Page 169 - 201902

第 2 期 胡程程，等: 氰尿酸钙/锌的制备及其在 PVC 制品中的应用 ·335·

以去离子水为溶剂制得氰尿酸钙和氰尿酸锌，并通 [9] Liu Peng (刘朋), Jiang Jianchun (蒋剑春), Jiang Pingping (蒋平平),
过元素分析、红外光谱、热重分析和扫描电镜对产 et al. Preparation and application of calcium/zinc laurel monomaleate
物进行了表征，确定了目标产物的生成。 used as thermal stabilizers for PVC[J]. Engineering Plastics
Application (工程塑料应用), 2015, 43(5): 105-110.
（2）热老化和刚果红实验表明，氰尿酸钙/锌
[10] Li Deling (李德玲), Ma Jiaqi (马嘉琦), Su Guixian (苏桂仙), et al.
复合体系对 PVC 制品具有良好的热稳定作用，当其
Effect of Ca-Zn stabilizer on thermal stability of PVC [J]. Plastics
用量为 PVC 质量的 1%且 m（氰尿酸钙）∶m（氰 (塑料), 2014, 43(1): 15-18.
尿酸锌）=3∶1 时，70 min 完全锌烧，热稳定时间 [11] Liu Yanbin, Liu Weiqu, Hou Menghua. Metal dicarboxylates as
达到 28 min。其作用机理为，通过捕捉 HCl 置换 PVC thermal stabilizers for PVC [J]. Polymer Degradation and Stability,
2007, 92(8): 1565-1571.
链上活泼的烯丙基氯，钙盐与 ZnCl 2 反应减少 ZnCl 2
[12] Zhu Lizhi, Wu Yijian, Shentu Baoqing, et al. Preparation and
浓度，有效地抑制了 PVC 初期着色降解以及提高了
characterization of zinc-mannitol complexes as PVC thermal
长期热稳定性能。
stabilizers with high efficiency[J]. Polymer Degradation and
（3）ESBO 是一种十分适合于氰尿酸钙/锌体系 Stability, 2016, 133: 399-403.
的辅助热稳定剂，不仅使氰尿酸钙/锌复合体系前期 [13] Chen Huanzhang (陈焕章), Li Hua (李花), Li Hong (李宏). Study on
和长期热稳定效果得到大幅度提升，而且在 m（氰 preparation and performance of zinc cyanurate thermal stabilizer for
PVC [J]. Journal of Hebei University of Science and Technology (河
尿酸钙）∶m（氰尿酸锌）=3∶2 时，热稳定时间能
北科技大学学报), 2016, 37(1): 33-38.
达到 76 min。
[14] Li Mei (李梅), Jiang Zaiyong (姜在勇), Liu Zhaogang (柳召刚), et
参考文献： al. Study on synthesis of lanthanum cyanuric and its thermal
stabilizing effect on PVC [J]. Plastic Technology (塑料科技),
[1] Wu Maoying ( 吴茂 英 ). Development trend and technological
2012, 40(4): 114-118.
progress of heat stabilizers for PVC[J]. Plastics (塑料), 2010, 39(3):
[15] Niu Cuiying (牛翠英), Shen Min (沈敏), Xiao Shan (肖珊). The
1-7.
determination of the zinc content in calcium-zinc salt-EDTA
[2] Wang Xingwei (王兴为), Wang Wei (王玮), Liu Qin (刘琴), et al.
complexometric titration [J]. China Well and Rock Salt (中国井矿
Plastic additives and formulation design technology [M]. Beijing:
盐), 2010, 41(3): 30-32.
Chemical Industry Press (化学工业出版社), 2016: 197-263.
[16] Geng Yanxia (耿艳霞). Determination of metal calcium content in
[3] Bai Qirong (白启荣). The functional mechanism of PVC heat
calcium line with EDTA titration[J]. Hebei Metallurgy (河北冶金),
stabilizer [J]. Technological Innovation and Productivity (科技创新
2015, (7): 69-71.
与生产力), 2007, (11): 31-32.
[17] Song Yinyin (宋银银). Investigation and application of the new type
[4] Folarin O M, Sadiku E R. Thermal stabilizers for poly(vinyl
Ca/Zn thermal stabilizer for poly(vinyl chloride) [D]. Wuxi: Jiangnan
chloride): A review[J]. International Journal of the Physical Sciences,
University (江南大学), 2012.
2011, 6(18): 4323-4330.
[18] Li Shumin (李树民). Study on Ca/Zn barbiturate thermal stabilizers
[5] Kiyoshi Endo. Synthesis and structure of poly(vinyl chloride)[J].
for poly(vinyl chloride)[D]. Beijing: Tsinghua University (清华大
Progress in Polymer Science, 2002, 27(10): 2021-2054.
[6] Starnes W H. Overview and assessment of recent research on the 学), 2011.
structuraldefects in poly(vinyl chloride)[J]. Polymer Degradation [19] Xu Xiaopeng, Chen Si, Tang Wei, et al. Investigation of basic zinc
Stability, 2012, 97(9): 1815-1821. cyanurate as a novel thermal stabilizer for poly(vinyl chloride) and
[7] Zhang Qixing (张启兴). The application of heat stabilizers in the its synergistic effect with calcium stearate[J]. Polymer Degradation
processing of PVC plastic product[J]. Polyvinyl Chloride (聚氯乙 and Stability, 2014, 99(1): 211-218.
烯), 2007,35 (7): 1-4. [20] Fu Ming, Li Degang, Liu Hao, et al. Insights into the use of
[8] Xu Shilu, Li Degang, Yu Xianjin, et al. Study on pentaerythritol-zinc zinc-mannitol alkoxide as a novel thermal stabilizer for rigid
as a novel thermal stabilizer for rigid poly(vinyl chloride)[J]. Journal poly(vinyl chloride) [J]. Journal of Applied Polymer Science, 2015,
of Applied Polymer Science, 2012, 126(2): 569-574. 132(23): 42038.