Page 107 - 《精细化工》2022年第12期

第 12 期 刘耀鹏，等: 废弃花生壳活化热解炭用于检测芦丁的电化学传感 ·2473·

表 2 实际样品中芦丁含量的检测（n=3） [10] MA G F, HUA F T, SUN K J, et al. Porous carbon derived from
Table 2 Detection of rutin content in real samples (n=3) sorghum stalk for symmetric supercapacitors[J]. RSC Advances,
2016, 6: 103508-103516.
标定值/ 检测值/ 加入量/ 测定值/ 回收率 RSD
样品 [11] YANG J P, XU H, CHEN H, et al. Removal of flue gas mercury by
(µmol/L) (µmol/L) (µmol/L) (µmol/L) /% /%
porous carbons derived from one-pot carbonization and activation of
2.00 1.96 0.50 2.44 96.0 3.2 wood sawdust in a molten salt medium[J]. J Hazard Mater, 2022,
H1202173 2.00 2.12 2.00 4.09 98.5 2.8 424: 127336-127349.
[12] KAMALI A R, YANG J G, SUN Q. Molten salt conversion of
2.00 2.03 6.00 8.12 101.5 3.5
polyethylene terephthalate waste into graphene nanostructures with
high surface area and ultra-high electrical conductivity[J]. Applied
Surface Science, 2019, 467: 539-551.
3 结论 [13] KAMALI A R, YANG J G. Effect of molten salts on the structure,
morphology and electrical conductivity of PET-derived carbon
以废弃花生壳为碳源，NaCl 为活化剂，采用一 nanostructures[J]. Polymer Degradation and Stability, 2020, 177:
109184-109195.
步熔融盐活化热解法制备了一类生物质多孔炭材 [14] CHEN G, ZHANG H W, YE J N. Determination of rutin and
料；与 PHPC 相比，PHAPC 具有丰富的孔道结构， quercetin in plants by capillary electrophoresis with electrochemical
比表面积增加了 1.6 倍，石墨化程度更高。将其作 detection[J]. Analytica Chimica Acta, 2000, 423(1): 69-76.
[15] TEMERK Y M, IBRAHIM H S M, SCHUHMANN W. Cathodic
为修饰材料构建的电化学传感器对芦丁具有选择性 adsorptive stripping voltammetric determination of the antitumor
吸附性能，PHAPC/GCE 与 PHPC/GCE 的 DPV 电流 drug rutin in pharmaceuticals, human urine, and blood serum[J].
Microchimica Acta, 2006, 153(1/2): 7-13.
响应差值为 24.72 µA。说明其中熔融盐起到了重要
[16] TAO J, HU Q X, YANG J, et al. In vitro anti-HIV and -HSV activity
的作用，提高了炭材料的电化学活性和导电率。本 and safety of sodium rutin sulfate as a microbicide candidate[J].
文探究的材料制备方法绿色环保简易，也符合当今 Antiviral Research, 2007, 75(3): 227-233.
[17] HASSAN H N A, BARSOUM B N, HABIB I H I. Simultaneous
废弃物再利用的可持续发展理念，其构建的传感器 spectrophotometric determination of rutin, quercetin and ascorbic
对芦丁的检测具有检出限低、灵敏度高和稳定性好 acid in drugs using a Kalman filter approach[J]. Journal of
等特点。 Pharmaceutical and Biomedical Analysis, 1999, 20(1): 315-320.
[18] CHEN Z, ZHANG L Y, CHEN G. Microwave-assisted extraction
followed by capillary electrophoresis-amperometric detection for the
参考文献：
determination of antioxidant constituents in Folium Eriobotryae[J].
[1] TONG X J, LI J Y, YUAN J H, et al. Adsorption of Cu(Ⅱ) by Journal of Chromatography A, 2008, 1193(1): 178-181.
biochars generated from three crop straws[J]. Chemical Engineering [19] LIU Q, CAI W S, SHAO X G. Determination of seven polyphenols
Journal, 2011, 172(2): 828-834. in water by high performance liquid chromatography combined with
[2] JIANG T Y, JIANG J, XU R K, et al. Adsorption of Pb(Ⅱ) on preconcentration[J]. Talanta, 2008, 77(2): 679-683.
variable charge soils amended with rice-straw derived biochar[J]. [20] ZHAN G C, LI Z, JUN H C, et al. A sensitive rutin assay using a
Chemosphere, 2012, 89(3): 249-256. simple probe manganese sulfate based on its novel resonance light
[3] ZHANG L, XU L, ZHANG Y G, et al. Facile synthesis of bio-based scattering decrease phenomenon[J]. Spectrochimica Acta Part A:
nitrogen- and oxygen-doped porous carbon derived from cotton for Molecular and Biomolecular Spectroscopy, 2008, 71(2): 344-349.
supercapacitors[J]. RSC Advances, 2018, 8(7): 3869-3877. [21] KATARZYNA T. Sensitive voltammetric determination of rutin at an
[4] DONG W Z (董文召), HAN S Y (韩锁义), XU J (徐静), et al. in situ plated lead film electrode[J]. Journal of Pharmaceutical and
Research status and application prospect of peanut shell[J]. Chinese Biomedical Analysis, 2009, 49(2): 558-561.
Agricultural Science Bulletin (中国农学报), 2019, 35(32):14-19. [22] SUN W, YANG M X, LI Y Z, et al. Electrochemical behavior and
[5] ZHANG T J (张铁军), OU X T (欧晓婷), KONG L Y (孔令漪), et al. determination of rutin on a pyridinium-based ionic liquid modified
Study on preparation of activated carbon using microwave method carbon paste electrode[J]. Journal of Pharmaceutical and Biomedical
from submerged shells and peanut shells and comparision of of the Analysis, 2008, 48(5): 1326-1331.
adsorption property[J]. Chemical and Biological Engineering (生物 [23] LI L (李蕾), ZENG Y B (曾延波), TANG C G (汤传贵) et al. A
化工), 2017, 3(3): 9-13. molecularly imprinted polymer on the surface of carbon nanotubes
[6] KESAVAN T, RAAJU S A S, DHARANESHWAR S, et al. N-doped and the preparation method and application: CN103965418A[P].
carbon nanosheets from biomass for ultra long-cycling and high energy 2014-08-06.
density symmetric supercapacitors[J]. ECS Journal of Solid State [24] WANG F (王芳), GUO J F (郭建峰), ZHANG Y L (张艳玲)，et al.
Science and Technology, 2021, 10(5): 051004-051018. Preparation and detection method of electrochemical sensor for
[7] SYLLA N F, NDIAYE N M, NGOM B D, et al. Ex-situ analysis of tea polyphenols and its components: CN114166908A[P].
nitrogen-doped porous carbons as electrode materials for high 2022-03-11.
performance supercapacitor[J]. Journal of Colloid and Interface [25] FECHLER N, FELLINGER T P, ANTONIETTI M. "Salt
Science, 2020, 569: 332-345. templating": A simple and sustainable pathway toward highly porous
[8] LIU W J, JIANG H, YU H Q. Development of biochar-based functional carbons from ionic liquids[J]. Advanced Materials, 2013,
functional materials: Toward a sustainable platform carbon 25(1): 75-79.
material[J]. Chemical Reviews, 2015, 115(22): 12251-12285. [26] LI J, LIU W L, XIAO D, et al. Oxygen-rich hierarchical porous
[9] ZHANG L M, YOU T T, ZHOU T, et al. Interconnected hierarchical carbon made from pomelo peel fiber as electrode aterial for
porous carbon from lignin-derived byproducts of bioethanol supercapacitor[J]. Applied Surface Science, 2017, 416: 918-924.
production for ultra-high performance supercapacitors[J]. Applied
Materials & Interfaces, 2016, 8(22): 13918-13925. （下转第 2491 页）