Page 208 - 《精细化工》2020年第1期
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·194·                             精细化工   FINE CHEMICALS                                  第 37 卷

                                                               净浆流动度实验表明,端羟基双子季铵盐以同掺和
                                                               先掺的复配方式均可以显著提高含 3%蒙脱土水泥
                                                               浆体的流动度且复配稳定性较好。XRD、XPS 和 Zeta
                                                               电位实验表明,端羟基双子季铵盐可以通过静电引
                                                               力和氢键作用优先吸附在蒙脱土的表面和层间,减
                                                               少蒙脱土对 PCE 的吸附,使得体系中更多的减水剂
                                                               作用于水泥,保证 PCE 分散特性,起到抗泥作用。
                                                               PCE 复配端羟基双子季铵盐可改善蒙脱土对 PCE 的
                                                               负面影响,为改善蒙脱土对 PCE 的负面影响提供了

                                                               新的研究思路,具有广阔的应用前景。
             图 9    减水剂浓度对水泥和蒙脱土表面 Zeta 电位的影响
            Fig. 9    Effect of superplasticizers concentration on the Zeta   参考文献:
                   potential of cement and MMT
                                                               [1]   Sakai  E,  Ishida  A,  Ohta  A.  New  trends  in  the  development  of
                 图 10 为 PCE 与不同质量浓度抗泥剂复配对水                          chemical  admixtures  in  Japan[J].  Journal  of  Advanced  Concrete
                                                                    Technology, 2006, 4(2), 211-223.
            泥和蒙脱土 Zeta 电位的影响,主要考察在复配体系                         [2]   Shi Caijun (史才军), He Fuqiang (何富强), Liu Hui (刘慧) et al.
                                                                    Recent  progresses  in  the  development  of  PC  super-plasticizer[J].
            中 PCE 和抗泥剂在蒙脱土上的竞争吸附。由图可知,                              Commercial Concrete Journal (商品混凝土), 2010, 12(2): 20-23, 33.
                                                               [3]   Wang  Ziming  (王子明),  Wu  Hao  (吴昊),  Xu  Ying  (徐莹)  et al.
            随着抗泥剂浓度的升高,水泥的电位变化不明显,而                                 Inhibitory effect of clay on application performance of polycarboxylate
                                                                    water  reducer[J].  Journal  of  Building  Materials  (建筑材料学报),
            蒙脱土表面的电位呈先上升后趋于不变的趋势。复                                  2014, 17(2): 234-238.
            配有 KNJ-2 的溶液中,蒙脱土的 Zeta 电位从初始的                     [4]   Ng S, Plank J. Interaction mechanisms between Na montmorillonite
                                                                    clay and MPEG-based polycarboxylate suerplasticizers[J]. Cement
            –22.58  mV 上升到–0.15  mV,这表明当体系中同时                       & Concrete Research, 2012, 42(6): 847-854.
                                                               [5]   Shao  Qiang  (邵强),  Sun  Shenmei  (孙申美),  Lin  Chun  (林春).
            存在阴离子的减水剂和阳离子的抗泥剂时,蒙脱土                                  Preparation and investigation of one anti-clay type polycarboxylate
                                                                    superplasticizer  modified  with  cyclodextrin  and  styrene  [J].  New
            优先吸附相对分子质量小带正电的双子季铵盐。双                                  Building Materials (新型建筑材料), 2016, 43(10): 9-12.
                                                               [6]   Wang Zhi (王智), Kao Youzhe (考友哲), Wang Linlong (王林龙) et
            子季铵盐浓度越高,吸附到蒙脱土表面的阳离子越多,                                al. Effect and mechanism of single mineral clay on dispersibility of
            双电层紧密层中的阳离子的数量也相应地增加,从而有                                polycarboxylic acid water reducer [J].Journal of Building Materials
                                                                    (建筑材料学报), 2015, 18(5): 879-887.
            效地补偿了表面电荷,使动电电位升得更快。当吸附反                           [7]   Liao Guosheng (廖国胜), He Zhenglian (何正恋), Liu Pei (刘佩).
                                                                    Study  on  the  adsorption performance  of  clay  mineral  components
            应达到平衡时,双电子层将会被压缩到溶剂化层叠合,                                on polycarboxylic acid water reducer[J].Silicate Bulletin (硅酸盐通
                                                                    报), 2015, 34(1): 227-231.
            其表现为蒙脱土表面电荷趋于一个定值。这是由于低                            [8]   Li Y, Zheng X, Wu K, et al. Synthesis of amphiphilic polycarboxylate
            分子量的 KNJ-2 分子间距小使其排布更加紧密,产生                             copolymer and its notable dispersion and ad-sorption characteristics
                                                                    onto  cement  and  clay[J].  Advances  in  Cement  Research,  2016,
            了更强的亲水效果,使得抗泥剂在蒙脱土上吸附更快,                                28(5), 344-353.
                                                               [9]   Zhu Hongjiao (朱红姣), Zhang Guanghua (张光华), Wang Ziru (王
            紧密层与扩散层的距离缩小得更快,表现为蒙脱土表面                                子儒). Polythylene glycol and mechanism with the suppression of
                                                                    montmorillonite effect on polycarboxlate superpiasticzer[J]. Journal
            电荷快速增加,这样就使得蒙脱土表面的活性位点                                  of Shannxi University of Science and Technology (陕西科技大学
                                                                    学报), 2016, 34(6), 110-116.
            更多地被双子季铵盐占据,表面对 PCE 的吸附减少。                         [10]  Lei L,  Plank  J. Synthesis and  properties  of a vinyl ether-based
                                                                    polycarboxylate  superplasticizer  for  concrete  possessing  clay
                                                                    tolerance[J]. Industrial Engineering Chemistry Research, 2014, 53:
                                                                    1048-1055.
                                                               [11]  Chen Youzhi (陈友治), Zhang Mai (张迈). Inhibitory mechanism of
                                                                    sulfonated  lignin  on  adsorption  behavior  of  montmorillonite
                                                                    towards polycarb[J]. Journal of the Chinese Ceramic Society (硅酸
                                                                    盐学报), 2017, 46(2): 202-207.
                                                               [12]  Wang Fanggang (王方刚), Lu Jiayue (陆加越), Liu Jianzhong (刘建忠),
                                                                    et al. Improvement of adaptability of poly-carboxylate super plasticizer
                                                                    to montmorillonite by anti-clay agent and its mechanism[J]. Journal
                                                                    of Building Materials (建筑材料学报), 2017, 20(4): 556-562.
                                                               [13]  Zhang Weihui (张卫辉), Wang Chunhua (王春华), Lin Wei (林炜).
                                                                    Synthesis of biodegradable gemini quaternary ammonium salt and
                                                                    its antimicrobial activity[J]. China Leather (中国皮革), 2017, 46(6):
                                                                    28-34.
                                                               [14]  Zhou  Mingsong  (周明松),  Qiu  Xueqing  (邱学青),  Yang  Dongjie
                                                                    (杨东杰). Adsorption properties of lignin and naphthalene dispersants
                                                                    on coal-water interface [J]. Chemical Journal of Chinese Universities
                图 10    双子季铵盐用量对水泥 Zeta 电位的影响                       (高等学校化学学报), 2008, 29(5): 987-992.
            Fig.  10    Effect  of  of  anti-clay  agent  concentration  on  the   [15]  Borchardt J K.Enhancerecovery and production stimulation[J]. ACS
                    Zeta potential of cement and MMT                Symposium Series, 1989, 10: 204-210.
                                                               [16]  Arya C, Newmen J B. An assessment of four methods of determining
                                                                    the free chloride[J]. Materials and Struc-ture, 1990, (23): 481-485.
                                                               [17]  Wang  Shanshan  (王珊珊),  Zhang  Jian  (张健),  Zhu  Yuejun  (朱玥
            3   结论                                                  珺),  et al.  Reducing  polymer  adsorption  by  using  low  molecular
                                                                    weight  surfactant  as  sacrificial  agent[J].  Chemical  Research  and
                                                                    Application (化学研究与应用), 2017, 29(7): 974-979.
                 合成了两种具有不同端基的双子季铵盐,将其                          [18]  Xing G B, Wang W P, Xu J. Grafting tertiary amine groups into the
                                                                    molecular  structures  of  polycarboxylate  super  plasticizers  lowers
            作为抗泥牺牲剂来改善蒙脱土对 PCE 的负面影响。                               their clay sensitivity[J]. RSC Advances, 2016, 6(108): 106921-106927.
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