Page 81 - 《精细化工》2023年第4期
P. 81
す 4 ᱻ๖⺧喑ぶ: ᱕䉕㏑㐡㉍ധ܊㘣⩢㼐䉕⮱ⵁ⾣䔈ᆂ g767g
ᰡͧ⌞ڒ喑㔹ᄦ CNF ⮱ݺⵁ⾣㘪ͧ᱕䉕㏑㐡㉍ 㘪㕄 [40] ᝃ᭜ݣิҀ㈨ፓᰶᕔ [41] ぶ喑䔆ψ䘪᭜ጒ͇
ڕ㏱ܳധ܊㘣⩢㼐䉕⮱ݣิӈᰶ᩵Ռ䞡ȡѳ CNF ̷ό䰭㼐۠⮱䬛䷅ȡౕ䭲⮱Ꮑ⩕̻ϔ৮ᐭ͚ࣾ喑
⮱ݣิጒ㞧ฺᱯ喑፥㻮⮱ݣิጒ㞧䰭㺮⊵㕄๔䛼⮱ ϧЙᰡիाλ䔶⩕⏣㼐㏑㐡㉍ࣷڣ㵺⩌➖ϔ৮ȡ
ఫ 2 PAM/CNF/LiCl ܊㘣ݣิࣷᱧ⤳ᘼఫ喍a喎喠PAMȠPAM/CNF হ PAM/CNF/LiCl ܊㘣⮱៶ѥᏁ߈-Ꮑअᰟ㏬喍b喎
হ⻨ၽ⩢ᄩ⢴喍c喎 [38]
Fig. 2 Schematic diagram of preparation and mechanism of PAM/CNF/LiCl hydrogel (a); Tensile stress-strain profiles (b) and
ionic conductivity (c) of PAM, PAM/CNF and PAM/CNF/LiCl hydrogels [38]
1.2 ⏣㼐㏑㐡㉍܊㘣⩢㼐䉕 ⏣㼐㏑㐡㉍܊㘣ڤᰶ๔䛼⮱ᓛႁ㐀Ჱ喑̺ϲ㘪
ͧ䔈̭ₒࡴ㏑㐡㉍܊㘣⩢㼐䉕⮱Ҭ⩕ᄬপহ ӈ͝ჹ⮱⻨ၽព᪐䕇䖀হ䋠์⮱⩢㼐䉕॥ᩣ⾧
ᄩ⩢ᕔ喑䃥็ⵁ⾣㔲ᄳⰛٶ䒙ाγ㑾㐉ႁ䯆ᰡ̭Ƞ 䬡喑䔅जВᑧ܊㘣⩢㼐䉕⮱ᴁ䴔ᕔȡᑍᮀࢇぶ [43]
㜡ჳ⮱⏣㼐㏑㐡㉍܊㘣 [42] ȡ⏣㼐㏑㐡㉍ں⩌ऻ̺ϲ ⩕㏥≳̻ CS 2 䕇䓴ࡃ႓ϑ㖁ݣᓄ㏑㐡㉍叼㘣⋟喑䕇
ज҉ͧԊ䃮⩢㼐䉕߈႓ᑧᏓহ͝ჹႁ䯆⮱俕᳣喑䔅 䓴Ⅱࡃั⤳ᒏڤᰶ㞜ສႁ䯆⢴হ⤳ᘠࣹ⩢ღ㵹ͧ
ज̻⣜⅔⅜͆☤ぶ䔈㵹ࡃ႓ϑ㖁܊㘣喑䔈̭ₒ䄰 ⮱㏑㐡㉍܊㘣⩢㼐䉕ȡౕₑധ̷喑ᑂڒ K 4 Fe(CN) 6
ᣔႁ䯆̻ࡴ߈႓ᕔ㘪ȡ܊㘣⩢㼐䉕⮱ႁ䯆㐀Ჱ҉ ͧ⅔ࡃ䔅࣌ϸ䉕Ҭ⩢㼐䉕ڤᰶᰡ倅⮱ࣺᏁ≨ᕔ喑В
ͧ⻨ၽэᄩ⮱䕇䖀ᄦ⩢㼐䉕⮱⻨ၽ⩢ᄩ⢴ࣷ⻨ၽэ 倅ጒ҉ᬣ⮱⻨ၽ⊀ᏓহࣺᏁ᩵⢴喑ᬻ᭫ౝ倅γ
䓀᩵⢴䊤Ɑڠ䩛҉⩕喑㔹⏣㼐㏑㐡㉍܊㘣ౕ䄰ᣔႁ ⩢㼐䉕⮱⻨ၽ⩢ᄩ⢴喑䓫ݝγ 15.2 mS/cmȡZHAO
䯆⢴䲏℁㏠ㆠ㏑㐡㉍܊㘣х߬ᰡ๔ȡZHANG ぶ [14] ぶ [44] ᄳ㏑㐡㉍⏣㼐ౕ 1-̮ധ-3-⩟ധৗਾ⅜ࡃ➖⮱
䕇䓴̺ह㧥↪⊡ں⩌⮱キࢂ∂喑ࢠजᄦ㏑㐡㉍⏣ ⻨ၽ⋟Ҁ͚喑ں䕇䓴⏣ݯ-ࣺ⏣ݯ∂В㏜Ⅱں⩌≴䨥
⋟ں⩌܊㘣⮱ႁ䯆㐀Ჱ䔈㵹䄰᪡喑䕇䓴䄰᪡܊㘣⮱ ᒏ܊㘣喑ᰭऻᄳڣ✒ᓄݝ⩢㼐䉕ȡ䄒⩢㼐䉕ႅ
ႁ䯆㐀ᲱजВҬڣᰡᭀ॥䭱ᄩ⩢≨ᕔ➖䉕喑ᰭ㏵ᓄ ౕ๔䛼࠭ܳጰ⮱ȠⰡᒱͧ 5~30 nm ⮱ᓛႁ喑В
Вݣิ⻨ၽэ䓀ᰡᔘȠ⻨ၽ⩢ᄩ⢴ᰡ倅⮱܊㘣⩢㼐䉕ȡ ӈ͝ჹ⮱⻨ၽព᪐䕇䖀হ䋠์⮱⩢㼐䉕॥ᩣ⾧䬡ȡ
