Page 32 - 《精细化工》2020年第3期

·450· 精细化工 FINE CHEMICALS 第 37 卷

4 总结与展望 reaction properties[J]. Dalton Transactions, 2017, 46(10): 3295-3302.
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该文总结了近年来国内外关于钒酸镍（Ni 3V 2O 8、 heterogeneous growth of macroporous CoV 2O 6 nanosheet for
NiV 3 O 8 等）材料的合成方法、晶体结构性质及作为 high-rate pseudocapacitive lithium-ion battery anode[J]. ACS applied
锂离子电池负极材料应用的研究进展。重点讨论了 materials & interfaces, 2016, 8(11): 7139-7146.
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改善钒酸镍电化学性能的几种方法。电极材料微纳
multilayered nanosheets: controllable synthesis, excellent Li-storage
米化、复合化、表面包覆等方法都可以在一定程度
properties, and investigation of electrochemical mechanism[J]. ACS
上改善钒酸镍材料的电化学性能。但钒酸镍的制备 Nano, 2014, 8(5): 4474-4487.
多在水溶液中制备，方法比较单一，开发新型溶剂 [11] NI S, MA J, LV X, et al. The preparation of NiV 3O 8/Ni composite via
（比如离子液体等）或其他先进制备方法对于钒酸 an in situ corrosion method and its use as a new sort of anode
镍的应用发展具有重要意义。到目前为止，关于 material for Li-ion batteries[J]. Journal of Materials Chemistry A,
2014, 2(24): 8995-8998.
Ni 3 V 2 O 8 等作为锂离子电池负极材料的报道还不多，
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对于 Ni 3 V 2 O 8 等纳米材料组成、结构与储锂性能之
of atomic thickness: excellent Li-storage properties and investigation
间的构效关系及机理需要进一步深入研究。从实际 of their electrochemical mechanism[J]. Journal of Materials Chemistry
应用的角度考虑，钒酸镍材料成本低廉，具有较好 A, 2016, 4(28): 10974-10985.
的应用潜力，但钒酸镍纳米材料的大规模工业生产 [13] LI M L, GAO Y, CHEN N, et al. Cu 3V 2O 8 Nanoparticles as
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成工艺（比如，以沉淀法合成性能参数优异的钒酸
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镍，并与碳材料复合）是钒酸镍材料能够广泛应用
chemically lithiated NaV 3O 8: a positive electrode material for use in
的基础。目前，关于将 Ni 3 V 2 O 8 作为锂离子电池负 rechargeable lithium-Ion batteries[J]. Journal of The Electrochemical
极材料用在全电池方面的报道极少，下一步应加强 Society, 1998, 145(2): 421-427.
其应用在全电池中的性能研究，促进 Ni 3 V 2 O 8 材料 [15] GAN L H, DENG D, ZHANG Y, et al. Zn 3V 2O 8 hexagon nanosheets:
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