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·1420· 精细化工 FINE CHEMICALS 第 35 卷

的 C—N、C==O（或 C==S、C—S）断裂并吸附在 [5] Zhang J, Liu W, Xue Q. The effect of molecular structure of
heterocyclic compounds containing N, O and S on their tribological
金属表面，其中 N 元素主要生成有机氮化合物或聚 performance[J]. Wear, 1999, 231(1): 65-70.
[6] Li J C, Fan B J, Ren T H, et al. Tribological study and mechanism of
合物，O（或 S）主要与 Fe 反应生成铁的氧化物（或 B-N and B-S-N triazine borate esters as lubricant additives in mineral
oil[J]. Tribology International, 2015, 88(1): 1-7.
硫化物），从而在摩擦副表面形成了富含 N 和 O（或 [7] Cao Yueping (曹月平), Yu Laigui (余来贵). The effect of tribenyl
S）等元素的复杂反应膜，从而提高油样的极压、抗 phosphate and dibutyl phosphite as additives on the tribological
behaviors of rapeseed oil[J]. Tribology (摩擦学学报), 2000, 20(2):
磨和减摩性能 [26-27] 。 119-122.
[8] Liu Yanli (刘艳丽), Liu Chaosheng (刘朝生), Wu Xiaojie (吴小杰),
et al. Synthesis and tribological behavior study of biodegradative
3 结论 lubricant additives[J]. Petroleum Processing and Petrochemicals (石
油炼制与化工), 2011, 42(7): 54-57.
[9] Qiu Y S. Investigation of lubricity of sulfurized olefin and dodecyl
（1）设计合成了 4 种具有不同结构的多功能润 amine salt of benzotriazole[J]. Tribology Transactions, 2008, 27(4):
359-365.
滑油添加剂（Ⅰ~Ⅳ），并采用核磁共振氢谱仪和飞 [10] Chong W W F, Ng J H. An atomic-scale approach for biodiesel
boundary lubricity characterisation[J]. International Biodeterioration
行时间质谱仪确证了其分子结构。 & Biodegradation, 2016, 113(1): 34-43.
（2）4 种添加剂在室温（25 ℃）加入量均可 [11] Huang Wenxuan (黄文轩). Summary of environmental compatible
lubricants[J]. Lubricating Oil (润滑油), 1997, 12(4): 1-8.
达到 2.0%以上，在低温（5 ℃）时加入量都能达到 [12] Sun Yubin (孙玉彬), Hu Litian (胡丽天), Xue Qunji (薛群基).
Development and research progress of environmental friendly
1.0%以上，表现出良好的油溶性；4 种添加剂的起 lubricating oil additives[J]. Tribology (摩擦学学报), 2008, 28(4):
381-387.
始热分解温度都在 197 ℃以上，最终热分解温度都 [13] Huang Weijiu (黄伟九). Research on the novel lubrication additive
在 350 ℃以上，能够满足实际工况要求，其中Ⅰ、 promoting biodegradation of lubrication oil[J]. Lubrication
Engineering (润滑与密封), 2009, 34(11): 5-8.
Ⅱ和Ⅲ能满足高温工况使用要求；4 种添加剂的铜 [14] Tang Z, Li S. A review of recent developments of friction modifiers
for liquid lubricants (2007-present)[J]. Current Opinion in Solid State
片腐蚀级别均为 1a，具有优良的抗腐蚀性。 & Materials Science, 2014, 18(3): 119-139.
（3）4 种添加剂均能明显地提高液体石蜡的极 [15] Zhao Hongbin (赵鸿斌), Peng Wenlong (彭文龙), Liu Rende (刘仁
德), et al. Synthesis, characterization and tribological properties of
压性能，Ⅰ和Ⅳ的 P B 值都比液体石蜡提高了 61%， butoxy dithiocarbonate acetic ester as lubricating additives[J].
Tribology (摩擦学学报), 2011, 31(5): 515-520.
P D 值比液体石蜡分别提高了 100%和 60%，具有作 [16] Zhao Hongbi (赵鸿斌), Liu Yanli (刘艳丽), Chang Hui (常慧), et al.
Synthesis, characterization and tribological properties of 1-H
为极压润滑油添加剂的应用潜力。4 种添加剂均能 benzotriazole chloroacetate derivatives[J]. Lubrication Engineering
(润滑与密封), 2008, 33(2): 714-720.
有效地提高液体石蜡的抗磨和减摩性能，添加 1.0% [17] Zhang Zhigang (张志刚), Zhao Hongbin (赵鸿斌), Chang Hui (常
Ⅰ、Ⅲ、Ⅳ的油样的 WSD 较液体石蜡分别降低了 慧), et al. Synthesis and tribological study of 1,4-di(dithiocarbamate
acetate) piperazine as lubricating oil additive[J]. Lubrication
34%、38%和 43%；含Ⅰ的油样平均摩擦系数比液 Engineering (润滑与密封), 2008, 33(1): 86-89.
[18] Li J, Xu X, Wang Y, et al. Tribological studies on a novel borate ester
体石蜡减小了 26%左右。 containing benzothiazol-2-yl and disulfide groups as multifunctional
（4）长磨实验钢球磨斑表面 SEM 图片显示， additive[J]. Tribology International, 2010, 43(5): 1048-1053.
[19] Ouyang Ping (欧阳平), Chen Guoxu (陈国需), Zhang Xianming (张
添加Ⅲ和Ⅳ的油样的长磨磨斑直径明显比液体石蜡 贤明). Performance of zero-sulphur/phosphorus quinazolinone amine
as multifunctional lubricating oil additive[J]. Acta Petrolei Sinica:
的小，磨痕规整，犁沟浅而细；EDS 结果表明，添 Petroleum Processing Section) (石油学报:石油加工), 2013, 29(3):
447-452.
加剂在摩擦过程中参与了摩擦化学反应，生成了复 [20] Jia Z, Xia Y, Pang X, et al. Tribological behaviors of different
杂的防护膜，从而提高极压、抗磨和减摩的性能。 diamond-like carbon coatings on nitrided mild steel lubricated with
benzotriazole-containing borate esters[J]. Tribology Letters, 2011,
（5）Ⅰ的极压、抗磨和减摩性能都明显优于Ⅱ， 41(1): 247-256.
[21] Zeng X, Shao H, Rao W, et al. Tribological study of
说明二酯结构的添加剂比二酰胺结构的添加剂更容 trioctylthiotriazine derivative as lubricating oil additive[J]. Wear,
2005, 258(5): 800-805.
易在摩擦过程中形成保护膜，从而提高极压、抗磨 [22] Xiong L P, He Z Y, Han S, et al. Tribological properties study of
和减摩性能；Ⅳ比Ⅲ具有更好的极压性能，但二者 N-containing heterocyclic imidazoline derivatives as lubricant
additives in water-glycol[J]. Tribology International, 2016, 104(1):
的抗磨和减摩性能相当，说明Ⅳ分子结构中的黄原 98-108.
[23] Yan J, Zeng X, Heide E V D, et al. The tribological performance and
酸酯基只改善了其极压性能，而对其抗磨和减摩性 tribochemical analysis of novel borate esters as lubricant additives in
rapeseed oil [J]. Tribology International, 2014, 71(1): 149-157.
能影响不大。 [24] Fan K, Li J, Ma H, et al. Tribological characteristics of ashless
dithiocarbamate derivatives and their combinations with ZDDP as
参考文献： additives in mineral oil[J]. Tribology International, 2008, 41(12):
1226-1231.
[1] Chen Yiping (陈祎平). Development of green fine chemicals[J]. [25] Huang Yihui (黄伊辉), Li Fenfang (李芬芳), You Jianwei (尤建伟),
Natural Science Journal of Hainan University (海南大学学报自然科 et al. The tribological properties of hydroxyl-containing dithiocarbamate
学版), 2002, 20(1): 77-82. derivatives as additives in rapeseed oil[J]. Petroleum Processing and
[2] Spikes H. Low- and zero-sulphated ash, phosphorus and sulphur Petrochemicals (石油炼制与化工), 2010, 41(3): 60-64.
anti-wear additives for engine oils[J]. Lubrication Science, 2008, [26] Zhu Miao (朱苗), Wang Jian (王鉴), Tang Haiyan (唐海燕), et al.
20(2): 103-136. Synthesis and tribological properties of the hydroxyl derivatives
[3] Yang Guangbin (杨广彬), Tian Yu (田雨), Zhang Jinfeng (张金峰), containing N and S[J]. Acta Petrolei Sinica (Petroleum Processing
et al. Preparation and tribological properties of N-containing Section) (石油学报(石油加工)), 2016, 32(4): 800-807.
heterocyclic borates as lubricant additives[J]. Tribology, 2012, 32(4): [27] Li Z, Li X, Zhang Y, et al. Tribological study of a highly
384-389. hydrolytically stable phenylboronic acid ester containing
[4] Wang Xianhui (王先会). Production and application of industrial benzothiazolyl in mineral oil[J]. Applied Surface Science, 2014,
lubricants[M]. China Petrochemical Press (中国石化出版社), 2011. 308(4): 91-99.