Page 191 - 《精细化工》2021年第7期

第 38 卷第 7 期 精 细 化 工 Vol.38, No.7
202 1 年 7 月 FINE CHEMICALS July 2021

水处理技术与环境保护
一种磁性-超疏水棉纤维的制备及性能

肖 乾 1,5 ，王 斌 1,2,3,4* ，黄月文 1,4 ，

雷春艳 1,5 ，周珊珊 1,5 ，祖伟皓 1,5

〔1. 中国科学院广州化学研究所，广东 广州 510650；2. 广东省电子有机聚合物材料重点实验室，广东
广州 510650；3. 中国科学院新型特种精细化学品工程实验室，广东 广州 510650；4. 国科广化（南雄）
新材料研究院有限公司，广东 广州 510650；5. 中国科学院大学，北京 100049〕

摘要：首先，将棉纤维浸泡在含有盐酸多巴胺（DA）和纳米 Fe 3 O 4 的 Tris-HCl 缓冲溶液中制备得到聚多巴胺
（PDA）-Fe 3 O 4 磁性棉纤维。其次，用十二烷基三乙氧基硅烷（DTES）在碱性的乙醇水溶液中对 PDA-Fe 3 O 4
磁性棉纤维进一步改性，得到 DTES-PDA-Fe 3 O 4 磁性-超疏水棉纤维。采用 FTIR、XRD、TG、SEM、EDS、AFM、
水接触角测量仪对改性前后棉纤维的化学组成、表面微观结构、疏水性能进行表征；测试了改性棉纤维分离效
率、吸附性能。结果表明：DTES-PDA-Fe 3 O 4 改性棉纤维具有微/纳米尺寸粗糙结构；具有优异的超疏水性和磁
性，水接触角大于 160°；该棉纤维可重复使用且具有超高选择吸附性能和油水分离性能，可吸附自身质量 8.96
倍的氯仿，对氯仿油水混合液分离效率大于 98.90%，可应用于生产生活中含油废水的处理。
关键词：十二烷基三乙氧基硅烷；四氧化三铁；聚多巴胺；磁性；超疏水；油水分离；水处理技术
中图分类号：X703；TB34 文献标识码：A 文章编号：1003-5214 (2021) 07-1473-07

Preparation and performance of a magnetic-superhydrophobic cotton fiber

1,5
1,4
1,5
XIAO Qian , WANG Bin 1,2,3,4* , HUANG Yuewen , LEI Chunyan ,
1,5
1,5
ZHOU Shanshan , ZU Weihao
〔1. Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650, Guangdong, China; 2. CAS
Engineering Laboratory for Special Fine Chemicals, Guangzhou 510650, Guangdong, China; 3. Guangdong Provincial
Key Laboratory of Organic Polymer Materials for Electronics, Guangzhou 510650, Guangdong, China; 4. CASH GCC
(Nanxiong) Research Institute of New Materials Co., Ltd., Guangzhou 510650, Guangdong, China; 5. University of
Chinese Academy of Sciences, Beijing 100049, China〕
Abstract: Firstly, polydopamine (PDA)-Fe 3O 4 magnetic cotton fiber was formed by polymerizing
dopamine hydrochloride (DA) and nano-ferric oxide (Fe 3O 4) in Tris-HCl buffer solution. Secondly,
dodecyltriethoxysilane (DTES) was used to further modify PDA-Fe 3O 4 cotton fiber in alkaline ethanol
aqueous solution and DTES-PDA-Fe 3O 4 magnetic-superhydrophobic cotton fiber was obtained. The
chemical composition, surface microstructure, and hydrophobic properties of cotton fibers before and after
modification were characterized by FTIR, XRD, TG, SEM, EDS, AFM, water contact angle measuring
instrument. The separation efficiency and adsorption properties of modified cotton fiber also be tested. The
results showed that DTES-PDA-Fe 3O 4 cotton fiber had a rough structure of micro/nano size. The
synthesized cotton fiber possessed excellent superhydrophobicity and magnetism with a water contact angle
greater than 160°. In addition, the modified cotton fiber could be reused and had ultra-high selective
adsorption and oil-water separation efficiency. It could absorb chloroform 8.96-fold of its own mass, and
the separation efficiency for chloroform-water mixture could reach above 98.90%.
Key words: dodecyltriethoxysilane; ferroferric oxide; polydopamine; magnetic; superhydrophobicity;
oil-water separation; water treatment technology

收稿日期：2021-01-12; 定用日期：2021-03-04; DOI: 10.13550/j.jxhg.20210045
基金项目：广州市科技计划项目（202002030223）
作者简介：肖 乾（1995—），女，硕士生。联系人：王 斌（1970—），男，研究员，E-mail：wangbin@gic.ac.cn。