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第 35 卷第 7 期 精 细 化 工 Vol.35, No.7
201 8 年 7 月 FINE CHEMICALS July 2018

建筑用化学品
ATO/GO 纳米复合材料的制备及性能

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李菁熠 1,2 ，李小瑞 ，朱 科 ，沈一丁 ，覃蜀迪
（1. 陕西科技大学 化学化工学院，陕西 西安 710021；2. 渭南师范学院，陕西 渭南 714099）
摘要：以氧化石墨烯（GO）为前体，通过氨丙基三乙氧基硅烷（KH550）将氧化锡锑（ATO）锚定到氧化石墨
烯片层上，制备得到氧化锡锑-氧化石墨烯纳米复合材料（ATO/GO）。通过高速分散法与水性环氧树脂乳液（AE）
共混，制备得到氧化锡锑-氧化石墨烯/水性环氧树脂复合乳液（ATO/GO-AE）。通过 XRD，XPS 和 SEM 对其结
构进行了表征。考察了 ATO/GO 含量对水性环氧涂料防腐及抗静电性能的影响。结果表明：随 ATO/GO 含量
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的增加，复合涂料表面电阻降低，ATO/GO 质量分数等于 3.0%时，表面电阻降低至 1.0×10 Ω 以下，达到了抗
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静电的使用要求，漆膜水蒸汽透过率降低至 62.13 g/(m ·h)，具有最低的腐蚀电流（I corr =3.73×10 A/cm ）和最
高的腐蚀电压（E corr = –0.1993 V），ATO/GO 的防腐效率与 AE 相比提高了 99.95%。
关键词：氧化石墨烯；氧化锡锑；防腐涂料；抗静电；建筑用化学品
中图分类号：TQ63 文献标识码：A 文章编号：1003-5214 (2018) 07-1248-07

Preparation and Properties of ATO/GO Nanocomposite

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LI Jing-yi , LI Xiao-rui , ZHU Ke , SHEN Yi-ding , QIN Shu-di
（1. Shaanxi University of Science & Technology, College of Chemistry and Chemical Engineering,Xi'an 710021, Shaanxi,
China; 2. Weinan Normal University, Weinan 714099, Shaanxi, China）
Abstract: A new ATO/GO nanocomposite was obtained by 3-aminopropyltriethoxysilane(KH550) modified
tin antimony oxide(ATO) anchoring on graphene oxide(GO) layers. Then, the resulting ATO/GO
nanocomposite was mixed with waterborne epoxy resin emulsion (AE) by high speed dispersion method.
The samples were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy(XPS) and
scanning electron microscope(SEM). The effect of ATO/GO content on the anticorrosion and antistatic
properties of waterborne epoxy coating was investigated. The results showed that with the increase of
ATO/GO content, the surface resistance of composite coating decreased. When the mass fraction of
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ATO/GO was greater than 3.0%, the surface resistance of composite coating was less than 1.0×10 Ω,
which could meet the anti-static requirements. The composite coating containing 3.0% mass fraction of
ATO/GO exhibited excellent anti-corrosion and antistatic properties. The water vapor transmittance of
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composite coating decreased to 62.13 g/(m h),and the lowest corrosion current density (I corr) and the
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maximum corrosion voltage (E corr) were 3.73×10 A/cm and -0.1993 V, respectively. In addition, the
anticorrosive efficiency was an improvement of 99.95% compared with that of blank sample.
Key words: graphene oxide; tin antimony oxide; anticorrosion coating; antistativity; building chemicals
Foundation items: National Natural Science Foundation of China (21505089,21544011); Special Scientific
Research Program of Shaanxi Provincial Education Department (17JK0270)

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在石化、交通、纺织、电器电子设备等行业 ， 10 ~1.010 Ω的具有防静电效应的防腐涂料，其以
静电可加速铁基材的腐蚀速率，需要涂装优良抗静 聚合物为成膜物质，通过加入导电材料浆料形成导
电性的防腐涂层。抗静电防腐涂料是表面电阻为 1.0 电通路以达到抗静电作用 [2-4] 。添加的导电材料包括

收稿日期：2017-07-01; 定用日期：2017-11-23; DOI: 10.13550/j.jxhg.20170528
基金项目：国家自然科学基金（21505089, 21544011）；陕西省教育厅科研计划项目（17JK0270）
作者简介：李菁熠（1989—），女，博士生。联系人：李小瑞（1958—），女，教授，博士生导师，E-mail：xrli@sust.edu.cn。