chemicals
(精细化工), 2014, 31(2): 157-162.
neutralized and lightly cross-linked acrylic acid effect of reaction
parameters[J]. Macromolecular Symposia, 2009, 277(1): 171-176. [22] Liu T G, Wang Y T, Guo J, et al. One-step synthesis of corn starch
[3] Raju M P, Raju K M. Design and synthesis of superabsorbent urea based acrylate superabsorbents[J]. Journal of Applied Polymer
polymers[J]. Journal of Applied Polymer Science, 2001, 80(14): Science, 2017, 134: 45175.
2635-2639. [23] Xu Z, Fei Q Z, Zhang X Y. Synthesis of the starch grafting of
[4] Liu Yugui (刘玉贵), Zhang Jin (张瑾), Zhu Zhongqi (朱忠其), et al. superabsorbent and high oil-absorbing resin[J]. Journal of
Preparation and properties of acrylic acid and acrylamide Environmental Sciences, 2013, 25: S97-S100.
superabsorbent copolymer[J]. Functional Materials (功 能材料), [24] Nie Ming (聂明). Study on synthesis and modification application
2013, 44(2): 157-160. of starch superabsorbent resin[D]. Chongqing: Chongqing University
[5] Liu T G, Qian L W,Li J, et al. Homogeneous synthesis of chitin-based (重庆大学), 2004.
acrylate superabsorbents in NaOH/urea solution[J]. Carbohydrate [25] Thakur S, Arotiba A O. Synthesis, swelling and adsorption studies of
Polymers, 2013, 94(1): 261-271. a pH-responsive sodium alginate-poly(acrylic acid) superabsorbent
2+
[6] Zheng Y A, Hua S B, Wang A Q. Adsorption behavior of Cu from hydrogel[J]. Polymer Bulletin, 2018, 75: 4587-4606.
aqueous solutions onto starch-g-poly (acrylic acid)/sodium humate [26] Shen Shiqi (沈仕奇), Zhu Zhifeng (祝志峰). Effect of amphoteric
hydrogels[J]. Desalination, 2010, 263: 170-175. grafting modification on the property of starch film[J]. New
[7] Abdel-Halim E S, Al-Deyab S S. Preparation of poly(acrylic Chemical Materials (化工新型材料), 2015, 43(9): 172-174.
acid)/starch hydrogel and its application for cadmium ion removal [27] Amin M C I M, Ahmad N, Halib N, et al. Synthesis and characterization
from aqueous solutions[J]. Reactive and Functional Polymers, 2014, of thermo- and pH-responsive bacterial cellulose/acrylic acid hydrogels
75: 1-8. for drug delivery[J]. Carbohydrate Polymers, 2012, 88: 465-473.
[8] Bai C, Zhang S F, Huang L, et al. Starch-based hydrogel loading with [28] Witono J R, Noordergraaf I W, Heeres H J, et al. Water absorption,
carbendazim for controlled-release and water absorption[J]. retention and the swelling characteristics of cassava starch grafted
Carbohydrate Polymers, 2015, 125: 376-383. with polyacrylic acid[J]. Carbohydrate Polymers, 2014, 103: 325-332.
[9] Hu Qiang (胡强), Meng Yuecheng (孟岳成).A review on the [29] Fu Songtao (符嵩涛), Li Zhenyu (李振宇). Research progress on
gelatinization of rice starch and aging[J]. Food Research and superabsorbent resin[J]. Plastics Science and Technology (塑料科
Development (食品研究与开发), 2004, 25(5): 63-66. 技), 2010, 38(10): 106-133.
[10] Liu Han (刘涵), Dang Xugang (党旭岗), Yang Piao (杨飘), et al. [30] Chen Zhanyun (陈展云). The synthesis of the super absorbent resin
Research on the solubility of corn starch by alkaline-urea with cassava starch graft acrylic acid and its application[D].
treatment[J]. Leather Science and Engineering (皮革科学与工程), Nanning: Guangxi University (广西大学), 2008.