Page 196 - 《精细化工》2020年第9期

·1910· 精细化工 FINE CHEMICALS 第 37 卷

从图 9 可看出，空白革样表面粗糙、板结，纤 [7] WANG X C (王学川), ZHANG M R (张铭让). Synthesis of phosphate
维之间黏结严重，纤维分散性差；经 LCF-P2 与市 ester and its application in leather fatliquor[J]. Leather Science and
Engineering (皮革科学与工程), 2002, 12(1): 24-26.
售加脂剂加脂处理后，革胶原纤维束排列较为规整， [8] PYKA P, VOLLNHALS B, POMREHN B. Phosphoric esters as
胶原纤维编织更加疏松，纤维间距增大。这是因为， extreme pressure additives: US6103675[P]. 2000-08-15.
[9] WANG X C, GUO X X, WANG H J, et al. Effect of linear-
磷酸酯键具有很强的金属络合性，可与纤维上的三
hyperbranched amphiphilic phosphate esters on collagen fibers[J].
价铬离子络合，且氧化磷酸酯加脂剂在纤维之间有 Journal of Agricultural and Food Chemistry, 2017, 65(1): 104-116.
良好的填充作用，从而可以使纤维分子间距变大， [10] LAN Y J (兰云军). The preparation of leather chemicals—Theory
and practice[M]. Beijing: China Light Industry Press (中国轻工业出
分子链间距超出了氢键与范德华力的作用力程，使 版社), 2001.
纤维之间的松散程度增加。 [11] SHI B (石碧), LU Z B (陆忠兵). Cleaner production technology of
leather making[M]. Beijing: Chemical Industry Press (化学工业出版
3 结论 社), 2004.
[12] ZHANG H T (张华涛). Present situation and prospect of China's oil
and chemical industry[J]. China Oils and Fats (中国油脂), 2010,
本文以一种新的氧化-磷酸酯化两步法对亚麻
35(9): 9-12.
油进行改性，制得 3 种加脂剂样品。随环氧化程度 [13] PENG W L (彭文利), WAN P B (万蓬勃), ZHANG X (张雄), et al.
的提高，自制加脂剂乳液稳定性增强，加脂后皮革 Research on the application of agile manufacturing in leather
production[J]. China Leather (中国皮革), 2003, 52(16): 121-123.
的柔软度及机械强度先增加后减小。 [14] LI F Y (李伏益), SHI L W (史立文), XU K H (徐坤华), et al.
加脂剂 LCF-P2 加脂后坯革的综合性能最好， Synthesis and properties of a novel light leather fatliquor[J]. China
2
加脂后皮革柔软度达10 mm，抗张强度为35.91 N/mm ， Leather (中国皮革), 2018, 47(9): 8-15.
[15] DAI Z (戴震), LI L (李莉), ZHANG H L (张海龙), et al. Research
撕裂强度为 49.56 N/mm，增厚率为 24.36%，在皮革 status of water-based polyurethane modified by vegetable oil[J].
增厚率、机械强度提高方面略优于市售加脂剂。 China Coatings (中国涂料), 2009, 24(2): 16-18, 35.
将亚麻油经氧化及磷酸酯化改性用作皮革加脂 [16] LI P (李萍), XU Y L (许艳玲), SHANG Z Q (尚志强). Optimization
and characterization of epoxy linseed oil plasticizer[J]. Journal of
剂，是一类新型结合型自氧化交联的加脂剂，特别 Tianjin Agricultural College (天津农学院学报), 2016, 23(1): 38-42.
适合于浅色革的加脂和柔软处理，具有良好的市场 [17] National Rubber and Rubber Products Standardization Technical
Committee Chemical Auxiliary Sub-Technical Committee. Determinating
前景。
the epoxy value of plasticizers: GB/T 1677—2008[S]. Beijing: China
Standard Press (中国标准出版社), 2008.
参考文献：
[18] LUO X M (罗晓民), DING S L (丁绍兰), ZHOU Q F (周庆芳).
[1] SAHU B, RATHINAM A, JAVID M A, et al. Preparation of fatliquor Physical and chemical analysis of leather[M]. Beijing: China Light
having antifungal activity using the oil of Citrullus colocynthis for Industry Press (中国轻工业出版社), 2013: 304-315.
application in leather processing[J]. Industrial Crops and Products, [19] KE Z H (柯振华), LUO H Y (罗海英). Application of scanning
2017, 108: 553-557. electron microscope and X-ray energy spectrometer in leather
[2] TANG Y F (汤亚芳), ZHANG J H (张钧涵), WANG J Y (王菊英), identification[J]. Western Leather (西部皮革), 2012, 34(6): 23-26.
et al. Study on organosilicon modified castor oil leather fatliquor[J]. [20] ZHONG M X (钟鸣翔), GE Z (葛赞), KANG P (康鹏), et al.
Fine Petrochemical (精细石油化工), 2018, 35(2): 55-57. Synthesis and performance of low quality lard leather fatliquor[J].
[3] DU J X, SHI L, PENG B Y. Amphiphilic acrylate copolymer Leather & Chemical Industry (皮革与化工), 2017, 34(4): 24-27, 34.
fatliquor for ecological leather: Influence of molecular weight on [21] CHEN Z G (陈占光), WANG Q E (王巧娥). Discussion on the
perormances[J]. Journal of Applied Polymer Science, 2016, 133(20): emulsification stability of fatliquors[J]. Leather Science and Engineering
43440. (皮革科学与工程), 2001, 11(1): 18-22, 41.
[4] CHEN M S (陈梦思), QIANG X H (强西怀), GUO Z N (郭灼能), et [22] ZHOU J J (周俊娇), ZHANG H (张辉), QIANG X H (强西怀), et
al. Preparation and application of amphoteric phosphate ester al. Preparation and fatliquing performance of fatty alcohol
fatliquor based on FTE[J]. China Leather (中国皮革), 2019, 48(4): polyoxyethylene ether gemini phosphate[J]. China Leather (中国皮
24-29, 35. 革), 2019, 48(4): 7-13.
[5] ZHANG Z C (张宗才), LIU C B (刘赤斌). Synthesis and application [23] WEI Z B (魏竹波). Multifunctional component of leather fatliquor
of phosphate fatliquor[J]. Fine Chemicals (精细化工), 1995, 12(4): [J]. Fine Chemicals (精细化工), 1991, 8(6): 32-36.
11-14. [24] WANG X C (王学川), HAO D Y (郝东艳), LI J (李季), et al.
[6] RAJARAMAN M P, SWAMY M P, BANGARUSWAMY S, et al. Preparation and application of linear hyperbranched phosphate ester
Studies on free and fixed fatty matter in leather[J]. Leather Science, polymer composite fatliquor[J]. Leather Science and Engineering (皮
1982, 29(4): 123-127. 革科学与工程), 2019, 29(5): 10-15.