Page 82 - 《精细化工》2020年第5期

·932· 精细化工 FINE CHEMICALS 第 37 卷

grafting polystyrene from guar gum using atom transfer radical
3 结论 addition[J]. Carbohydrate Polymers, 2017, 176: 266-272.
[11] BHULLAR N, KUMARI K, SUD D. A biopolymer-based composite
（1）利用一步水热反应法成功合成了 GO/GA- hydrogel for rhodamine 6G dye removal: Its synthesis, adsorption
isotherms and kinetics[J]. Iranian Polymer Journal, 2018, 27:
g-PAMPS 复合水凝胶，FTIR、XRD、SEM 表征显 527-535.
示复合水凝胶具有均匀的三维交联网状结构，GO [12] KONG H L, YANG J X, ZHANG Y F, et al. Synthesis and antioxidant
properties of gum arabic-stabilized selenium nanoparticles[J].
在凝胶中具有较好的相容性。
International Journal of Biological Macromolecules, 2014, 65: 155-
（2）水凝胶对阳离子染料有较好的吸附效果， 162.
在 GO 质量浓度为 0.3 g/L、凝胶用量为 0.05 g、溶 [13] HUANG M H (黄敏慧), BAO Z B (鲍宗必), DUAN Shuran (段舒
然), et al. Optimization of acid hydrolysis for preparing larabinose
液 pH 为 7、温度为 50 ℃、染料初始浓度为 200 mg/L from gum arabic[J]. CIESC Journal (化工学报), 2015, 66(7):
时，凝胶对 MB 和 CV 的吸附量和吸附率分别为 2528-2533．
395.68、381.70 mg/g 和 98%、96%。吸附等温线和 [14] WANG X N (王雪妮), XU J H (徐继红), HE M Q (何梦奇), et al.
Synthesis and characterization of a GA-g-PAA/ST composite
吸附动力学表明，水凝胶对 CV 的吸附符合 Langmuir hydrogel[J]．Fine Chemicals (精细化工), 2019, 36(4): 633-638.
模型，对 MB 的吸附更符合 Freundlich 模型。准二 [15] SHARMA G, KUMAR A, NAUSHAD M, et al. Fabrication and
characterization of gum arabic-cl-poly(acrylamide) nanohydrogel for
级动力学模型更符合水凝胶对 MB 和 CV 的吸附过
effectiveadsorption of crystal violet dye[J]. Carbohydrate Polymers,
程。吸附热力学表明，水凝胶对 MB 和 CV 染料分 2018, 202: 444-453.
子的吸附是无序且随机的，吸附后混乱度增加，吸 [16] ZHANG T L (张田林), WANG J J (王佳佳), ZHU C Y (朱彩艳), et
al. Synthesis of quaternary ammonium salt chelating resin and its
附过程属自发的不可逆过程。
adsorption of lead ion[J]. Acta Polymerica Sinica (高分子学报),
（3）复合水凝胶加入 GO 能明显提高凝胶的力 2013, (9): 1219-1225.
学性能。经过 5 次吸附解吸循环后，复合水凝胶对 [17] SAHRAEI R, GHAEMY M. Synthesis of modified gum tragacanth/
graphene oxide composite hydrogel for heavy metal ions removal
两种染料的吸附率仍然达到 80%以上，可以多次重 and preparation of silver nanocomposite for antibacterial activity[J].
复使用，具有较好的使用价值。 Carbohydrate Polymers, 2017, 157: 823-833.
[18] LEI B (雷蓓), HE A (何蔼), CHENG C (程冲), et al. Adsorption of
参考文献： cationic dyes by biopolymers mediated graphene oxide gels[J]. Acta
Polymerica Sinica (高分子学报), 2014, (3): 341-349.
[1] YANG J Y, YUE B Y, TENG J, et al. Aqueous metal ions adsorption [19] SONG X, HUANG X H, LI Z X, et al. Construction of blood
by poly (ethylene glycol) modified graphene oxide： Surface area compatible chitin/graphene oxide composite aerogel beads for the
and surface chemistry effects[J]. Desalination and Water Treatment, adsorption of bilirubin[J]. Carbohydrate Polymers, 2019, 207: 704-
2019, 138: 147-158. 712.
[2] WEI J Z (魏金枝), CHEN F N (陈芳妮), SUN X J (孙晓君), et al. [20] MARCANO D C, KOSYNKIN D V, BERLIN J M, et al. Improved
Adsorption performance of amino functionalized magnetic graphene
synthesis of graphene oxide[J]. ACS Nano, 2010, 4(8): 4806-4814.
oxide composite to ionic dyes[J]. China Environmental Science (中
[21] HUANG Q (黄桥), SUN H J (孙红娟), YANG Y H (杨勇辉).
国环境科学), 2016, 36(7): 2020-2026.
[3] ZHANG Y Y, GONG S S, ZHANG Q, et al. Graphene-based Spectroscopic characterization and analysis of graphite oxide[J].
artificial nacre nanocomposites[J]. Chemical Society Reviews, 2016, Chinese Journal of Inorganic Chemistry, 2011, 27(9): 1721-1726.
45(9): 2378-2395. [22] XIE Y Z (谢元仲), XU S Y (徐淑艳), ZHANG W L (张维丽), et al.
[4] KUILLA T, BHADRA S, YAO D, et al. Recent advances in graphene Preparation and properties of graphene and polylactic acid
based polymer composites[J]. Progress in Polymer Science, 2010, composites[J]. Packaging Engineering (包装工程), 2016, 37(9):
35(11): 1350-1375. 7-11.
[5] SHEN Y, FANG Q, CHEN B. Environmental applications of three- [23] XU J H (徐继红), XU S W (许少薇), ZHOU J S (周加深), et al.
dimensional graphene-based macrostructures: Adsorption, transformation, Synthesis and swelling behaviors of GA-g-PAMPS/APT
superabsorbent resin[J]. Fine Chemicals (精细化工), 2016, 33(7):
and detection[J]. Environmental Science & Technology, 2015, 49(1):
753-760.
67-84.
[6] SHAN G R (单国荣), ZHANG N (张宁). Research progress on [24] ZHAO G X, JIANG L, HE Y D, et al. Sulfonated graphene for
graphene oxide composite hydrogels[J]. CIESC Journal (化工学报), persistent aromatic pollutant management[J]. Advanced Materials,
2018, 69(2): 535-545. 2011, 23 (34): 3959-3963.
[7] BAO Y, MA J, SUN Y. Swelling behaviors of organic/inorganic [25] MINITHA C R, LALITHA M, JEYACHANDRAN Y L, et al.
composites based on various cellulose derivatives and inorganic Adsorption behaviour of reduced graphene oxide towards cationic
particles[J]. Carbohydrate Polymers, 2012, 88(2): 589-595. and anionic dyes: Co-action of electrostatic and π–π interactions[J].
[8] WANG Y Z, SHI X N, WANG W B, et al. Synthesis, characterization, Materials Chemistry and Physics, 2017, 194: 243-252.
and swelling behaviors of a pH-responsive CMC-g-poly (AA-co-AMPS) [26] MENG Q R (孟倩茹), WU C Y (吴称意), LENG S (冷珊), et al.
superabsorbent hydrogel[J]. Turkish Journal of Chemistry, 2013, Preparation of carboxymethyl chitosan/sodium alginate hydrogel and
37(1): 149-159. its adsorption performance for cationic dyes[J]. Environmental
[9] ZHAO Y S (赵彦生), LI Q (李琼), HU D (胡灯). Synthesis and Pollution & Control (环境污染与防治), 2015, 37 (8): 58-63.
responsive properties of modified poly (aspartic acid)/ poly (acrylic [27] CRINI G, PEINDY H N, GIMBERT F, et al. Removal of C.I. basic
acid) composite absorbent resin[J]. Fine Chemicals (精细化工), green 4 (malachite green) from aqueous solutions by adsorption using
2016, 33(6): 620-627. cyclodextrin-based adsorbent: Kinetic and equilibrium studies[J].
[10] YANG Y, CHEN F, CHEN Q, et al. Synthesis and characterization of Separation & Purification Technology, 2007, 53(1): 97-110.