Page 75 - 《精细化工》2023年第4期
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す 4 ᱌                  Ᲊܜᑧ喑ぶ:  ბڲᓛ䛼㠜ㆨ VOCs ٶ⅔ࡃ䭺㼐יࡃݯ⮱ⵁ⾣䔈ᆂ                                 g761g


            䬡⮱䩛Ⱕο҉⩕ᄩ㜡γ⩹䲏⩢㢤ܳጰ̺Ꭰ㶎喑ߍᔘ                             Ꮑ⩕͚⮱ᗲۢᎣ̺⌲ẇ喠
            γ⩢㢤ϻ䙺Ҁݝ Zr ࣌ၽ喑Вࣷ䕇䓴 Zr—P 䩛ݝ BP                          喍3喎็᪝יࡃݯ⮱⽠Ⴧᕔহᓗ⣜Ҭ⩕ᕔ㘪⁍Ҡ喠
            㶕䲏⮱䒙⼨喑ϻ㔹ើݣγ⩢ၽ-⾧⾡ᄦ⮱ฺव喑෋ᑧ                                喍4喎ౕݖ⩕㏠ㆠٶיࡃݯ䭺㼐Ⱋᴴ↎ᴀ➖⮱䓴
            γ יࡃݯౕ ज㻮ٶ̸ ᄦ⩟㠜⮱ 䭺㼐᩵⢴ ȡ                            ⼸͚喑ज㘪чϔ⩌̭ψ≨ᕔ͚䬡Ҁᝃ᫝⮱➖⻺喑Ⴐ
            BP@UiO-66 ⮱व᜽ͧ෋ᑧ⩢㢤䒙⼨᣽ӈγ᫝⮱᫦                         Й⮱ᄬপࣷ࢞რᕔ䰭䔈̭ₒᣏ⾣喠
            ∂喑ᆂ⹧γ BP@MOFs ᱽ᫆⮱ज㵹ᕔ喑ͧ㠜ㆨ VOCs                          喍5喎ฺᱯ⮱ݣิ≮⼸䭽ݣγٶיࡃݯౕጒ̷͇
            ⮱䭺㼐᣽ӈγ⤳䃧ധ⵭ȡ                                        ⮱๔㻱὎Ꮑ⩕ȡ
                                                                   ⩞λᄦ PCO ឭᱜ⮱γ㼐ᰶ䭽喑䦵ᄦВ̷䬛䷅᣽
                                                               ܧ̭ψᐧ䃛喟㐔㐚⌞ڒⵁ⾣ऱ⻺ٶיࡃᱽ᫆⮱ᆋᕔ喑
                                                               Ꭳᵦᢛ⤳䃧ⵁ⾣Გ䃫䃎ٶיࡃҀ㈨喑जВ䶱≸ܧڣ
                                                               ౕ᱗Გⵁ⾣͚⮱ᕔ㘪喑हᬣڠ∕౴Ⱕיࡃݯ⮱ࣾᆂ喑
                                                               ᓄݝФᵩѻ᏶喑व᜽᫦∂キࢂ⮱ٶיࡃݯ喠㐩वݖ
                                                               ⩕ጒ͇≨ߕϔ⩌⮱Ꮜᐰ➖व᜽倅᩵⮱יࡃᱽ᫆喑䕇
                                                               䓴ĄВᏌ⇨Ꮜą⮱⤳ᔢ䖬ٺ఍Ꮜᐰ㔹ᄩ㜡࢞რ⣜ධ
                                                               ⮱䬛䷅Ȳຯݖ⩕क़䨙↎−व᜽ MIL-101(Cr)ȳȡ㐀व
                                                               ڣЃឭᱜᲒࡼह䓫ݝ䶱᱌᩵᳉喍ຯٶ☚יࡃহٶ⩢
                                                               יࡃ喎喠ౕיࡃݯיࡃᕔ㘪⮱䃱Ф᫦䲏喑ᐧ⿸䃱Фᴴ

                 ఫ 8  BP@UiO-66 ٶ䭺㼐⩟㠜⮱ज䛺⩕ᕔ         [76]        ۳喑䖢ᓗ䃱Фᴴ۳喑䔈㔹Ӱ䔈倅ᕔ㘪יࡃݯ⮱ᐭࣾȡ
            Fig. 8    Reusability of BP@UiO-66 for photodegradation of   ᱗Გ PCO ឭᱜ⮱ⵁ⾣Ꮑ䯳ౕ͚᫝ಸٶיࡃݯ⮱ᐭ
                   toluene [76]
                                                               ࣾȠᏌᐰ䉱⎽倅թࡃݖ⩕হ㐀वڣЃឭᱜぶᲒ䔈̭
            4.2.3   ➧➟ٶ⩌⩢ၽ                                     ₒ䲍䓾჋䭲Ꮑ⩕ȡ
                 ᔘ䕌䔋㐚⊵㕄ٶ⩌⩢ၽजᰶ᩵Ӱ䔈⩢ၽ-⾧⾡                          ࣯㔰᪴⡛喟
            ᄦ⮱ܳ⻨喑᣽倅ٶיࡃ᩵⢴ȡCAO ぶ                [77] 䕇䓴Ⅱ☚∂
                                                               [1]   GUO D W, FENG D D, ZHANG Y L, et al. Synergistic mechanism
            ݣิܧ Bi 2 WO 6–x /䲋ᮣᔮ BiOCl喍p-BWO喎㏠ㆠ❴ȡ
                                                                   of biochar-nano TiO 2 adsorption-photocatalytic oxidation of toluene
            p-BWO ㏠ㆠ❴㷘ज㻮ٶ⚔ᄱϔ⩌⩢ၽ-⾧⾡ᄦ喑ٶ                              [J]. Fuel Processing Technology, 2022, 229(1): 107200-107213.
            ⩌⩢ၽ㷘[W(Ę)O 6–x ]ᢂ㣤喑ᄳ W(Ę)䔅࣌ͧ W(ė)喑                 [2]   HO V T T,  CHAU D H, BUI K  Q,  et al. A high-performing
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            Ҭ㏠ㆠ❴अ㨊喑㔹 O 2 ᄳ W(ė)⅔ࡃͧ W(Ę)喍␯⮪                         of gaseous toluene[J]. Inorganics, 2022, 10(3): 29-45.
            ᔮ喎喑䕇䓴Ⴙ᜽अ㞟ᓗ⣜ज̺᫚⊵㕄ٶ⩌⩢ၽ喑㔹⾧                            [3]   QIU S X, WANG W J, YU J Q,  et al. Enhanced photocatalytic
                             3
            ⾡Ӱ䔈γ⩟㠜 C(sp )ÿH 䩛⮱≨ࡃ喑Ҭ p-BWO ㏠ㆠ                        degradation efficiency of formaldehyde by in-situ fabricated TiO 2/C/
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            ❴ౕ䭺㼐⩟㠜ᬣڤᰶ㞜ສ⮱ᕔ㘪ȡ̻ Bi 2 WO 6 Ⱕ℁喑                         Journal of Solid State Chemistry, 2022, 311(2022): 123110-123120.
            p-BWO ᄦ⩟㠜⮱䭺㼐᩵⢴᭫㦄᣽倅喑ڣ䒙ࡃ⢴᣽倅                          [4]   LI X Q, ZHANG  L,  YANG Z Q,  et al. Adsorption materials for
                                                                   volatile organic compounds (VOCs) and the key factors for VOCs
            γ 166 Ժ喑ڣ͚͝ჹ⮱ᮣᔮ-䲋ᮣᔮ䓦⩹㑖ⴚγ⾧⾡
                                                                   adsorption process: A review[J]. Separation and Purification Technology,
            ⮱䓮⼨䌜ᒱ喑͝ჹ⮱[W(Ę)O 6–x]ࢂٰ㘪ᢂ㣤⩢ၽ㔹ᑧ                          2020, 235(26): 116213-116273.
            ݣܳ⻨䒪≮ၽȡ                                            [5]   ALIVAND M S, TEHRANI N H M H, ASKARIEH M, et al. Defect
                                                                   engineering-induced porosity in graphene quantum dots  embedded
                                                                   metal-organic frameworks for enhanced benzene and toluene adsorption
            5   㐀᲌䄚̻ᆂ᱈                                             [J]. Journal of Hazardous Materials, 2021, 416(47): 125973-125985.
                                                               [6]  BAYTAR  O,  ùAHIN Ö, HOROZ S, et al. High-performance gas-
                 ๗䭠㘪᭜㜗♣⩹⮱जں⩌䉱⎽喑ᄳڣٲܳݖ⩕                              phase adsorption  of benzene and toluene on activated carbon:
            Გᰶ᩵ࣨ䮑㠜ㆨ VOCs喑чͧϧㆨ⹫чፓᲒ̭Ⴧ⮱                               Response surface optimization, reusability, equilibrium, kinetic, and
                                                                   competitive adsorption studies[J]. Environmental Science and Pollution
            ㏼≻᩵⯷ȡ᱙᪴䬽䔝γٶיࡃ䭺㼐⮱҉⩕ᱧ⤳喑᪡                                 Research, 2020, 27(4): 26191-26210.
            ⤳ܧڲȠใ䘕఍㉍ᄦ䭺㼐᩵⢴⮱ᒞ৺喑ᎣᠴܧजВ                             [7]   ZHAO H,  YANG  C Y, LV K  L,  et al. Single atomic Au induced
                                                                   dramatic promotion of the photocatalytic  activity of  TiO 2 hollow
            䕇䓴ᣧᱯȠ䉢䛾ᆋ↶⼜ȠࡷᄩҀฺवȠ➧➟ٶ⩌⩢
                                                                   microspheres[J]. Chemical Communications, 2020, 56(11): 1745-1748.
            ၽ⮱ᩦᕔឭᱜᲒᰶ᩵᣽倅יࡃݯ⮱ٶ႓ᕔ㘪喑ѳ㏠                             [8]   WU P, JIN X J, QIU Y C, et al. Recent progress of thermocatalytic
            ㆠٶיࡃݯϺႅౕВ̸ 5 ͗䬛䷅喟                                      and photo/thermocatalytic oxidation for VOCs purification over
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            ⣜ධ↎ᴀ䬛䷅喠                                            [9]   VIKRANT K, WEON S, KIM K H, et al. Platinized titanium dioxide
                 喍2喎㷘ᐭࣾ⮱ٶיࡃݯϲౕ჋侹ⵁ⾣͚➦Ⴧ⮱                             (Pt/TiO 2) as a multi-functional catalyst for thermocatalysis, photocatalysis,
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            ᲎У̸㶕⣝ܧ㞜ສ⮱יࡃ≨ᕔহ⽠Ⴧᕔ喑ѳౕ჋䭲                                 Materials Today, 2021, 23(7): 100993-101032.
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