Page 56 - 《精细化工》2020年第2期

·258· 精细化工 FINE CHEMICALS 第 38 卷

结构和官能团功能化等能够提高传感层和酸性气体 production of metal organic frameworks (MOF) for CO 2
的相互作用和特定选择性，能够改善 MOFs 的导电 adsorption[J]. Science of the Total Environment, 2020, 707: 135090.
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性，利用其导电性和中空结构等可以大大提高传感 frameworks: Syntheses, structures and improved gas storage and
器对气体的传感性能。目前，基于 MOFs 的化学电 separation properties[J]. Coordination Chemistry Reviews, 2019,
378: 2-16.
阻传感器对酸性气体的研究还比较少。对酸性气体
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研究的方向主要是单一 MOFs、MOFs 的合成后修饰 stimuli-responsive systems for drug delivery[J]. Advanced Science,
和 MOFs 的衍生材料作为传感材料。研究者可以探 2019, 6(1): 1801526.
[12] CHEN W, WU C S. Synthesis, functionalization, and applications of
索更多其他多功能材料和 MOFs 结合，通过合理的 metal-organic frameworks in biomedicine[J]. Dalton Transactions,
设计来提高传感器对不同环境的抗干扰能力、长期 2018, 47(7): 2114-2133.
[13] ZENG J Y (曾锦跃), WANG X S (王小双), ZHANG X Z (张先正),
稳定性和在室温下的灵敏度，使传感器向小型化、
et al. Research progress in functional metal-organic frameworks for
可携化迈近，实现商业应用。目前，基于 MOFs 材 tumor therapy[J]. Acta Chimica Sinica (化学学报), 2019, 77(11):
料的酸性气体传感器的研究可以发现： 1156-1163.
[14] MAINA J W, POZO-GONZALO C, KONG L X, et al. Metal organic
（1）有些 MOFs 可以提高传感器的水稳性。 framework based catalysts for CO 2 conversion[J]. Materials
（2）MOFs 的合成后修饰可以提高传感器对特 Horizons, 2017, 4(3): 345-361.
定气体的选择性。 [15] JIAO L, WANG Y, JIANG H L, et al. Metal-organic frameworks as
platforms for catalytic applications[J]. Advanced Materials, 2018,
（3）多种 MOFs 传感器组成的传感阵列可以用 30(37): 1703663.
于混合气体的传感。 [16] ZHAO J B (赵建波), YUAN H F (袁海丰), XIE B (谢冰), et al.
Progress in catalytic application of metal-organic framework[J]. New
（4）导电 MOFs 和柔性基底的结合有望实现可 Chemical Materials (化工新型材料), 2020, 48(2): 50-54.
穿戴传感。 [17] CHIDAMBARAM A, STYLIANOU K C. Electronic metal-organic
（5）网状导电结构和材料的等网状合成有利于 framework sensors[J]. Inorganic Chemistry Frontiers, 2018, 5(5):
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实现低功耗传感。 [18] VARGHESE A M, KARANIKOLOS G N. CO 2 capture adsorbents
（6）单组分或多组分纳米粒子的掺杂可以增强 functionalized by amine-bearing polymers: A review[J]. International
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MOFs 传感器的稳定性和提高响应。
[19] STASSEN L, DOU J H, HENDON C, et al. Chemiresistive sensing
（7）MOFs 和其他多功能传感材料的复合可以 of ambient CO 2 by an autogenously hydrated Cu 3 (hexaiminobenzene) 2
改善传统材料存在的问题，从而优化传感性能。 framework[J]. ACS Central Science, 2019, 5(8): 1425-1431.
[20] FREUND P, MIELEWCZYK L, RAUCHE M, et al. MIL-53(Al)/
（8）MOFs 材料的经济性、热稳定性、化学稳 carbon films for CO 2-sensing at high pressure[J]. ACS Sustainable
定性和导电性等问题仍然存在挑战，需要进一步探 Chemistry & Engineering, 2019, 7(4): 4012-4018.
[21] ZHENG Y, WAN S, YANG J, et al. Recent advances in
索和设计更合适的方案及策略。
post-synthetic modification of metal-organic frameworks: New types
and tandem reactions[J]. Coordination Chemistry Reviews, 2019,
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