Page 80 - 《精细化工》2023年第4期
P. 80

g766g                             ㇫㏳ࡃጒ   FINE CHEMICALS                                 す 40 ࢤ

            ఍ₑ喑ज̻ڤᰶхᐯ⩢ࡃ႓ᕔ㘪⮱ᄩ⩢➖䉕ฺव                      [30] ȡ  H 2 O喎ݣิγ܊㘣⩢㼐䉕ȡDMSO Ӱ䔈γ PVA ⮱܊
            ⢸䯲ैぶ     [31] В CNF ͧ܊㘣⩢㼐䉕⮱㏠ㆠ඘᫆喑ᩜᦾ                 㘣ࡃ喑㔹 CNF ݆҉ͧڣ͚⮱㏠ㆠ඘᫆喑ᓄݝ⮱܊㘣
            ᄩ⩢ധ䉕㑾㐉ᝃ᭜Ⱑᣒٲᒀ俕᳣᣽ӈ߈႓ᩜᦾহ᣽                             ⩢㼐䉕ڤᰶᲮ倅⮱䴔ᕔ喑៶ѥᏁअ>600%⮱हᬣᏁ߈
            ӈ㑾㐉㐀Ჱ喑ݣิܧڤᰶхᐯ⩢ࡃ႓হ߈႓ᕔ㘪⮱                             䓫ݝγ 2.1 MPaȡₑใ喑CNF ⮱ႅౕҬ PVA 俕᳣ᒏ
            ܊㘣⩢㼐䉕ȡCHEN ぶ         [32] ᝭ݣิ⮱㏠ㆠ㏑㐡㉍܊㘣              ᜽γᰡ็ᅯ⁎⮱็ႁ㐀Ჱȡ㐀᳉㶕ᬻ喑⌨ߍγ PVA
            䕇䓴᣽倅㏠ㆠ㏑㐡㉍⮱䪬ᒱ℁ᰶ᩵ౝ᣽ࡴγ܊㘣⮱                             䉕䛼 4%⮱ CNF ऻ喑⩢㼐䉕⮱⻨ၽ⩢ᄩ⢴䒰㏜ PVA
            ߈႓ᕔ㘪喑ᰡ๔⮱䪬ᒱ℁ΌᘼঠⱭ㐆܊㘣ፓᲒᰡ͝                             ܊㘣᣽ࡴγ 2 Ժ喑Ꭳ́ DMSO ⮱ႅౕҬ䄒܊㘣⩢㼐
            ჹ⮱ႁ䯆㐀Ჱࣷ℁㶕䲏⼜喑㘪ͧᄩ⩢➖䉕᣽ӈᰡ็                             䉕जВౕ䊲ѻ⍖⣜ධ̸ࣾᡒ҉⩕ȡSONG ぶ                  [36] ݣิ
            ⮱ฺवѺ◦ȡₑใ喑ZHANG ぶ             [33] 䔅ࣾ⣝喑㏠ㆠ㏑          ⮱܊㘣⩢㼐䉕ӊ䲍ڲ䘕㖇Άι䚴⮱ᴁᕔ䨫⃢̻㏠ㆠ
            㐡㉍⮱ႅౕ㘪์Ӱ䔈㏑㐡㉍䨫͸䬡Ⱕο㑍㐂হ䔋                              ᱕䉕㏑㐡㉍喍LCNF喎俕᳣⮱㉔ჳϑ㏴㑾㐉㐀ᲱҬ࠲
            ᣒ喑ᰶ᩵㕄᪐γใ⩹Ꮑ߈喑෋ᑧγ܊㘣߈႓ᕔ㘪ȡ                             ᠙☚߈႓Ƞ߈႓ࣷ⩢ࡃ႓ぶ็᫦䲏ᕔ㘪䘪ᰶγ᭫㦄
            ఍㔹喑᝭ݣิ⮱܊㘣⩢㼐䉕ᑧᏓᬻ᭫倅λ̭㝙ⴠ⇦                             ᣽ࡴȡMO ぶ     [37] В CNF ͧ俕᳣喑[2-(⩟ധ͆☜䚝ധ
            ധ㖇व➖܊㘣ȡ                                            ⅔ധ)Άധ]ι⩟ധ-(3-⸧䚥͆ധ)⅏⅔ࡃ䨢ͧࢂҀ喑ᑂ
                 CNF ̺ϲ҉ͧ㏠ㆠ඘᫆෋ᑧγ܊㘣⩢㼐䉕⮱ᑧ                        ࣾ㜗⩞ധ㖇वव᜽γ͑ᕔ⻨ၽಸ⸧ധ⩉㤉ⷞࢂҀᲒ
            Ꮣ̻䴔ᕔ喑䔅䕇䓴⅏䩛̻ڣЃ倅ܳၽ䨫㑍㐂ᒏ᜽㑾                             व᜽܊㘣⩢㼐䉕ȡ⩞λ͑ᕔ⻨ၽധఏহⅡܳၽ͸䬡
            ⟣㐀ᲱВ䔈̭ₒ෋ᑧ܊㘣⩢㼐䉕⮱߈႓ᕔ㘪ȡCHEN                           ⮱ᑧ䲆⩢Ⱕο҉⩕喑ፓᰶₐ䉌⩢㢤⮱͑ᕔ⻨ၽಸ⮱
            ぶ [34] ݣิγक़䨹⯽⮱ⶩ⴯ϑ㖁㖇Ά☜䚴喍PVA喎/㏠                      ⩢㼐䉕ͧ܊㘣᣽ӈγхᐯ⮱ԊⅡᕔ㘪喑㔹 CNF 俕᳣
            ㆠ㏑㐡㉍܊㘣⩢㼐䉕喍B-PVA/CNF喎喍ఫ 1喎ȡ                         㼐۠γ͑ᕔ⻨ၽ㖇व➖⮱㘳ᕔ䬛䷅喑ϻ㔹Ԋ䃮ڣ㏱

                                                               㷲⮱⩢↍̺ч఍ბใ⋟Ⱕ㧥ࣾᝃใ߈ϔ⩌⮱ᑜៅᒞ
                                                               ৺䪬Ͳ⽠Ⴧጒ҉⮱㘪߈ȡ
                                                                   CNF ڤᰶ䒰๔⮱䪬ᒱ℁喑̻๔䘕ܳᄩ⩢㖇व➖
                                                               ฺवᬣοⰥ㑍㐂㘪ᒏ᜽ࣹ㑾㐉㐀Ჱ⮱܊㘣⩢㼐䉕喑
                                                               CNF 㘪์ٲᒀ෋ᑧҀВ᣽倅ڣᱧᷝᑧᏓহ⻨ၽ⩢ᄩ
                                                               ⢴ȡGE ぶ   [38] ౕ CNF হ LiCl ⮱ႅ̸ౕ喑䕇䓴͆☜䚝
                                                               㘧喍AM喎̭ₒ㜗㖇वव᜽γࣹ㑾㐉܊㘣喍ఫ 2喎ȡ
                                                               CNF ̻㖇͆☜䚝㘧喍PAM喎͸䬡ᒏ᜽⅏䩛҉⩕হܳ
                                                               ၽ䨫䬡㑍㐂喑㘪ᰶ᩵㕄᪐܊㘣⮱ใߍᏁ߈喑䉸ε܊
                                                               㘣㞜ສ⮱䴔ᕔȠ៶ѥᕔহࢸ㑖ᕔȡᒀ LiCl ⮱䉕䛼⊀
                                                               Ꮣܳݘͧ 100Ƞ300 হ 500 g/L ᬣ喑ݣิγ̭㈨݄
                                                               PAM/CNF/LiCl ܊㘣喑ܳݘ䃝ͧ PAM/CNF/LiCl 10%Ƞ
                                                               PAM/CNF/LiCl 30%হ PAM/CNF/LiCl 50%喑ڣ͚喑
                                                               PAM/CNF/LiCl 50%܊㘣҉ͧ⩢㼐䉕㏱㷲⮱䊲㏔⩢
                                                               ღகౕѻ⍖᲎У̸ڤᰶ⽠Ⴧ⮱⩢ࡃ႓ᕔ㘪হ倅䓫
                                                               748%⮱ᐣᆂ ᕔ喑ह ᬣ⻨ ၽ⩢ᄩ ⢴ౕ –40 Ď倅䓫
                                                               2.25 S/mȡWANG ぶ   [39] ݣิγ̭⻺㖇͆☜䚝㘧-叱࣌

                                                               㘣ᣒ᳊㖇व➖ฺव CNF喑ڣ㘪์ౕ䨹⯽⏣⋟͚㏱㷲
            ఫ 1  B-PVA/CNF ܊㘣⩢㼐䉕ݣิࣷᱧ⤳⹧ᘼఫ喍a~b喎喠
                  ܊㘣⩢㼐䉕៶ѥ̻㜗ԛฺ჋➖ఫ喍c喎              [34]          ᜽ࣹ㑾㐉㐀Ჱ܊㘣⩢㼐䉕ȡCNF ҉ͧ᣽ӈᓛႁ㑾㐉
            Fig. 1    Schematic diagram of preparation and mechanism   㐀Ჱ⮱ϟⅡᕔ俕᳣喑㘪์ٲᒀ෋ᑧҀВ᣽倅܊㘣⩢
                   of B-PVA/CNF gel electrolyte (a~b); Stretching and   㼐䉕⮱ᱧᷝᑧᏓহ⻨ၽ⩢ᄩ⢴喑ᰭ㏵⩢㼐䉕⻨ၽ⩢
                   self-healing  physical diagram of gel electrolyte
                   (c) [34]                                    ᄩ⢴䓫ݝγ 28.8 mS/cm喑हᬣᏁअ᣽ࡴγ 4 Ժ喑ധ
                                                               λ䄒⩢㼐䉕㏱㷲⮱䨹⩢↍ጟ㏼㘪ͧᴁᕔज⾬ᝡ⩢ၽ
                 PVA হ CNF ͸䬡ज䕇䓴ⶩ⴯჋⣝γߕᔮज䔳                      䃫ิ䔈㵹ӈ⩢ȡ
            ϑ㖁喑ᰭ㏵㣤ᓄ⮱܊㘣⩢㼐䉕᠒ᰶхᐯ⮱叼ᑦᕔȠ                                 㐩̷喑⩕㏠ㆠᅧᏓ⮱ CNF ݣิ⮱܊㘣⩢㼐䉕ڤ
            㞜ສ⮱叼㐀ᕔ㘪হᲮᑧ⮱㜗ᘵᕔ㘪喑Ꭳ́ڤᰶ                               ᰶ͝ჹȠ㜡ჳ⮱ႁ䯆㐀Ჱ喑㘪䔈̭ₒ᣽倅ڣ䴔ᕔࣷ
            18.1 mS/cm ⮱倅⻨ၽ⩢ᄩ⢴喑ᰭ㏵㏱㷲᜽जៅऍᑜ                       ⻨ၽэᄩᕔ㘪ȡओใ喑㏠ㆠ㏑㐡㉍㘪̻ڣЃᄩ⩢㖇
            ᰟВࣷज㜗ᘵव⮱䊲㏔⩢ღகȡYE ぶ                 [35] ᄳ PVA ̻    व➖ฺवϑ㖁㔹̺ϔ⩌ᢿ᫒喑ϻ㔹䉸ε܊㘣⩢㼐䉕
            CNF ⌤वऻ䕇䓴ᑂڒι⩟ധχⵉⅡ⏣⋟喍DMSO/                          㜗ᘵवぶᕔ㘪ȡ㏑㐡㉍㏠ㆠҀ㈨Ⱕ䒰⏣㼐Ҁ㈨ⵁ⾣
   75   76   77   78   79   80   81   82   83   84   85