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第 35 卷第 9 期 精 细 化 工 Vol.35, No.9
201 8 年 9 月 FINE CHEMICALS Sept. 2018

综论
超临界二氧化碳流体染色工程化研究进展

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郑环达 ，郑禹忠 ，岳成君 ，韩建国 ，郑来久
（1. 大连工业大学 辽宁省清洁化纺织重点实验室，辽宁 大连 116034；2. 中昊光明化工研究设计院有限
公司，辽宁 大连 116031；3. 中昊（大连）化工研究设计院有限公司，辽宁 大连 116023）
摘要：介绍了超临界 CO 2 流体基本性质；综述了近年来国内外在超临界 CO 2 流体工程化染色装备系统、工程化
染色工艺技术和专用染料三方面的最新研究进展。结果表明：经过多年发展，适用于散纤维、筒纱、织物的超
临界 CO 2 流体工程化染色装备开始逐步推向市场，并可通过智能安全联锁系统保障装备的安全运行；聚酯纤维
材料超临界 CO 2 流体染色工程化染色工艺技术日趋成熟，已经在世界范围内进行了初步生产应用；但天然纤维
超临界 CO 2 流体染色专用染料仍存在色牢度差，易于造成设备腐蚀等问题。指出超临界 CO 2 流体染色专用商品
化染料体系建立、超临界 CO 2 流体染色装备工业放大设计和超临界 CO 2 流体染色工艺放大效应是该项技术产业
化应用进程中应着力解决的关键问题。
关键词：超临界 CO 2 ；装备；染料；染色；工艺；研究进展
中图分类号：TS193 文献标识码：A 文章编号：1003-5214 (2018) 09-1449-09

Research Progress on Engineering Technology of Supercritical
Carbon Dioxide Fluid Dyeing

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ZHENG Huan-da , ZHENG Yu-zhong , YUE Cheng-jun , HAN Jian-guo , ZHENG Lai-jiu
（1. Liaoning Provincial Key Laboratory of Ecological Textile, Dalian Polytechnic University, Dalian 116034, Liaoning,
China; 2. Zhonghao Guangming Research & Design Institute of Chemical Industry Co., Ltd., Dalian 116031, Liaoning,
China; 3. Zhonghao (Dalian) Research & Design Institute of Chemical Industry Co., Ltd., Dalian 116023, Liaoning, China）
Abstract: Basic properties of supercritical CO 2 fluid was introduced. Recent research advances of
engineering apparatus system, engineering dyeing procedure and special dyes in supercritical CO 2 fluid
were reviewed at home and abroad. The results show that after many years of development, supercritical
CO 2 fluid engineering dyeing apparatus for fibers, bobbins and fabrics have been gradually put into the
market, which can guarantee the safe operation by employing an intelligent security interlock system.
Engineering dyeing procedure technology for polyester in supercritical CO 2 fluid becomes more and more
mature, and has been made initial production applications worldwide. However, special dyes for natural
fibers dyeing in supercritical CO 2 fluid still have the problems of poor color fastness and are easy to cause
equipment corrosion. At last, the problems that should strive to solve in the industrialization of supercritical
CO 2 fluid dyeing were put forward, including the establishment of special commercial dye system for
supercritical CO 2 fluid dyeing, the industrial amplification design of supercritical CO 2 fluid dyeing
apparatus and the amplification effect of supercritical CO 2 fluid dyeing procedure.
Key words: supercritical CO 2; apparatus; dye; dyeing; procedure; research progress
Foundation items: Group Project of Liaoning Provincial Department of Education (2016J003); China
Postdoctoral Science Foundation (2017M611420)

中国是世界上规模最大的纺织服装生产、消费 行业之一。根据中国印染行业协会统计数据显示，
和出口国，纺织染整行业是纺织工业中最重要的子 全国印染企业数量超过 2300 家，印染布年产量高达

收稿日期：2017-08-22; 定用日期：2017-12-12; DOI: 10.13550/j.jxhg.20170688
基金项目：辽宁省协同创新群体专项（2016J003）；中国博士后基金面上项目（2017M611420）
作者简介：郑环达（1987—），男，讲师，博士。联系人：郑来久（1956—），男，教授，电话：0411-86323511，E-mail：fztrxw@dlpu.edu.cn。