Page 181 - 201811

第 11 期 闫继芳，等: 水性纯丙乳液的合成及其附着性能 ·1967·

的接触角从 62.6°降到 27.8°，乳液与 BOPP 薄膜之 1747.
间的界面张力从 19.01 mN/m 降至 4.87 mN/m，乳液 [8] Tomic N Z, Veljovic D D, Trifkovic K, et al. Numerical and
experimental approach to testing the adhesive properties of modified
在 BOPP 薄膜上的附着牢度从 50%提高到 95%，这
polymer blend based on EVA/PMMA as coatings for optical fibers
些结果说明单体配比对水性聚丙烯酸酯乳液的润湿 [J]. International Journal of Adhesion and Adhesives, 2017, 73:
性和附着性能影响较大，软单体含量越高，润湿性 80-91.
越好，附着牢度越好。当 m(MMA)∶m(2-EHA)=7∶ [9] Zheng Z J, Tian X H, Sun J Y, et al. Studies of latex blends of natural
rubber/poly (methyl methacrylate-co-2-ethylhexyl methacrylate) and
13 时，虽然乳液的附着牢度满足应用要求，但此时
their comparison with incompatible natural rubber/poly (methyl
乳液膜较黏，后续可合成核壳结构的乳液或引入交 methacrylate) [J]. Polymer Science Series A, 2015, 57(5): 613-621.
联单体，使合成的乳液既满足附着牢度要求，干燥 [10] Haloi D J, Ata S, Singha N K, et al. Acrylic AB and ABA block
后的乳液膜又不发黏。 copolymers based on poly (2-ethylhexyl acrylate) (PEHA) and poly
(methyl methacrylate) (PMMA) via ATRP [J]. ACS Appl Mater
参考文献： Interfaces, 2012, 4(8): 4200-4207.
[11] Saindane P, Jagtap R N. RAFT copolymerization of amphiphilic
[1] Pi P H, Chen X, Wen X F, et al. Preparation and characterization of
poly(ethyl acrylate-b-acrylic acid) as wetting and dispersing agents
ambient-temperature self-crosslinkable water-soluble acrylic resin for
for water borne coating [J]. Progress in Organic Coatings, 2015, 79:
PE film ink [J]. Journal of Coatings Technology and Research, 2016,
106-114.
13(1): 73-80.
[12] Liu Jie (刘杰). Investigation on diffusional behavior of water-
[2] Kajtna J, Likozar B, Golob J, et al. The influence of the insoluble chain transfer agents in emulsion polymerization [D].
polymerization on properties of an ethylacrylate/2-ethyl hexylacrylate Beijing: Beijing university of chemical technology (北京化工大学),
pressure-sensitive adhesive suspension [J]. International Journal of 2008.
Adhesion and Adhesives, 2008, 28(7): 382-390. [13] Legrand D G, Gaines G L Jr. The molecular weight dependence of
[3] Duan Y F, Huo Y D, Duan L. Preparation of acrylic resins modified polymer surface tension [J]. Journal of Colloid & Interface Science,
with epoxy resins and their behaviors as binders of waterborne 1969, 31(2): 162-167.
printing ink on plastic film [J]. Colloids and Surfaces [14] Wang Rong (王荣), Fu Heqing (傅和青), Chen Huanqin (陈焕钦).
a-Physicochemical and Engineering Aspects, 2017, 535: 225-231. Study on surface tensions of modified acrylate emulsion PSA [J].
[4] Wang Haiqiao (王海侨), Zhang Lin (张琳), He Lifan (何立凡), et al. China Adhesives (中国胶粘剂), 2013, 22(10): 1-6.
Silane coupling agent modified acrylic emulsion for waterborne ink [15] Gu Jiyou (顾继友). Bonding theory and bonding foundation [M].
application [J]. New Chemical Materials (化工新型材料), 2010, Beijing (北京): Science Press (科学出版社), 2004, 72.
38(6): 108-111. [16] Bajpai S, Rai J S P, Nigam I. Synthesis and characterization of
[5] Chen Xi (陈曦), Xue Chaoxia (薛超霞), Pi Pihui (皮丕辉), et al. poly[methyl methacrylate-co-2-ethylhexyl acrylate-co-poly (propylene
Preparation of ambient temperature self-crosslinking waterborne glycol diacrylate)] latices [J]. Journal of Applied Polymer Science,
acrylate resin for PEand PP film ink [J]. Electroplating and Finishing 2011, 122(1): 676-684.
(电镀与涂饰), 2015, 34(14): 765-769. [17] Lei L, Xia Z, Lin X, et al. Synthesis and adhesion properties of
[6] Li Yunan (李玉南), Cui Jiamin (崔嘉敏), He Lifan (何立凡), et al. waterborne polyurethane dispersions with long-branched aliphatic
Synthesis of polyacrylate latex for waterborne ink and its application chains [J]. Journal of Applied Polymer Science, 2015, 132(12). DOI:
on BOPP film [J]. New Chemical Materials (化工新型材料), 2014, 10.1002/app.41688.
42(8): 234-236. [18] Galliano A, Bistac S, Schultz J. Adhesion and friction of PDMS
[7] Owens D K, Wendt R C. Estimation of the surface free energy of networks: molecular weight effects [J]. J Colloid Interface Sci, 2003,
polymers [J]. Journal of Applied Polymer Science, 1969, 13(8): 1741- 265(2): 372-379.

（上接第 1947 页） [15] Ma J, Guo X, Ying Y, et al. Composite ultrafiltration membrane
[12] Jia X, Pan Z, Xiu Y, et al. A novel metal-organic framework tailored by MOF@GO with highly improved water purification
composite MIL-101(Cr)@GO as an efficient sorbent in dispersive performance [J]. Chemical Engineering Journal, 2016, 313: 890-898.
micro-solid phase extraction coupling with UHPLC-MS/MS for the [16] Qiu X, Wang X, Li Y. Controlled growth of dense and ordered
determination of sulfonamides in milk samples[J]. Talanta, 2016, metal-organic framework nanoparticles on graphene oxide[J]. Chemical
169: 227-238. Communications, 2015, 51(18): 3874-3877.
[13] Piscopo C, Polyzoidis A, Schwarzer M, et al. Stability of UiO-66 [17] Wang C H, Liu X L, Chen J, et al. Superior removal of arsenic from
under acidic treatment: Opportunities and limitations for post-synthetic water with zirconium metal organic framework UiO-66[J]. Scientific
modifications[J]. Microporous and Mesoporous Materials, 2015, 208: Reports, 2015, 5: 16613-16623.
30-35. [18] Liang Q, Jin J, Liu C, et al. Fabrication of the ternary heterojunction
[14] Cao Y, Zhao Y, Lu Z, et al. Preparation and enhanced CO 2 adsorption Cd 0.5Zn 0.5S@UiO-66@g-C 3N 4 for enhanced visible-light photocatalytic
capacity of UiO-66/graphene oxide composites[J]. Journal of hydrogen evolution and degradation of organic pollutants[J]. Inorganic
Industrial and Engineering Chemistry, 2015, 27: 102-107. Chemistry Frontiers, 2017, 5: 335-343.