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第 35 卷第 9 期 精 细 化 工 Vol.35, No.9
201 8 年 9 月 FINE CHEMICALS Sept. 2018

功能材料
三维 Fe@GE-Cu 复合材料的制备及其催化性能

周 勇，杨 怡，刘巧云

（常州工程职业技术学院 制药与环境工程系，江苏 常州 213164）

摘要：以葡萄糖为碳源、NH 4 Cl 为发泡剂、纳米金属 Fe 为促进葡萄糖石墨化的催化剂，制备了 Fe@GE 复合材
料，通过 UV-vis、Raman 分析表明，复合材料 Fe@GE 石墨化程度高，石墨烯膜缺陷少；再以 Fe@GE 作为基
质材料，采用低温水热法成功将其与纳米 Cu 进行复合，制备了三维 Fe@GE-Cu 复合材料。通过 TEM 和 FESEM
分析证明，Fe@GE 与纳米 Cu 成功复合；通过 XRD、FTIR 和 ICP 测试表明，复合材料 Fe@GE-Cu 在常态下较
为稳定。以 49 mL （200 mg/L）重铬酸钾溶液为例，进行催化还原性能测试，加入 1 mL 质量分数为 88%的甲
酸水溶液后，再加入 10 mg 催化剂 Fe@GE-Cu 0.65 ，在 9 min 时，Cr(Ⅵ)已被全部还原，表明该复合材料具有高
效催化还原 Cr(Ⅵ)的性能，能有效解决重金属污染问题。
关键词：石墨烯；铁纳米粒子；纳米复合材料；催化性能；功能材料
中图分类号：TQ426.61 文献标识码：A 文章编号：1003-5214 (2018) 09-1486-05

Preparation and Catalytic Performance of Three-dimensional
Fe@GE-Cu Composite

ZHOU Yong, YANG Yi, LIU Qiao-Yun
（Institute of Pharmaceutical and Environmental Engineering, Changzhou Vocational Institute of Engineering, Changzhou
213164, Jiangsu, China）

Abstract: A Fe@GE composite was synthesized by using glucose as carbon source, NH 4Cl as foaming
agent, iron nanoparticles as catalyst to promote the graphitization of glucose. The resulting Fe@GE
composite exhibited high degree of graphitization with less defects, which was confirmed by UV-vis and
Raman spectroscopy. Subsequently, Fe@GE composite combined with nano-Cu through low-temperature
hydrothermal method to produce a three-dimensional (3D) Fe@GE-Cu composite. The 3D Fe@GE-Cu
composite was testified by TEM and FESEM. In addition, the Fe@GE-Cu composite was stable under
ambient state according to the analysis results of XRD, FTIR and ICP. The catalytic reduction activity of the
prepared composite was tested by the reaction of 49 mL K 2Cr 2O 7 solution (200 mg/L). After adding 1 mL
(mass fraction 88%) HCOOH and 10 mg Fe@GE-Cu 0.65 catalyst, Cr(Ⅵ) was completely reduced within 9
minutes, indicating that the composite Fe@GE-Cu 0.65 had high catalytic activity in the reduction of Cr(Ⅵ)
and could effectively solve the problem of heavy metal pollution.
Key words: graphene; iron nanoparticles; nano-composite; catalytic performance; functional materials
Foundation items: Industry-Academia-Research Prospective Joint Research Project of Jiangsu Province
(BY2015032-01); Top-notch Academic Programs Project of Jiangsu Higher Education Institutions
(PPZY2015B178)

铬元素广泛分布在大自然中，主要有两种价态。 各种废水中，如染料废水、金属电镀废水和制革废
六价铬〔Cr(Ⅵ)〕是一种致癌和致突变的有毒物质， 水等。中国每年产生的铬废水高达几十万吨 [1-3] 。而
易被人体吸收，在水体中溶解度高，频繁被发现于 三价铬是无毒、较为惰性的，是人体所需的微量元

收稿日期：2017-04-20; 定用日期：2018-01-12; DOI: 10.13550/j.jxhg.20170333
基金项目：江苏省产学研前瞻性联合研究项目（BY2015032-01）；江苏高校品牌专业建设工程资助项目（PPZY2015B178）
作者简介：周 勇（1969—），男，副教授，E-mail：511594416@qq.com。